配位

AIM:To study the therapeutic effect of Diammonium Glycyrrhizinate lipid ligand on alcoholic fatty liver.

目的 ：观察新一代甘草酸制剂甘草酸二铵脂质配位体对酒精性脂肪肝的治疗作用。

In the thesis, we also present atomistic molecular dynamics simulations of the growth of diamondlike films via low-energy Carbon atoms deposition on Si (111) substrate.

10eV沉积，沉积的C原子有不少和衬底Si原子发生成键，但膜中3C配位的C原子含量仍很高，说明10eV沉积，膜与衬底间的结合性有所改善，但膜中石墨微结构仍大量存在。

As compared to isop, the coexistence of electron-donating -OH,-C(CH_3_3 or electron-withdrawing groups (-NO_2) groups in the dicarboxylate derivatives has a significant effect on the molecular self-assembly.

同间苯二甲酸相比较，含有取代基的5-羟基间苯二甲酸、5-硝基间苯二甲酸和5-叔丁基间苯二甲酸在一定程度上影响着配位聚合物的自组装。

For this pyrolysis, cadmium acetate dihydrate and sulfur powder were used as the cadmium source and sulfur source, respectively.

以三辛基膦为单一配位溶剂，二水合乙酸福和硫粉为前驱体，用高温热解的方法制备CdS纳米棒。

Quantum chemical calculations were performed based on these conformations to explain the experimental data. 4. The molecular recognition of the chiral Salen Fe complexes towards imidazole derivatives and the measure of the equilibrium constants of host-guest system of the Salen Fe and EMIm a.

用紫外-可见光谱滴定法考察了不同主体Salen-Fe对咪唑及其衍生物的分子识别行为，测定了识别过程的平衡常数和热力学参数，讨论了影响主客体配位能力的有关因素；系统地考察了主客体缔合反应的圆二色光谱性质。

When methoxyethanol was used as the solvent,tantalum ethoxide can be chemically modified with acetic acid to producetantalum alkxo-acylate precursor, and therefore the hydrolysis of 〓can be slowed down.

在以乙二醇单甲醚为溶剂时，乙醇钽与醋酸作用生成乙醇钽的乙酰基配位化合物，可以减弱水解反应的进行。

Glutin or chitosan salt is taken as the matching template.

用明胶或甲壳胺盐作为配位模板。

The structure was characterized by elemental analysis and IR spectroscopy as well as thermal gravimetric analysis.

对该配位聚合物进行元素分析、红外光谱表征、热重分析和X-射线单晶衍射测定。

These compounds are of substantial interest both inviewpoints of theory and practical applications, mainlyunder the stimulus to achieve synthetic models either foractive sites of iron-sulfur proteins or for transitionmetal catalysts. This thesis describes the synthesis, structures andconformations of 51 new iron-sulfur cluster complexes,which have been characterized by elemental analysis andstandard spectroscopic methods. In addition, single-crystalX-ray diffraction analyses were performed for 4 representa-tive new compounds. Reactivities of μ-〓 with mono- and di- Grig-nard reagents derived intermediates toward various organicelectrophilic substrates were studied, along with complexa-tion of arynyl-containing iron-sulfur clusters by 〓Thus, several bridged, non-bridged, monomeric, dimeric,homonuclear, heteronuclear iron-sullfur and iron-sulfur co-balt-carbon cluster complexes were synthesized. A novelreaction and convenient route for the synthesis in highyield of tetranuclear iron complexes 〓 containing atetracoordinated sulfur atom was discovered, whereas aplausible mechanism based on experimental results was propo-sed for the formation of the new cluster type.

鉴于有机铁硫原子簇化学在基础理论发展和应用方面的重要意义，因此我们开展了这一课题的研究，并取得以下主要成果： 1、本文共合成了51个新有机铁硫及含钴碳簇基的有机铁硫原子簇配合物，除用元素分析，NMR，IR，MS法表征其结构和构象外，还用X-光衍射技术测得四个代表性配合物的单晶结构和构象； 2、我们业已发现炔基Grignard试剂同〓可形成一种&开环&与&闭环&中间物的平衡混合物，研究该平衡混合物同各种亲电试剂的反应； 3、研究发现了一种可高产率地形成〓含〓四配位硫挛合簇的新化学反应并对此反应提出了—种有趣的反应机理； 4、首次由1，4-二溴丁烷双Grignard试剂与〓制得一种新型铁硫簇双硫阴离子活性中间体，并进而研究了它的亲核反应性能； 5、找到了通过〓的光化学反应来合成簇合物〓-〓的一条有实用价值的新路线。

Studied the coordination chemical reaction of Fe、Co、Ni、Cu、Mg、Ca、Al with TC,OTC,CTC and the ternary association of Co-OTC、Ni-CTC with DAN,we found that the formation of new compounds improved significantly the hydrophilic properties of TCs,the TCs are transformed into hydrophobe from hydrophilic matter.

2研究了Fe、Co、Ni、Cu、Mg、Ca、Al与TC、OTC、CTC之间的配位化学反应和Co-OTC、Ni-CTC与DAN之间的三元缔合作用，发现新化合物的形成显著改善了TC、OTC、CTC的亲水性能，使其由亲水物质转变为疏水物质，有利于提高亲水有机溶剂气浮浮选体系对水样中痕量四环素类抗生素的测定灵敏度和分离/富集效率。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。