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Tripodal ligand has rich coordination form, and the supramolecular chemistry of its copper and silver complexes is essential for creating new functional materials.

三脚架型配体有着丰富多样的配位方式，其铜、银配合物超分子结构的研究在新型材料的研制中有着重要的指导意义。

Tripodal ligand has rich coordination form, and thesupramolecular chemistry of its copper and silver complexes is essential for creatingnew functional materials.

三脚架型配体有着丰富多样的配位方式，其铜、银配合物超分子结构的研究在新型材料的研制中有着重要的指导意义。

In the last few years, the tripodal ligands bearing nitrogen atoms have drown much attention because of their polydentate, flexility and ease to synthesize.

近年来，含氮三脚架配体因其多配位点、半刚性及易合成等特点，对其稀土配合物的发光研究引起了人们的广泛兴趣。

For thecopper and silver complexes, tripodal ligands exhibit rich coordination forms, andthe coppers exhibit different geometry such as square-plan, square pyramidal, andtrigonal bipyramidally geometry.

在铜、银配合物中，三脚架配体表现出多种配位方式，铜离子有平面四边形、四方锥、三角双锥等不同的空间构型。

One mixed-ligand complex ofnH2Otpa=terephthalate, tripy=4'-(4methyoxyphenyl-2,2':6',2-terpyridine was synthesized and characterized by IR, elemental analysis and thermo-gravimetric analysis. The crystal structure of the product was established by single-crystal X-ray diffraction.

采用水热法合成了新的维链状锌的配位聚合物nH2O（tpa=对苯二甲酸，tripy=4'-（4-甲氧基苯基）－2，2'：6'，2-三联吡啶），通过红外光谱和元素分析对该配位聚合物进行了结构表征，用X射线单晶衍射测定了晶体结构。

By following the "self-assisted molecular editing" protocol first established in our labs,a number of Aphos ligands were efficiently prepared from a single starting material and they were screened for catalytic efficacy, leading to the discovery of the best-performing Aphos appended with a 3-nitrophenyl group at the C4 position.Combination of this Aphos with Pd_2 offers a precatalyst for successful cross-coupling of unactivated aryl chlorides with aryl boronic acids at room temperature.The reactions took place under mild basic conditions to produce the products in high yields.

通过我们首次提出的&自助分子剪裁&的概念从单一起始物快速合成和筛选了一系列膦配体，并发现C4位含3-硝基苯基的的膦配体和醋酸钯联用可以在室温下顺利地催化不活泼氯代芳烃和芳基硼酸的偶联反应，反应条件温和且产物收率很高。

You like chinese films in their original undubbed versions.

你喜欢没有配过音的中国电影。（配过音的算啥中国电影？

Fluouricil is usually used as anticancer drug, its derivative, 5-fluoro-uracil-1- acetic acid has good biological activity. Its complexes were presented in literatures. However, the coordination modes of it are paradox in literatures. The single crystal structure was resolved to clarify the confusion. The result indicates the carboxylic group coordinates to zinc ion in unidentate, and the heteroatoms of pyrimidine ring are not involved in coordination. Antitumor activity against SMMC-7721 was also examined.

7.5-氟尿嘧啶是临床上广泛使用的抗癌药物，它的衍生物5-氟尿嘧啶-1-乙酸亦具有良好的生物活性，有关它的金属配合物亦有报道，但其结构指认相当混乱，为此研究了它与锌的配合物单晶结构，证明了5-氟尿嘧啶以单齿羧基与锌配位，而嘧啶环氮并未配位，也研究了它对SMMC-7721细胞株的抗肿瘤作用。

Pit corrosion is a main kind of localized corrosion. The process of forming pit corrosion includes three stages-formation of pit source, development of pit cave and forming occluded corrosion cell. Molybdate series inhibitors can be inhibitive, for it can control three stages of pit development. First, there is apparent synergistic effect between molybdate and phosphate, which can suppress formation of pit source. Second, there is apparent passivation of molybdate inhibitor according to electrochemistry analysis, which let oxidation film in unoccluded cave repassivate.

首先，钼酸盐与磷酸盐或硅酸盐复配的缓蚀剂具有较理想的缓蚀性能，并且有明显的协同作用，从而能抑制部分点蚀核的产生；其次，钼酸盐复配缓蚀剂的使用，从电化学的角度分析，具有明显的钝化性能，且钝化区间较宽、维钝电流密度较小，从而能使未封闭的蚀孔或点蚀核附近的氧化膜再钝化，得到有效的修复；最后，对于还有部分蚀孔发展成为闭塞腐蚀电池的情况，钼酸盐、磷酸盐能进入蚀孔内部并且在酸性条件下生成铁钼磷酸盐，从而有效地减缓了点蚀的恶化，抑制了腐蚀的发展。

The tentative plan should provide for an amount of cargo in each hold so that no one hold will require an unproportional number of gang hours of work to discharge the cargo.

配载图应给每个货舱配以一定数量的货物，使任何一个货舱都不至于需要一种不相称的卸货工作舱时量。

Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在，'歼灭战perfuming自己与胡努特，那麼，他来到和SAT 。