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The first part is to synthesize 5-formyl -8- quinolinol from 8-uinolinol and chloroform , using ethanol as a solvent. Then analysizing the 5-formyl-8-quinolinol by IR. The second part is , according to ideas of molecule designing, to synthesize the new self-assembly Inorganic-Organic coordination polymers Co(u2-bpyV2O6,(C4H4N2)Ni2(H2O)2-V4Ol2,(Cl2Hl2N2)Co-V2O6 using Cu, Ni, and Co as templating, 4-cyano-pyridine(4-CNPy), 4,4-bipyridine,pyrazine, l,2-bis(4-pyridyl)ethane, 5-formyl -8- quinolinol as building blocks and Ammonium Metavanadate (NH4VO3) as subordinate building blocks by Hydrothermal , analysizing their content of element determining their structures by X-Ray diffraction.

本课题实验分为两部分：一是配体的合成，以8-羟基喹啉、三氯甲烷为原料，以乙醇为溶剂，合成了5—甲醛基—8羟基喹啉并且对其进行了IR的分析测定；二是配位聚合物的合成，通过分子设计，采用溶剂热法以Cu、Ni、Co为中心离子，以5—甲醛基—8羟基喹啉、4，4-联吡啶、吡嗪、1，2-二吡啶基乙烷为配体，以偏钒酸根(VO_3~-)为辅助配体，通过水热法自组装合成了新的3-D网状结构配位聚合物Co(μ_2-bpy)V_2O_6，(C_4H_4N_2)Ni_2(H_2O)_2·V_4O_(12)，C_(12H_(12)N_2Co·V_2O_6，并对其进行了元素分析和晶体结构的测定。

In particular, it has remained unclear how oogamy arose from isogamy, a more simple form of sex in which ery similar reproductie cells take on different "mating types" but do not differentiate as distinct sperm and egg.

尤其是异配生殖如何由同配生殖转化而来，我们对此还懵懵懂懂。同配生殖是一种更为简单的结合形式，在此过程中，非常相似的生殖细胞不管三七二十一地就与不同的配子结合，都不分这些配子是&公&是&母&。

The molecular designs and synthesis of triarylamine-based picolinic acid derivatives used as ancillary ligands, and their cyclometalated iridium complexes used as red-and green-emitters, as well as optoelectronics properites of these compounds were investigated in order to solve current problems of organic/polymeric electroluminescent materials and devices.

本论文针对目前有机/聚合物电致磷光材料和器件存在的问题，开展了新型三芳胺吡啶羧酸类辅助配体及其红光和绿光环金属铱配合物电致磷光材料的分子设计、合成和光电性能研究，主要包括：(1)设计、合成了三种新型的三芳胺吡啶羧酸类双齿阴离子型辅助配体；(2)以三芳胺吡啶羧酸衍生物作为双齿阴离子型辅助配体，合成得到了两个系列的红光和绿光环金属铱配合物；(3)研究了三芳胺吡啶羧酸类辅助配体分子结构对环金属配合物的紫外吸收和光致发光性能的影响；(4)以环金属配合物为客体，聚芴和恶二唑衍生物为主体，制作了聚合物电磷光器件，研究了含三芳胺吡啶羧酸类辅助配体、环金属配合物客体材料和聚合物主体材料等分子结构对电致发光性能的影响。

The X-ray crystal structure analysis of the complexes shows that all lanthanidecomplexes exhibit a tripodal ligand coordination mode, with three imino nitrogenfrom benzimidazolyl and pyridyl group, and one amino nitrogen atoms as donors.The ligands show two kinds of configuration: the fan-like and the pincer-like. Bothintra- and intermolecular π-π interactions are found in these complexes.

晶体结果表明，在所有的稀土配合物中，三脚架配体均用三个支脚上的苯并咪唑、吡啶环氮原子及一个顶端的氮原子和稀土离子进行配位，表现出三脚架式配位方式，同时，三脚架配体有风扇形及钳子形两种空间配位构型，并形成了分子内及分子间的π-π堆积作用。

This technology includes: General superplasticizer compound technology, Chennai, Department superplasticizer compound technology, Sulphamate superplasticizer compound technology, melamine superplasticizer compound technology, Superplasticizer Aliphatic compound technology.

本项技术包括：普通减水剂复配技术，奈系减水剂复配技术、氨基磺酸盐减水剂复配技术、三聚氰胺减水剂复配技术，脂肪族减水剂复配技术。

We have studiedthe coordination water-substituted reactions and the phase-transferchemistry of dozens of trinuclear or tetranuclear sandwich-typePOMs and found that organic molecules or polymers can becoordinated to these polyanions after dehydration, thus more thanone hundred coordinated products are obtained, indicating that thesepolyanions are excellent ligands in organic solvents.

我们首次对夹心三、四核等几十种化合物中配位水进行了配位水取代反应及相转移化学研究，脱水后可配位有机分子或有机高分子，得到上百种配位产物，因此在有机溶剂中它们是优秀的配体。

The crystal consists of two similar but independent molecules in the asymmetric unit and the Ce ion coordinated toward ten donor atoms, six of which belong to the nitrogen atoms of two tridentate ligands and four oxygen atoms from two bidentate picrates.

晶体中一个不对称单元内有两个结晶学上独立的分子，这两个分子的构型基本相同，中心Ce3＋均与两个三齿配位的配体及两个双齿配位的苦味酸根配位，配位数为10。

The results indicated that: Tripyrazolone, tripodal and crptands ligand L〓, L〓 and L〓 have good coordination ability with rare earth ions Rare earth ions were coordinated with their oxygen and nitrogen atoms.

结果表明，三脚架结构吡唑啉酮、三酸和穴醚配体与稀土离子有较好的配位作用，它是通过氮原子、氧原子与稀土离子配位的。而穴醚配体与稀土离子配位效果却不好。

In order to investigate the relationship between the open-chain ligands and metal ions, and the possibility of the metal complexes used as electroluminescent materials, a new naphthol schiff base ligand which is a open-chain crown and its four transition metal complexes, a new amide type tripodal ligand containing heterocyclic ring, two tripodal ligands (H〓L〓 and H〓L〓) containing phenol schiff bases and their rare earth complexes were synthesized and characterized.

为了进一步研究和探讨开链配体与金属离子的配位作用，以及金属配合物作为电致发光材料的可能性，我们设计合成了含萘酚环的Schiff碱开链冠醚H〓L〓及四种过渡金属(Zn、Ni、Co、Cu)配合物，两个含酚羟基的Schiff碱三足配体H〓L〓和H〓L〓及稀土配合物，一个含杂环的酰胺型三足配体L〓，培养了配体L〓的单晶，确定了其晶体结构。

According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.

测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下（pH=1.0～14.0）的乙二醇／水（V／V=1：1）溶液低温ESR谱，发现不同pH下，溶液中具有不同组成的配合物，根据不同pH下ESR谱的变化，利用Johnson的加合规则并结合红外光谱，推测了它们在溶液中的可能结构；利用波谱参数计算了配合物键参数；利用电子光谱数据计算了配合物的晶体场参数，讨沦了它们的成配特性，结果表明：VO配合物属离子型配合物，随取代水分子的配体（Ser、Phen或Bipy）数目增加，键参数减小，配合物共价性增强，同时得出这些体系中，生物配体竞争配位规律：Phen和Bipy与VO的配位能力比Ser强。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。