配位

It crystallizes in the monoclinic space group C2/c, with a=1.6953(3)nm, b=1.9241(4)nm, c=1.7760(4)nm,β=94.75(3)°. Each Gd ion is coordinated by two oxygen atoms from two different radicals NITPh(OCH3)3 and six oxygen atoms from three hfac molecules to form eight-coordinated dodecahedron geometry.

Gd离子采取八配位的模式，两个氮氧自由基作为单齿端基配体分别以氮氧基团的氧原子与Gd离子配位，三个六氟乙酰丙酮阴离子分别以两个氧原子与Gd离子配位，构成十二面体。

It isconfirmed by ~1H NMR,~(13)C NMR and X-ray crystallographic analysis that complexes 60-63are monopyridine complexes and show distorted square pyramid geometries; complexes 64and 65 are bispyridine complexes and show pseudo-octahedral geometries, where twopyridine ligands are in cis arrangement and trans to the NHC and the benzylidene ligandrespectively, the bond length between ruthenium and pyridine ligand trans to the benzylideneligand is 16 pm longer than the bond length between ruthenium and pyridine ligand trans tothe NHC ligand.

1H NMR、~(13)C NMR及X射线单晶衍射分析证明，配合物60-63是单吡啶衍生物配位的钌卡宾配合物，具有变形的四方锥构型；配合物64、65为双吡啶衍生物配位的钌卡宾配合物，具有变形的八面体构型，其中两个顺式配位的吡啶衍生物分别处于氮杂环卡宾和苯亚甲基的反位，处于苯亚甲基反位的吡啶衍生物对应的钌-氮键长要比处于氮杂环卡宾反位的长出16 pm。

From the structural analysis of three praseodymium complexes, we could draw a conclusion that as the dentate arms of carboxyl group on ligands elongating, the coordination numbers of Pr and the coordination modes of ligands increase, and the mean distances between metallic atoms of metallic helices existing in these complexes augment.2. By altering 5-substituting group of isophthalic acid three series of lanthanide complexes 8～19 with 5-methylisophthalic acid and 5-nitroisophthalic acid have been prepared.

从得到的三个配体的镨配合物的结构分析可以看出，随配体的羧基齿臂的增长，Pr的配位数逐渐增大，配体的配位模式增多，配合物中存在的螺旋金属链中的金属间平均距离增大。2、通过改变间苯二甲酸配体的5位取代基，制备了5-甲基间苯二甲酸和5-硝基间苯二甲酸的三个系列稀土羧酸配合物8～19。

Furthermore, the one-dimensional complexes 26 and 28 with strongπ-πpacking interactions are prepared from DMF solvent, which indicates that the traditional solvent volatilizing method could bring low-dimensional complex.4. By measuring the enthalpy changes of the liquid phase formation reaction for complexes a~e, and calculating the electronic densities of five 5-substituted derivation of isophthalic acid, we can make a conclusion that 5-substituted group changing of the ligand has a little influence on oxygen atoms of carboxyl groups.5. Fluorescence experiments of these complexes indicated that they could be used for luminescence materials in future.6. Using packing saturation rule we calculated and analyzed these series of complexes, and the results showed that the changes of complexes with changes of ligands could be explained from the rule.

在DMF溶剂中得到了具有强π-π堆积作用力的一维配位聚合物[Ln(5-NO_2-bdc)(NO_3)]Ln=Pr(26和Ho(28)，表明传统的溶剂挥发合成条件可以得到低维的配合物。4、通过配合物a～e的液相生成反应焓的测定，以及配体阳离子的电子密度计算，进一步佐证了间苯二甲酸的5位取代基变化对配体的羧基氧原子配位能力影响不大的结论。5、荧光特性表明此类配合物可以用于发光材料。6、利用堆积饱和规律对所得系列的配合物的进行计算和分析，发现随着配体的变化，配合物的变化可以从堆积饱和规律出发进行解释。

The X-ray crystal structure analysis of the complexes shows that all lanthanidecomplexes exhibit a tripodal ligand coordination mode, with three imino nitrogenfrom benzimidazolyl and pyridyl group, and one amino nitrogen atoms as donors.The ligands show two kinds of configuration: the fan-like and the pincer-like. Bothintra- and intermolecular π-π interactions are found in these complexes.

晶体结果表明，在所有的稀土配合物中，三脚架配体均用三个支脚上的苯并咪唑、吡啶环氮原子及一个顶端的氮原子和稀土离子进行配位，表现出三脚架式配位方式，同时，三脚架配体有风扇形及钳子形两种空间配位构型，并形成了分子内及分子间的π-π堆积作用。

It follows that the de-protonic reaction of hydroxide group for PVA had taken place in above solution, and the coordination group for deprotonic oxygen of PVA had produced more. These ligands interact with some Fe3+ of ferric hydroxide while the ferric hydroxide in new emergence is forming,causing the formation of Fe-PVA coordination polymer-the composition of the reddish brown resinoid substance.

推定PVA部分羟基在上述条件下发生脱质子反应而提供L-配位体，Fe盐水解生成初生Fe3的Fe3+，它既有空轨道，又有较强的正电场，故能吸引PVA高分子配位体L-上的氧而形成O→Fe配位键，从而发生L-与Fe3+离子间的交联反应，生成多核Fe-PVA配位聚合物而析出红棕色树胶状物。

The crystal consists of two similar but independent molecules in the asymmetric unit and the Ce ion coordinated toward ten donor atoms, six of which belong to the nitrogen atoms of two tridentate ligands and four oxygen atoms from two bidentate picrates.

晶体中一个不对称单元内有两个结晶学上独立的分子，这两个分子的构型基本相同，中心Ce3＋均与两个三齿配位的配体及两个双齿配位的苦味酸根配位，配位数为10。

The results indicated that: Tripyrazolone, tripodal and crptands ligand L〓, L〓 and L〓 have good coordination ability with rare earth ions Rare earth ions were coordinated with their oxygen and nitrogen atoms.

结果表明，三脚架结构吡唑啉酮、三酸和穴醚配体与稀土离子有较好的配位作用，它是通过氮原子、氧原子与稀土离子配位的。而穴醚配体与稀土离子配位效果却不好。

As the distances between coordination sites of auxiliary ligands increasing, the distances between adjacent two-dimensional [Er(5-NO_2-bdc)_2]~- anion layers enlarged. As the bulks of auxiliary ligands largening, the coordination configuration of Er optimized and the dimensions of coordination polymers increased.

增大辅助配体的配位点之间的距离，增大了二维[Er(5-NO_2-bdc)_2]~-阴离子层之间的距离；增大辅助配体的空间位阻，优化了金属离子的配位几何构型，使配位聚合物的维度增大。

The central 5, 5'-disubstituted bipyridine units of each ligand coordinate theNi or Fe ion, while all the terminal 6-monosubstituted bipyridine units of the ligands keep free of coordination, as the result trinuclear triple-stranded helicate 〓 can not form. This is considered to be caused by the steric hindrance of the methylene substituents α to the chelating nitrogens of the terminal bipyridine units and the strain caused by linkage mode.

配体L〓与Ag作用得到〓，两个配体链相互缠绕着两个Ag离子周围形成双股螺旋结构并以头尾式排列(见图3)，由于配体中位于配位N原子α或β位的末端甲基或次甲基取代基的空间位阻阻碍了头对头式异构体的形成，也正是由于配体头尾式排列而使Ag双股螺旋得以形成，这一结果表明该螺旋体的组装过程中自发地采取了空间阻碍尽可能小的那个构型。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。