配位

Therefore, the energy of π(superscript *) orbit decreases, the probability of optical absorption increases, the n→π(superscript *) electronic transition enhances, and the absorption band broadens and shows red-shift. The above phenomenon will result in the degradation of optical properties of ZnO/silicone white paint under proton exposure.

同时Si-O-Si链内氧原子未成键的孤对电子与邻近硅原子的3d空轨道配位，降低了π轨道的能量，提高了对光吸收的几率，增强了n→π电子跃迁，使吸收带红移，从而导致ZnO/silicone白漆光学性能退化。

Under optimal conditions, oxidation of ethylbenzene into acetophenone under 1 atm O2 and 1 mol% NHPI reach to 64% yield.

在最佳的催化状态下，苯乙烷能在1 atm的氧气、1 mol% NHPI与轴向配位基为吡啶的紫质修饰二氧化钛共催化下，氧化成苯乙酮，并得到64%的产率。

The effect of the molar ratio of amino acid to copper,microwave power,reaction time and pH value on chelate reaction was investigated.

采用微波螯合工艺，对复合氨基酸与铜的配位比、微波时间、微波功率及反应体系的pH对螯合反应的影响进行详细的研究。

The magnitude of the values shows the order of acrylonitrile

讨论了这些体系的电化学-配位反应机理。

In addition,the reaction of osmanaphthalene with different kinds of ligands gave new osmanaphthalenes.

最后研究了CO和不稳定的卡拜副产物的反应，得到CO配位的锇乙烯基化合物。

But in the + moiety, the three benzimidazole rings shared the whole space equally, the dihedral angel among them is about 120°, just like three fan blades of an airscrew, the molecular structure appear gear-like shape.

X-射线单晶衍射测试、红外、紫外等方法确定了三(2-苯并咪唑亚甲基)胺的Fe和Co配合物的结构，由晶体结构发现金属配位情况不同、配合物在结构上存在着差异，Fe为八面体构型，而Co为三角双锥构型；其次，两配合物中的苯并咪唑环间夹角不同，配合物中包含N2和N4的两个苯并咪唑环间夹角仅为9.41(0.11)，几乎构成一个平面，呈蝴蝶形；后者Co三个苯并咪唑环几乎平分了整个空间，它们之间的夹角约为120，呈三扇叶螺旋桨式构型，为齿轮形。

An algebraic expression consisting of three terms connected by plus or minus signs.

由一个金属离子与两个或两个以上非金属离子构成配位键的过程。

It was found that solvent pyridine plays an important role in the formation of nanocrystalline nickel selenides due to its appropriate coordinative ability and alkalescence.

又在50℃的温度下，在吡啶溶剂中以水和肼为还原剂，得到了Ni〓Se和NiSe〓，纳米晶溶剂吡啶由于具有合适的配位能力及碱性而在反应中起了关键作用。

CALORIMETRIC TITRATION FOR COORDINATION REACTION OF 2, 3-BENZO-8, 11, 15-TRIMETHYL-18-CROWN-6 WITH ALKALI AND ALKALINE EARTH METAL IONS

若干碱金属及碱土金属离子与2，3-苯并-8，11，15-三甲基-18-冠-6配位反应的量热滴定研究

Arenedisulfonates have much stronger coordination ability to alkali, alkaline earth than to transition metal ions.

芳烃二磺酸根离子与碱金属离子和碱土金属离子的配位能力比过渡金属离子强。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。