邻苯二酚

Results showed that reaction temperature has little effect on the molar ratio of catechol to hydroquinone and reactive period of catalyst.

试验结果表明，反应温度对反应产物中邻苯二酚/对苯二酚的比例和催化剂的活性周期的影响不明显，过氧化氢/苯酚摩尔比对邻苯二酚/对苯二酚的比例的影响较大，提高过氧化氢/苯酚摩尔比会降低邻苯二酚/对苯二酚的比例，缩短催化剂的活性周期。

It has been observed that pyrocatechol and m-phenylenediamin can sensitively inhibit the discoloration of neutral red oxidation by the H2O2 and in the presence of catalyzer Fe in dilute sulfuric acid solution but the inhibitory effects of two organic compounds can not be added. Based on this research, the advantages of artificial neural network were adopted to handle the experimental data and a new inhibitory kinetic spectrophotometry of simultaneous determination for pyrocatechol and m-phenylenediamin with artificial neural networks was established.

在硫酸性介质中，Fe能够催化H2O2氧化中性红褪色反应，邻苯二酚和间苯二胺都能阻抑该催化氧化褪色反应的速度，研究发现：两者对Fe催化H2O2氧化中性红褪色反应阻抑作用不具有加和性，根据这一现象，用人工神经网络处理非线性体系的优势进行数据处理，从而建立了一种新的测定邻苯二酚和间苯二胺混合物的人工神经网络阻抑动力学光度法。

Catalysts in three synthesis routes,the hydroxylation of 4-tert-butyl-phenol,the alkylation of pyrocatechol by tert-butyl alcohol and the alkylation of pyrocatechol by isobutene,were discussed in detail in terms of reaction conditions,catalysts,temperature,reaction time etc.

论述了对叔丁基苯酚羟基化法、邻苯二酚与叔丁醇烷基化法和邻苯二酚与异丁烯烷基化法生产对叔丁基邻苯二酚的合成路线的催化剂。

The linear ranges of determination for pyrogallol, phloroglucinol, pyrocatechol, resorcinol and parodioxybenzene were 1.0×10〓～2.0 ×10〓mol l〓, 1.0×10〓～1.0×10〓mol l〓, 1.0×10〓～6.0×10〓mol l〓, 1.0 ×10〓～2.0×10〓mol l〓 and 1.0×10〓～6.0×10〓mol l〓 respectively, and their detection limits were 7.2×10〓mol l〓, 6.8×10〓mol l-1, 2.1 × 10〓mol l〓, 7.1×10〓 mol l〓 and 2.2×10〓mol l〓 respectively.

该方法测定连苯三酚、间苯三酚、邻苯二酚、间苯二酚和对苯二酚的线性范围分别为1.0×10〓～2.0×10〓mol l〓，1.0×10〓～1.0×10〓 mol l〓，1.0×10〓～6.0×10〓mol l〓，1.0×10〓～2.0×10〓mol l〓和1.0×10〓～6.0×10〓mol l〓；检出限分别为7.2×10〓mol l〓、6.8×10〓 mol l〓、2.1×10〓 mol l〓、7.1×10〓mol l〓和2.2×10〓mol l〓。

Analysis of the treated aqueous solution was conducted with GC-MS,and the main intermediates during phenol degradation were isobutyric acid,malonic acid,benzoquinone,butenoic acid,oxalic acid,maleic acid,succinic acid,hydroquinone,catechol and resorcin.

利用GC-MS分析了苯酚降解主要中间产物为异丁酸、丙二酸、对苯醌、丁烯酸、乙二酸、顺丁烯二酸、丁二酸、邻苯二酚、对苯二酚及间苯二酚等，并据此推测了苯酚电催化氧化的可能反应途径。

C. I. Reactive blue KN-R, Alizarin brilliant green G and Hostlam blue R could not be degraded by Zoogloea HP3. Furthermore, ABAS degradation was regressed under the exisitence of the above dyes. 1-Aminoanthraquinone-2sulfonic sodium, 1, 4-dihydroxylanthraquinone-2-sulfonic sodium, 1, 4, 5, 8tetrahydroxylanthraquinone, anthraquinone, aniline, phenol, catechol and ophthalic acid could be degraded by Zoogloea HP3. Aniline was the most degradable substrate among ABAS, aniline, phenol, catechol and o-phthalic acid. However, benzenesulfonic sodium and p-amino benzenesulfonic sodium were not degraded by it.

动胶菌HP3不能降解活性艳蓝KN-R、弱酸性绿GS及毛用活性蓝HW-R等蒽醌型染料，且染料的存在对菌体降解溴胺酸有不同程度的抑制作用；动胶菌HP3可以降解1-氨基蒽醌-2-磺酸钠、1，4-二羟基蒽醌-2-磺酸钠、1，4，5，8-四羟基蒽醌、蒽醌及苯酚、邻苯二酚、苯胺、邻苯二甲酸等苯系化合物，而不降解苯磺酸钠、对氨基苯磺酸钠；在溴胺酸、苯酚、邻苯二酚、苯胺、邻苯二甲酸中，苯胺是动胶菌HP3的天然底物。

The super acid SO〓/ZrO〓, due to its strong acidity, favores the dealkylation and disproportionatin of 4-TBC or/and DTBC, preventing the increase of the selectivity for 4-TBC.

而固体超强酸SO〓/ZrO〓由于酸性较强，易于发生4-叔丁基邻苯二酚和3，5-二叔丁基邻苯二酚的脱烷基反应和4-叔丁基邻苯二酚的歧化反应，因此不利于提高4-叔丁基邻苯二酚的产率。

Microcalorimetry was applied to follow the toxic effects caused by different diphenol compounds on microbial activity of Chinese fir soil.

用微量量热技术分析了三种二酚类化合物(邻苯二酚、间苯二酚、对苯二酚)对土壤微生物活性的毒性作用。

Organic: dihydroxybenzene, oxalic acid, hydroquinone, fumaric acid, gulonic acid, o-dihydroxybenzne; m-dihydroxybenzene; coke powder, tartaric acid, cyanuric acid, G salt, R salt.

有机物：苯二酚、草酸、对苯二酚、富马酸、古龙酸、邻苯二酚、间苯二酚、焦炭粉、酒石酸、氰尿酸、 G 盐、 R 盐。

In the hydroxylation of phenol with H〓O〓 in the presence of Ti-ZSM-5, water is best solvent. It produces catechol and hydroquinone simultaneously, and catechol/hydroquinone ratio is approximately 0.85. The results show H〓O〓 utilization ratio increase 14%, when nonoxidizable weak acid HAc is added into the reaction system. Under the conditions of Ti-ZSM-5 as catalyst, phenol/H〓O〓 ratio being 10, a little HAc, temperature 75℃, reaction time 6h, H〓O〓 utilization ratio reaches 74. 6mo1% in the reaction.

对Ti-ZSM-5催化苯酚羟基化的研究结果表明，水是最好的溶剂，羟基化有邻、对苯二酚两种产物，并且邻苯二酚/对苯二酚摩尔比可维持在～0.85左右；向反应体系中加入非氧化性弱酸性助剂HAc时，H〓O〓有效利用率较未加入助剂时可提高14mol%；当催化剂用量为8g/100g苯酚、苯酚/H〓O〓比为10、反应温度75℃、添加少量HAc的条件下，反应6h后，H〓O〓有效利用率可达74.6mol%。

I can not make it blossom and suits me

我不能让树为我开花

When temperatures are above approximately 80 °C discolouration of the raceways or rolling elements is a frequent feature.

当温度高于 80 °C 左右时，滚道或滚动元件褪色是很常见的特征。