配位

The formation constants and enthalpies of coordination reactions were calculated using computer program made by ourselves.

借助计算机用自编程序算出了配位反应的生成常数和焓变，进而算出了配位反应的自由能变化和熵变化。

In some extraction system, it is proved that water may coordinate the extracted complex in equilibrated organic phase.

本文对萃取平衡数据的分析结果表明在一些萃取体系中存在水与萃合物的配位，并提出了萃合物配位水数的求算方法。

It is set forth that the symmetry of coordination anions in crystals is coincident with that of morphology if the boundaries of unit cell are divided with the faces,edges and angles of anionic coordination polyhedrons.

提出晶胞界线是以负离子配位多面体的面、棱和角为界面而划分的；晶体中负离子配位多面体的对称性与晶体形态的对称性是对应一致的。

The coordination reactions of Cu and Ni with acid alizarine blue B in the presence of cetyltrimethylammonium bromide micelle were investigated using the microsurface adsorptionspectral correction technique. The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu or Niand AABB.

应用微相吸附-光谱修正技术，研究了Cu、Ni与酸性茜素蓝B在溴化十六烷基三甲铵胶束上的配位反应，分析了表面活性剂在配位反应中的增效机理，表征了二元和三元结合物的性质。

In terms of the obtained values of parameters, it is demonstrated that the covalency of the bonding between Mn〓 and ligands in SrTiO〓: Mn〓 is stronger than the one of the bonding between Cr〓 and ligands in SrTiO〓: Cr〓.

通过分析得到的常压参量值，揭示了在SrTiO〓：Mn〓中Mn〓与配位体之间的共价作用比SrTiO〓：Cr〓中Cr〓与配位体之间的共价作用更强。

Based on thermal analyses, thermal decomposition mechanisms were predicted that at the first step the polymer lost two coordination water molecules and at the second step lost two formates companied by the formation of some kinds of materials.

根据热分析，推测该配位聚合物的热分解机理为：在第一步失去两个配位水，在第二步失去两个甲酸根并伴随着某种残余物质的生成。

The complexes areneutral as shown by values of molar conductivity in aqueous solution, namely,〓 The crystal structure determinations show that, in complexes, metal ions werecoordinated by four nitrogen atoms and form slightly distorted square planar configuration,relationship between fluorene ring plane and coordination plane is similar to those betweenpeptide planes of β-folding in proteins. The complex molecules linked by hydrogen bonds formone dimension chain or two dimension network structure.

摩尔电导测定表明他们都是二氧四胺中酰胺氮去质子化后形成的产物。X-射线衍射晶体结构测定表明〓的铜、镍配合物的配位多面体都是稍微畸变的平面正方形，配合物分子中芴基平面与配位平面的关系类似于蛋白质β-折叠结构中肽平面之间的关系，配合物分子之间通过氢键连接成一维链状或二维网状结构。

Complex Ho and complex La lose solvated THF in thetemperature range of 28-156℃, 28-128℃, respectively.

钬配合物和镧配合物的热失重分析表明，配合物含有1份配位的THF，并且在较低的温度区间失去其配位的溶剂。

The coordinated COD of 3 and 4 can be replaced by carbon monoxide to yield the corresponding dicarbonyl species [(C,N-pyN^C-R) M2]BF4 (14, M= Rh; 15, M= Ir). Ligand substitution of 11a by phosphines and azide causes the de-complexation of pyridinyl-nitrogen donor to generate the corresponding carbene rhodium complexes [(C-pyN^C-Mes)RhPR3] (17a, R = Ph, 17b, R = Et) and [RhN3] (19), respectively, indicating the labile nature of steric-hindered pyridinyl-nitrogen donor.

螯合错合物的吡啶配位，可以容易被σ-予体，如卤离子、叠氮阴离子、膦试剂，置换；但是铑与铱金属螫合物与π-酸试剂，如一氧化碳、异腈，则发生COD被置的产物14a与16；与三甲基亚磷酸酯反应时，COD及吡啶均会被取代而得到单芽的三铑-碳烯错合物18；双膦化合物则会取代铑金属上全部的配位基。

This chapter discusses the "complementarydistribution" on the basis of the arrangement of argument structure and theta structure. It isthe arrangement rules that cause the phenomenon of "complementary distribution".

针对动结式在把字句和重动句中的分布存在互补规律的现象，用前文总结出来的配位规则进行分析和验证，表明这种&互补&现象背后隐藏的真正动因仍在于这种配位规律。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。