配位

In addition, Me N-Pd distance of 12c (2.080--2.083 A) is shorter than that of 15c (2.159 A).

说明二聚体中N和Pd的配位作用较强；12c中Pd和羟基O的距离为4.226？

Because of the property of donative electron of the methoxy group and the participation of the carbonyl group of the coumarin into the complexation proces...

研究表明，由于在香豆素的6 位上引入一个甲氧基，对应的主－客配合物的稳定常数较（7－甲氧基－4－亚甲基）香豆素基－单氮杂－ 18－冠－6（ MMC－ MAC（O5））与阳离子配位的稳定常数又有所增高。

The formation of martensite is accomplished by the immigration of well-defined glissile interface (121)fcc type and its misfit dislocations can produce the lattice invariant deformation on the basis of phenomenal theory of martensitic crystallography, however, LID is retarded slightly after the migration of interphase (121)fcc, i.e.a thin plate-like zone exists without LID in martensite near the well-defined interface. When the temperature reduces to the Ms point, the lattice parameter of austenite matrix is √3/2 times that of the martensite without LID. This critical condition for spontaneous transformation agrees with that the stack fault energy in matrix is less than zero according to Olson and Cohen's nucleation model.

通过模型分析表明：fcc/bcc马氏体形核与长大过程是通过(121)fcc型择优界面推移进行的，界面上的错配位错可以完成马氏体晶体学唯象理论要求的点阵不变变形，但LID要稍滞后于界面迁移，即在马氏体形核与长大过程中推移界面新相一侧存在一未发生LID的新相薄区；当相变温度达到马氏体相变点Ms时，母相奥氏体与这一薄区的晶格常数比为√3/2，这一几何条件和Olson-Cohen形核模型中要求扩展位错层错区界面能γ≤0是等价的。

It is found in this study that in the TiAl-based composite with addition of boron, there is a new phase of Ti〓B which has a base-centered orthogonal structure and a space group of Cmmm.

当取向差为正时，在（110）面上每隔14个[1〓0]点阵矢量产生一个界面错配位错；当取向差为负时，在（010）面上每隔15个[100]点阵矢量产生一个"锁位错"。

After thehexa-coordinate phosphorus intermediate formed, the phosphoryl N→Omigration reaction would have the lowest activated energy and should be themain reaction.

六配位磷中间体形成之后，继而发生磷酰基的N→O转位反应的活化能非常低，所以它是主反应。

But under the same conditions, the reactions of the complex (41) with organic lithium reagents give a kind of novel complexes in which the nucleophile is added to the a-carbon of the phthalazine ring.

然而含有桥羰基的2，3-二氮杂萘配位的羰基双铁络合物4l在相同的条件下与芳基锂试剂反应时，芳基锂却是亲核加成在氮杂环的α位羰上，生成一类结构独特的双氮双铁羰基络合物。

In addition, the relationship between the structure and the third-order nonlinear properties of this complex is discussed.

探讨了配合物的结构和其三阶非线性光学性质的关系，认为配位化合物的丌共轭离域体系的增大和金属中心离子与配体之间的电子转移是配合物具有更大非线性折射率的主要原因。

Two coordination polymers [Pb6(H2O)24]·3H2O(1)(H3cit=citric acid)and Pb(H2O)2(2)(tar=tartaric acid)were synthesized under hydrothermal conditions and characterized via IR,TG-DTA,C,H,N elemental analysis,XRD and single crystal X-ray diffraction analysis.

在水热条件下，合成了2个含柔性配体柠檬酸和酒石酸的二价铅配位聚合物[Pb6(H2O)24]。3H2O(1)(H3cit=citricacid)及Pb(H2O)2(2)(tar=tartaricacid)。用红外光谱、差热-热重、元素分析、粉末X射线衍射及单晶X射线衍射等手段对化合物进行了表征。化合物1属三斜晶系，P1空间群，a=0.97053(19)nm，b=0.9764(2)nm，c=1.0955(2)nm，α=109.016(3)°，β=98.380(3)°，γ=92.136(3)°，V=0.9671(3)nm3，Z=2，R1=0.0420，wR2=0.1049，GOF=1.064。

The regularities of the substitution effects of the electron-pushing group and the electron- withdrawing group on the electronic structures and the related properties of the complexes, e.g. the energies and the compositions of some frontier molecular orbitals, the spectroscopy properties, the atomic net charge populations on main ligands, the coordination-bond lengths and the coordination-bond angles of the complexes, etc. have been investigated.

探讨供电子基团和拉电子基团在主配体上的取代对配合物的电子结构及相关性质，如配合物前沿分子轨道的能量、组成、光谱性质、原子的净电荷布居及配位键长键角等的影响规律。

As support, Agarose can benot only used in normal condition, but also in denaturalization (for example, 6 mol/Lhydrochloric acid carbamidine or 8 mol/L urea). Herein, the preparation of IMACmatrixes were conducted using agarose as support, carboxymethylated aspartate as chelating ligand and Co~(2+) and Ni~(2+) as chelating center ions.

本实验用琼脂糖作为基质，选用四配位，与金属离子有较强作用力的羧甲基天冬氨酸为配基，以Co~(2+)、Ni~(2+)作为螯合金属离子，合成了一系列金属螯合亲和色谱填料，并对其蛋白质分离性能进行了研究。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。