配

Therefore heteronuclear Cu-Ln compounds have commonly been synthesized with hetero-donor ligands comprising two types of ligating atoms coordinated each to Cu and Ln atoms, respectively.

因此通常用含有能分别和铜，稀土配位的两种配位原子的配体来合成异核Cu-Ln配合物。

For thecrystal in MeOH, X-ray single-crystal analysis reveals that each Schiff base provideone iminic N, one phenolic O and one hydroxylic O to chelate the four Cu andthus resulted in a pseudo-cubane structure. Different from the crystal obtained inMeOH, each Cu are tetra-coordinated not penta-coordinated.

充分证明了所设计的Schiff碱配体是一种桥联配体，不仅在配位形式上有多样性，而且在晶体排列方面也应具有多样性，是构建具有新颖物化性质及结构的超分子聚集体的良好前体。

Two qina ligands chelate a cobalt ion by 0 and N atoms and two DMSO ligands coordinate a cobalt ion by two O atoms at an axis. The complex formed inerratic octahedron configuration, and π-π stacking weak interaction was observed between the molecules.

配合物为单斜晶系，P2(1)/C空间群，2个qina配体以氮原子和氧原子与Co离子螯合配位，2个DMSO以氧原子与Co离子轴向配位，形成规则的八面体构型配合物，分子之间存在π-π堆积弱相互作用。

In C. reinhardtii, isogamous sexual reproduction occurs through "plus" and "minus" mating types.

C。 reinhardtii藻的同配有性生殖通过&正&配子和&负&配子结合产生。

Reaction of α,α,α,α-tetra (o-aminophenyl) porphyrin with isonicotinic acid yields the ligand 1b bearing two coordination sites whose structure has been verified by IR、UV-Vis、〓H NMR and MS spectra.

以α，α，α，α-四卟啉为母体，经过与异烟酸缩合反应得到具有两个配位位置的配体1b，配体的结构经过IR、UV-Vis、〓H NMR、MS验证。

Two coordination polymers composed of in situ synthesized ligand deriving from isophthalic acid through the hydroxylation on the 2-position have been synthesized under hydrothermal conditions.

利用铜离子的氧化还原性质，以铜离子和间苯二甲酸在水热条件下反应使配体发生羟基化衍生成2，6-二羧基苯酚，并组装出2个含衍生配体的配位聚合物。

In this study aldylencdithiomethylene Malonic acid acts as the main coordination agents and compound iron ion have been synthesized by the means of solution, As a result ,the 1D polymer is obtained.

本论文采用常规的溶液合成方法，首先设计合成了一个以含有二硫缩烯酮结构的丙二酸类配体和过渡金属铁离子的单核配合物，再以此单核配合物作为配体设计合成了三个异多核配合物和配位聚合物。

Application of MNPK significantly increased the potentially mineralizable nitrogen (N0) and the rate of N mineralization.

化肥长期配施有机肥或秸秆，显著提高了土壤氮素矿化势(N0)以及矿化率，其中化肥配施有机肥土壤浅大于化肥配施桔秆处理。

Five of their single crystals were obtained and their structures were determined by X-ray diffraction. By comparison, it was found that dithiocabamate complexes often formed an exactly planar MS4 unit, such as [Mo(R2dtc)2]; and also formed a special MS 5 unit, such as [Cu2(R2dtc)4], the copper atom lies in a distorted square-pyramidal environment.Four kinds of heteropoly acids were prepared and characterized; a series of solid superacid catalyst of supported heteropoly acid were prepared and characterized; regioselectivites of chlorobenzene mononitration with nitric acid with different heteropoly acid on different supports and reaction conditions have been investigated.

培养并解析了5个该类配合物的单晶结构，通过比较，发现二硫代氨基甲酸盐与过渡金属容易形成四配位结构，金属原子与4个硫原子共平面，比如二乙基二硫代氨基甲酸钼；也能形成比较特殊的五配位结构，比如二乙基二硫代氨基甲酸双核铜，Cu原子与5个S原子相连，处于一个变形的四方锥结构的配位环境。

The compound 1 and 2 are bouth isolated monosubstituted Keggin polyoxometalate with pendant organic ligands. The organic ligand contact to the Ni or Mn atom using the N atom.

化合物1和2为一孤立的带有悬臂有机配体的Keggin结构，有机配体利用它的端基氮原子配位到金属Ni或Mn原子上。

Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在，'歼灭战perfuming自己与胡努特，那麼，他来到和SAT 。