配位

Suzuki cross-coupling of aryl bromides with arylboronic acid is one of effective methods to form biphenyl derivatives in organic synthesis.

在有机合成中，Suzuki交叉偶联反应是制备联苯类化合物最重要的方法之一，本论文设计并合成了二个P⌒O系列、一个P⌒N系列双齿配位的钯配合物。

First ofall, these are techniques based on the use of chemically bonded complexing groupings.

首先，它们都是基于采用了化学方法结合的配位组分的技术。

First ofall, these are techniques based on the use of chemically bonded complexing groupings.

首先，这些技术都基于化学键合配位基团的应用。

We note from the further studies that in the crystals, which sharing the similar crystal structures and coordinational environments, the magnitude of the Stokes shift of the luminescence of the dopant ion is in line with the average covalency of the replaced lattice site. This is because that the nature of Stokes shift is the energy transfer from the luminescent ion to the host lattice. The value of this energy is determined by the frequency of the host lattice in which the frequency is controlled by the chemical bond characters.

更深入的研究发现，在晶体结构和中心离子配位环境非常相似的系列晶体中，掺杂离子发射光的Stokes位移值与其所取代格位的平均共价性成正比的关系，这是由于Stokes位移的本质是发光离子在发光过程中向基质以光波辐射的形式传递能量，这一能量的大小是由基质的振动频率决定的，而基质的化学键性质恰恰决定着基质的振动频率。

This makes Ni-W-P powder more suitable for partial hydrogenation of dienes. The kinetic results suggest there are some different between the active sites of Ni-P and Ni-W-P powder. DSC, XRD and EXAFS results suggest that the tungsten codeposition makes Ni-W-P powder more amorphous than Ni-P powder.

动力学结果表明在两种合金微粒上，不仅环戊二烯与环戊烯的相对配位能力不同，而且它们各自的反应速率常数也不一样，表明非晶态Ni-P、Ni-W-P合金微粒的催化活性中心存在着一定的差异。

Herein the latest developments of olefin aqueous polymerization which are mainly promoted by late- transition metal catalysts are reviewed including ethylene,α-olefins, cyclo-olefins and dienes polymerization, along with ROMP of cyclo-olefins and CO/olefins copolymerization.

本文综述了后过渡金属催化剂水相催化烯烃配位聚合的一些新进展，内容包括烯、α-烯烃、环烯烃、二烯烃的聚合反应和环烯烃的开环聚合反应以及CO/烯烃的共聚反应等方面。

In compound 1, two independent other than dimerized copper-phenanthroline graups are fused to the oxggen atoms in the vacant site of the mono-lacunary polyanton in parallel.

该化合物分子中2个独立的非二聚体的铜－邻菲啰啉平行地与缺位多酸空穴外的氧配位键合，通过元素分析、红外光谱、热重分析和X射线单晶衍射对其结构进行了表征。

Er concentration.2. With the analysis of the optical parameters calculated by Judd-Ofelt theory and the lifetime of ~4I_(13/2) of Er gotten in experiment, we investigated Y dopings dispertion effect and influence to the environment of Er .3. In the research of Er/Yb/Al co-doped laser glass, we fixed the Er:Yb at 1:6 and varied the Al concentration.

我们利用Judd-Ofelt理论，计算得到了Er/Y共掺玻璃的Judd-Ofelt强度系数、光谱质量因子、自发辐射弛豫率和能级寿命等光谱参数，并且给出了不同Y掺杂浓度下Er~(3 )离子的荧光量子效率；结合Er~(3 )离子~4I_(13/2)能级的荧光寿命，深入探讨了掺Y对高浓度Er~(3 )离子在硼硅酸盐玻璃中分布的弥散作用和对配位场环境的影响。

The structure and appearance of the glass-ceramics after heat-treat...

随着热处理温度的升高，β-石英固溶体转变成β-锂辉石固溶体，而且微晶玻璃相应的变为不透明的乳白色，同时红外光谱可以检测到Al—O键的配位状态，且温度越高，Al—O键所占的比重越大。

So far they have been synthesized with various substituted groups and cavity-size of 4-20 phenol units. Calixarenes have been utilized in fields of complexation, catalysis, extraction, ionophore and so on.

目前已经合成出了4-20个苯酚单元所构成的不同环腔尺寸和具有不同取代基的杯芳烃：它已在配位、催化、萃取、离子载体、分离材料等领域得到了应用，在色谱中的应用也日益受到关注。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。