配位

Then, inhibition mechanism and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles and quaternary ammonium salts are studied from microscope through quantum chemistry calculation, and according to the results, theory predicting and proof testing of a benzene nitrile (2-benzo butyl nitrile) are made.

利用Hansch关系的研究结果表明，苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀效率，可用苯腈类化合物氰基氮原子的净电荷密度和分子最高占据轨道能量或分子最低空轨道能量构成的表达式表达。量子化学计算研究结果表明：1、苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀机理可能是：苯腈类化合物分子以其氰基氮原子上的电子提供给铁的3d空轨道，形成配位键；同时铁的3d轨道上的电子提供给苯腈类化合物分子的能量最低空轨道，形成&反馈键&。

Five new polysiloxane-platinum complexes ("Si-Pt-1"-"Si-Pt-5") have been prepared by reaction of chloroplatinic acid with various silica-supported polysiloxanes(1-5) bearing ligand group CHC6H4N(CH3)2, CHC6H4OH,- N(OC-CH3)2,-CN and - COOH.

以二氧化硅为载体的侧链上含有配位基团和-COOH的聚硅氧烷(1-5)分别与氯铂酸反应制备了五种聚硅氧烷-铂络合物(&St-Pt-l&—&St-Pt-5&)。

According to the existing hours of this lesson, we mainly explain rudimentary knowledge relevant to inorganic chemistry, including colligative property of diluted solution and four balances (Acid-base equilibrium, precipitate-dissolve equilibrium, oxidize-reduce equilibrium and coordinate equilibrium) and two structures (atomic structure, molecular structure ).

从而为后续分析化学，有机化学，物理化学及相关专业课程的学习打下必要的基础。因此，根据现有的实际课时数，主要讲解有关的基础知识。包括稀溶液依数性和四大平衡(酸碱平衡，沉淀-溶解平衡，氧化-还原平衡，配位平衡)，二大结构。

Puertin is representative of isoflavone compounds. To study the mutual reaction between puertin and Cu, Ca, Fe, Zn, Al, and Mg which exist in Pueraria, methods of conductometric titration, spectrophotometry. and pH-potentiometric titration is used.

以葛根素作为异黄酮类化合物的代表，用电导法、分光光度法、pH电位法研究葛根素与葛根中含量较多的微量元素Cu、Ca、Fe、Zn、Al、Mg在水溶液中的配位作用，计算了金属配合物的稳定常数。

Concentrations of free copper and mucus and other parameters including pH and alkalinity of the gill microenvironment of Cyprinus carpio exposed to copper of various levels were determined using Playle's apparatus.

利用 Playle设计的装置测定了不同铜暴露水平下鲤鱼鳃部进出水中的游离铜离子浓度、粘液含量及有关参数。用MINTEQA2和单配位体模型联合的试算方法计算了不同形态铜含量以及鳃部粘液对铜的络合能力。

Leaf blade to 9.5 cm, margin distinctly denticulate to dentate, teeth to 2 mm; corolla ca.

叶片给9.5厘米，边缘明显去配位基的具小齿，齿在毫米；约的花冠1.8厘米；花丝4-5毫米；茎可达40厘米 3c var。

Margin of valves long dentate, dentate, or denticulate.

裂片边缘长配位基，具牙齿，或具小齿。

The effects of ,, and temperature on the distribution ratio have been investigated. The composition of the extracted species is determined by the methods of slope ratio, continuous variation,extraction isotherm curves and their chemical analyses. The extraction is found to proceed according to the reaction:AuCl_4 ~-+DEOTA_(0)TAuCl3 .DEOTA_...

着重研究了盐酸浓度、氯离子浓度、氢离子浓度和温度诸因素对萃取的影响；对有机相中金的反萃行为也进行了初探；通过斜率法、等摩尔系列法、萃取等温线法确定了配合物的组成；推定了DEOTA在盐酸体系中萃取金的机理为配位取代反应；计算了萃取反应的表观平衡常数和配合物的稳定常数。

He order of promoting the slag desulphur capacity of them from large to small is: Ti〓, Ca〓, Al〓, Mg〓.

i〓的作用要大于其它四配位离子并且还有促使Si和Al〓增大表面粘度的作用。

The azacrown ether complexes are formed by coordination of azacrown ether and metal ion, the azacrown ether is 1,12-diaza-3,4,9,10-dibenzo-5,8-diazacyclopentadecane-N,N'-diacetic acid, the metal ion can be any one of Cu2 , Ni2 , Co2 or Zn2 and so on.

所述氮杂冠醚配合物为氮杂冠醚与金属离子配位而成，氮杂冠醚为1，12-二氮杂-3，4，9，10-二苯并-5，8-二氮杂环十五烷-N，N'-二乙酸，所述金属离子可以为Cu 2 、Ni 2 、Co 2 或Zn 2 等中任一种。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。