配位

Compared with the catalytic behaviors of the reference catalysts, CpTiCl〓 and n-CpTiCl〓, we could identify that the pendant ethereal group played an important role in this selective trimerization process.

将它们的催化性能与CpTiCl〓、n-CpTiCl〓比较，可以确定，氧对钛活性中心的配位对乙烯三聚反应起重要作用。

Furthermore, tripodal ligands and their complexes represent excellent capability and fine application prospect in many aspects, such as coordination chemistry, electrochemistry, medicine, catalytic chemistry, biochemistry, and supramolecular chemistry.

三脚架结构的化合物及其配合物在配位化学、电化学、医学、催化化学、生物化学、超分子化学等方面均表现出优良的性能和很好的应用前景。

The axial interaction of vanadyl meso-tetraphenylporphyrin and nickel meso-tetraphenylporphyrin with different Lewis basic solvents was investigated by using an ultraviolet-visible spectrophotometric method.

应用紫外可见分光光度法研究了氧钒对四苯基卟啉和镍对四苯基卟啉与Lewis碱性溶剂的轴向配位作用。

Four amino-acid ligands(glycine, serine, aspartic acid, phenylalanine) was selected to coordinate with vanadyl cation to form amino-acid vanadyl complexes.

选择甘氨酸、丝氨酸、天冬氨酸和苯丙氨酸四种氨基酸与氧钒离子配位形成氨基酸氧钒配合物。

Thus. Treatment of CR1R2=C=CH2 (R1 = R2 = Me; R1 = H, R2 = n-Bu; R2 = Ph; R2 = cyclohexyl; R2 = cyclopentyl, R2 = C6H5O, R2 = 2-IC6H4O, R2 = 4-IC6H4O) with bisdiborn in the presence of Pd2 (5 mol %) and 3-iodo-2-methyl-2-cyclohexen-1-one (5 mol %) in toluene at 80 oC gave products bearing both vinylic and allylic boron moieties in good to excellent yields.

但我们发现可以使用Pd金属错合物与有机碘化物共同催化下的系统，来进行此种加成反应。溶剂的选择以甲苯为最佳，Pd错合物以没有强配位基存在为最好的选择。

Metallothioneins are a group of cysteine-rich, low-molecular-weight proteins, which can bind metal ions through mercaptide bonds.

金属硫蛋白(metallothionein，简称MT)是一类富含半胱氨酸的低分子量蛋白质，能够通过配位键结合金属离子。

The interactions of alkali and alkaline-earth ions and rare—earth metal ions with saccharides, resulting in the formation of saccharide adducts, have been investigated in great detail.

本文主要从糖的构型、构象、金属离子半径的大小和电荷的影响等方面入手分别研究了固体和水溶液中糖与金属离子的配位现象。

At first,the amino group of amino acid esters interacts with the carboxyl group of the amino acid residue of this porphyrinatozinc to form 1:1 adducts.

氨基酸酯的氨基首先与氨基酸残基的羧基作用形成1：1的加合物，然后与锌卟啉的中央锌原子配位形成1：2的加合物，客体分子与主体分子上的氨基酸残基之间的排斥作用以及主客体之间的色散力作用是主体分子能识别客体分子的另外两种作用。

It is shown from study results that the soluble iron has a strong controlling effect on the phytoplanktonic growth, and most of soluble iron is chelated with ligand such as siderophore with high affinity to Fe 3+.

研究表明，可溶性铁对浮游植物生长有很强的控制作用，大部分可溶性铁是同具有极强铁亲和力的配位体螯合在一起的，如铁载体。

The salt effect of biosorption process might be related with the radii of cations and the stability of chelates, maybe also related to the interaction between anions and functional groups which had positive charge.

生物吸附过程的盐效应可能与阳离子的半径以及与配位体所形成的配合物的稳定性有关，也可能与菌体表面带正电荷的官能团与阴离子之间的静电作用有关。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。