配位

Due to their applications in magnetic, optical, electronic and catalyst, polynuclear lanthanide clusters are of importance. In this part, a series of nanowheel-shaped nonanuclear lanthanide clusters,〓〓(Ln=Sm~Tm; BA=benzoylacetone), were prepared and characterized. Each complex can exist in three phases, i. e., cubic, tetragonal and triclinic.

本论文第二部分在醇溶液中以三乙胺调变溶液pH，利用β-二酮配位方式的灵活性成功地构筑了一系列结构稳定、纳米尺度轮状的九核稀土配合物〓〓（Ln=Sm~Tm；BA=苯甲酰丙酮），并在不同溶剂中重结晶分别得到了三斜、四方以及立方三种晶型的晶体。

In the compound 2, the Co ions are five-coordinated in trigonal bipyramidal geometry.

而在化合物2中，Co离子是五配位三角双锥几何体。

Each metal is nine-coordinated and formed tricapped trigonal prism geometry.

每个金属离子都是9配位形成三冠三棱柱的几何构型。

Both endo-cyclic and exo-cyclic tin atoms are five-coordinated and have coordination geometry of distorted trigonal bipyramid.

内环锡和外环锡原子均为五配位的畸变三角双锥构型。

Adsorption mechanism of uranyl ion (UO22+) on this polymer was studied with IR spectra and by means of the adsorption behaviors of compounds of similar structure.

为了探索吸附机理，本文用类似结构的化合物作吸附铀的对比和从红外光谱均可看出，吸附剂的各配位基在同铀的配合中，表现出明显的协同作用。

Three heteronuclear uranyl complexes were obtained via hydrothermal reaction, too.

另外，在水热条件下，还利用这些芳香有机酸合成了三个铀的异核金属配位聚合物，这为铀的异核金属配合物家族增添了新的成员。

Selection of surfactant, fluid carrier, in water phase and membrane solvent in EML technology was discussed.

探讨了乳状液膜工艺中的表面活性剂、流动载体、内水相与膜溶剂的选择，pH值、乳水比、搅拌速度、温度、操作时间及配位效应的最佳工艺条件的确定。

For the metal-oxygen clusters containing tungsten, the pyrolysis procedure of potassium salt with [P2W18O62]6-anion is similar to that of metal-oxygen clusters with [P2Mo18O62]6-anion, whenas the NH4+, Cu2+salts of [P2W18O62]6-seem to decompose directly into WO3 at 400 ℃, 450 ℃,respectively.

以钨为配位原子的钾盐在410 ℃也有相似的行为，但铵盐和铜盐却没有观察到类似的热重排现象，分别在400 ℃， 450 ℃直接热分解为WO3。

Which is made up of long carbon chain by N-alkylation or acylation,The surface activity is greatly enhanced because of structure of borate surfactants and the basic property of long carbon chain.

它们将长碳链通过N烷基化和酰化联接在一起的一类含硼表面活性剂，由于是含四配位硼氧杂环结构的表面活性剂和结合长碳链的基本性质从而极大的提高了表面活性。

From the results of IR and XPS spectrocopy. The cationic sol components H〓SiO〓 and 〓 of the solution trend to adsorp on the surface of electronegative aegirine because of electrostatic acctraction each other, and interrupted the collector's reaction with Fe〓 on the surface. Hence the flotation of aegirine was decreased, on the other hand, there is electrostatic repulsion between the surface of hematite and the cationic sol H〓SiO〓.〓, Which has advantage to dispersion of hematite particles, therefore, the hematite flotation is achieved sucessfully with anionic collector.

根据红外光谱和XPS测试结果可知，在弱酸性介质中，活性硅酸胶体抑制剂中荷正电的胶团H〓SiO〓及〓由于电性吸引而选择性地覆盖在荷负电的钠辉石表面，从而阻碍了阴离子捕收剂与表面Fe〓的配位作用，导致钠辉石的浮游被抑制；而赤铁矿表面由于荷正电，与矿浆中的H〓SiO〓、〓等硅酸胶团存在着电性排斥作用，有利于赤铁矿颗粒的稳定分散，所以赤铁矿能够被脂肪酸捕收剂吸附而选择性上浮。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。