配位

The semiconductor nanocrystalline surface is modified by using organic overlay method. As an organic overlay,-methacrylic restrains the reuniter between the grains in the latter process. Furthermore, it can combine with empty bond of atom at grain surface state and eliminate the surface state.

应用有机包覆的方法对纳米颗粒进行了表面修饰，作为包覆剂的α-甲基丙烯酸有效抑制了后处理工艺中纳米颗粒间的团聚现象，在纳米颗粒表面形成帽层，并与粒子表面态的原子悬键进行配位，这对消除表面态是非常有益的。

Basal leaves petiolate, usually rosulate, entire, dentate, or pinnately divided.

通常，具叶柄的基生叶，全缘，配位基，或成羽状裂。

Background and Objective: The basic structure of salicylaldehyde amino acid Schiff base compounds includes a C=N chemical bond.

背景与目的：水杨醛氨基酸Schiff碱基本结构中含C＝N键，当基与金属离子配位后生物活性增强，表现出一定的抗癌、抑菌等活性。

The calcination and presence of adsorbed phases could lead to rearrangement of Si species in framework, and reaction of MTH aggravates desilication of the SAPO molecular sieves framework.

通过2D〓Al 3Q MAS NMR区分了多种不同配位状态的Al物种，动态跟踪了Al物种在吸附/反应过程中的变化情况。

The reactions of pyridine-2-carbaldehyde semicarbazone with transition metal Ni(II,Cosalts afford two pyridine-2-carbaldehyde semicarbazone transition metal compounds.

配合物[CoL2]·(ClO4)2·H2O(3)，分子式C14H18Cl2CoN8O11，Mr=604.19，属三斜晶系，空间群P-1，晶胞参数：a=9.984(3) A， b=11.082(4) A， c=12.196(5) A ，Dc=1.769Mg/m3，α=112.954(4)°，β=110.050(4)°，γ=94.017(3)°，V=1134.4(7) A3， Z=2，μ=1.067mm-1， F(000)=614，结构偏离因子R=0.0501 和ωR=0.1028，配合物(3)的中心金属离子采取六配位的变形八面体。

We suggested that a coordinate linkage should forms between the surface of skutterudite and a top of PAn chains based on the analysis of infrared spectra.

由复合材料红外光谱的蓝移及N-H红外振动模强度的变化提出了聚苯胺分子与方钴矿表面可能存在配位键的假设，很好地解释了实验中的现象。

A mode of the directionally growth of PAn on the surface of NaFe〓P〓rod-like particle was suggested. Some of aniline molecules in the reactants are fixed on the surface of skutterudite particles before the beginning of the polymerization. Other aniline molecules link with the aniline molecules fixed on the surface of skutterudite and form liner chains when the initiater is added into the reactants.

提出了聚苯胺在棒状方钴矿NaFe〓P〓材料表面定向生长的物理化学模型：在表面配位键的作用下方钴矿晶须表面首先附着了一层苯胺单体，在引发剂的作用下溶液中的苯胺分子在这层单体上定向聚合，形成了定向聚苯胺线性分子。

The binding interaction of DNA with the di-iron complex 〓, designed as a model for the di-iron active site in mammalian purple acid phosphatase , are examined firstly and spectroscopically.

对所有研究的含有双核铁、双核锌及双核铜的配合物促进DNA双链水解断裂的反应性进行比较，我们发现要有效地水解断裂DNA双链，对DNA骨架的磷酸基氧原子有一定配位作用的双核金属离子是必要的，因为两个金属离子间存在协同作用，这与有关的天然酶类似。

The results show that the zirconium sol has good spinnability when n: n= 1:3, reaction time is 6h and aging temperature is 15℃. The ZrO_2precursor fibers are made from hydrous zirconia chelated by acetylacetone. The sintercd fibers arecomposed of metastable tetragonal phase and sized about 15μm in diameter. Moreover, there aremany pores inside the fibers, but no cracks.4. ZrO_2/PVP hybrid fibers were prepared by blending the spinnable zirconium sol and 10 wt%PVP solution.

结果表明，当n(ZrOCl_2·8H_2O)：n(H_2O_2)=1：3，反应时间6h，陈化温度15℃时可得纺丝性能良好的锆溶胶，ZrO_2前驱体连续纤维的组成主要为经乙酰丙酮配位的ZrO_2水合物，热处理后的ZrO_2纤维的相结构为亚稳四方相，纤维的直径为15μm左右，纤维中存在大量的纳米级气孔，但无明显裂纹。4。

Fibrous hydrous zirconia, spinnable hydrous zirconia chelated by acetylacctone and modifiedhydrous zirconia were synthesized from zirconium oxychlorid(ZrOCl_2·8H_2O) and then applied toprepare ZrO_2/PVA electrospinning hybrid fibers, ZrO_2/PVA continuous hybrid fiber and ZrO_2/PVPhybrid microsphere respectively. The chemical structure, properties, microstructure and formationmechanism of the corresponding materials were investigated.

论文以无机盐ZrOCl_2·8H_2O为原料，合成出纤维状的ZrO_2水合物、乙酰丙酮配位的可纺性ZrO_2水合物和正丁醇改性的ZrO_2水合物，分别与PVA和PVP杂化复合，制备出ZrO_2／PVA杂化电纺纤维、ZrO_2／PVP杂化连续纤维和ZrO_2／PVP杂化微球，并对相关材料的组成、结构、性能及形成机理等进行了深入分析和研究。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。