配位

The recent progresses in the study on the fluorescence of rare earth complexes and application for the determination of the rare earth elements and organic compounds, as fluorescent probes for bioactive materials analysis and as detection means in separation technology were reviewed in detail. In chapter two, the absorption spectra of the 4f electron transitions of the complexes of the neodymium, praseodymium, holmium and erbium with fleroxacin in the presence of CPC have been studies by normal and derivative spectrophotometry.

本文以稀土元素配位化学为基础，以导数吸收光谱技术和荧光光谱技术为研究手段，利用新一代喹诺酮类抗菌药物，抗凝血类杀鼠药物的化学结构特点和大环化合物冠醚与金属离子突出的配位能力，以分析应用为目标，系统研究了这些化合物同稀土元素形成的配合物的光吸收和荧光特性，通过对体系实验条件的优化，使体系的稳定性、选择性和灵敏度得到显著改善。

Crystal analyses reveal that the Nickel is coordinated by six oxygen of water with distorted octahedron environment.

晶体分析表明镍与6个水分子的氧原子配位形成畸变的八面体构型，其中H2O(10)中的氧原子作为桥联原子，同时与Ni和K配位。

The Mn is coordinated by four carbonyl O atoms from the DMF molecules and two phenolate O atoms of the picrate anions, forming a distorted octahedral structure.

在不对称单胞中存在着两种配位环境相同的Mn离子，四个DMF中的羰基氧原子和两个苦味酸根离子中的酚氧原子直接和Mn离子配位，形成了一个扭曲的八面体几何构型。

The last feature reflects a highly ordered structure of pore arrays. Solid state ^2^7Al MAS NMR investigation showed further that even at high level of aluminum (x~A~l=0.303), the Al atoms could still be incorporated tetrahedrally in the MCM-41 structure.

文中还利用^2^7AlMASNMR研究了试样中Al的化学环境，结果表明，即使在高铝含量的情况下，样品中的铝原子仍以四配位结合在MCM-41的硅骨架上，未能检测出骨架外六配位铝的存在。

Such derivatives are prepared by reacting a kaolin group mineral with a reagent, such as, an alkali metal halide or an ammonium halide which converts the majority of the octahedrally coordinated aluminum in the kaolin group mineral to tetrahedrally coordinated aluminum.

这种衍生物是通过将高岭族矿物与一种试剂，例如一种碱金属卤化物或一种卤化铵进行反应，从而将高岭族矿物中的大部分六配位铝转化为四配位铝而制备的。

In chapter 2, concerning the chemistry of many kinds of olefin-coordinated alkoxycarbene iron complexes and their isomerized products previously synthesized by our group, we examined their thermolysis reactions and many novel thermolysis products were isolated.

第二章中，对于我们小组以往合成的各类烯烃配位的铁卡宾络合物及其异构化产物，为了研究其反应性能，我们从热解反应着手，研究了一系列烯烃配位的铁卡宾络合物及其异构化产物的热解反应，获得了一系列新奇的热解产物。

Ta atom is triangularly coordinated and M atom is trigonal-pyramidally surrounded by Te atoms.

Ta具有三角形的Te配位， M具有三角锥的Te配位。

Coordination saturation is thus proved to be space saturation in the uranyl equatorial plane.

由此说明铀酰的配位饱和实际上是配位空间的饱和。

It is the fluorosilicic ion that exsits in the slurry and plays an important role in flotation, fluorosilicic ion not only reacted with Fe〓 on the surface of aegirine to form ionic compound, but also formed stable Si-F bond in Si-O etching reaction. Only ionic compound was obtained when it was attached to hematite surface according to the theories of coordination chemistry, Compared with SiF〓, Fatty acid ion preferentially acts with Fe〓 on the minerals surface, therefore, SiF〓 Can't obstruct the adsorption of collector on the surface of hematite completly, but can reduce the flotation recovery of aegirine selectively.

运用FTIR、XPS等测试方法仔细研究了氟硅酸盐抑制剂对含铁硅酸盐钠辉石的选择性抑制作用机理，氟硅酸盐在弱酸性条件下对赤铁矿浮选的抑制作用很微弱，而对含铁硅酸盐钠辉石强烈抑制，从而扩大了两者之间的浮选差异；SiF〓是矿浆中起抑制作用的主要成分，SiF〓不仅与钠辉石表面的Fe〓形成离子型配合物，而且还与Si-O键形成稳定的Si-F共价键，而与赤铁矿表面只能形成离子型配合物，根据晶体配位场理论，与SiF〓相比较羧酸根离子将优先与矿物表面Fe〓发生配位作用，因此SiF〓的存在并不能完全阻碍捕收剂在赤铁矿表面的吸附作用，却能够选择性地抑制钠辉石的上浮。

At the beginning of the treatment with BF〓·Et〓O, the BF〓 will coordinate with the alkoxyl group to form intermediates, and the intermediates will then convert to the fluorinated products that generate more active species for styrene polymerization under the selected conditions.

在〓加入的开始时，BF〓和甲氧基形成配位中间体，然后此中间体转化成BF3配位的氟化物。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。