邻苯二甲酰亚胺

Low-valent titanium reagent induced the monomolecular reduction of N-substitutedphthalimides supplied a new method of synthesis hydroxyl lactams. This method was moreeconomic, convenient and in higher yields comparing with other methods reported before,therefore it has practical value.

4低价钛试剂引起邻苯二甲酰亚胺的单分子还原反应提供了一种合成羟基内酰胺的新方法，和文献方法相比，我们的方法试剂便宜易得，毋需溶剂，操作简便，收率也有所提高，具有实用价值。

Phthalimide,anthranilic acid,2methyleneglutaronitrile bromina 1bromobutane 1,2benzisothiazole3one.

邻苯二甲酰亚胺，邻氨基苯甲酸，2亚甲基戊二脯，2溴2溴甲基戊二脯，溴代正丁烷，1.2苯并异噻唑3酮。

Therefore, this paper selected the direct oxidation route to synthesize α-isophorone, and according to the principles of green chemistry, oxygen was used as the oxidant, with non-metal N-hydroxy-phthalimide as catalyst, for preparation of Isophorone.

因此本论文的研究选用以α-异佛尔酮直接氧化的路线，且根据绿色化学的原则，以氧气为氧化剂，用一种无金属参与的N–羟基邻苯二甲酰亚胺为催化剂催化α-异佛尔酮，为氧代异佛尔酮的制备提供一条全新的途径。

Firstly, a series of organic molecules which use phthalimido group as electron acceptor, N as electron donor, COO~- as eletrofugal group were synthesized based on SET-promoted photocyclization processes. These compounds were irradiated by 500 W ultraviolet under nitrogen atmosphere in room temperature. After filtration of the photochemical character of these molecules, substrate S1 and S2 were selected as appropriate model reactants. Secondly, the monosubstituted derivatives at the 6-position ofβ-cyclodextrin were synthesized as chiral template of photocyclization.

首先，以单电子转移机理为指导，设计了一系列以邻苯二甲酰亚胺基为电子受体、N为电子给体、羧基为离去基团的光环合反应底物，这些化合物在氮气保护下以500瓦紫外光室温下进行光照反应，对这一系列的分子的反应情况进行了研究与筛选，最终选择底物S1和S2作为研究光环合反应中立体控制方法的模型底物；其次，又合成了一系列6-位单取代β-环糊精，以此作为光环合反应的手性模板。

A synthetic method for N-(5-nitro-6-chloro-3-pyridine methyl) phthalimide is studied.

研究了N-（5-硝基－6-氯－3-吡啶甲基）邻苯二甲酰亚胺的合成方法。

By using 4-chloro-5-nitro phthalimide as raw material and through aminoysis, reduction, cyclization and hydrolysis, end-produce benzimidazole-5,6-diformic acid is prepared.

本发明公开了一种苯并咪唑－5，6－二甲酸的制备方法。该方法是以4－氯－5－硝基邻苯二甲酰亚胺为原料，依次经过氨解、还原、环合、水解反应过程，制得最终产品苯并咪唑－5，6－二甲酸。

Then, N-(5-nitro-6-chloro-3-pyridinemethyl) phthalimide is obtained after the nitrating reaction of N-(6-chloro-3-pyridine methyl) phthalimide. The yield of the obtained product is 90.5%, and its melting point is 143.1~143.8℃.

缩合产物再经过硝化，合成N-（5-硝基－6-氯－3-吡啶甲基）邻苯二甲酰亚胺，其熔点为143.1~143.8℃，收率为90.5%。

Mainly engaged in sodium azide, barium azide, three phosphorus nitride Friday, phenyl isothiocyanate, 1 - phenyl -5 - mercapto-tetrazole, 4 - dimethylamino-pyridine, 2 - mercapto--5 -- methyl-1,3,4 thiadiazole, N-hydroxy phthalimide, anhydrous betaine and betaine hydrochloride, such as fine chemical raw materials and medicine, pesticide intermediates of the development, production and sales.

主要从事叠氮化钠，叠氮化钡，五氮化三磷，异硫氰酸苯酯，1-苯基-5-巯基四氮唑，4-二甲氨基吡啶，2-巯基-5-甲基-1，3，4噻二唑，N-羟基邻苯二甲酰亚胺，无水甜菜碱及甜菜碱盐酸盐等精细化工原料及医药、农药中间体的开发、生产和销售。

Triphosgene ; carbamic acid ethyl ester ; phthalimide

三光气；胺基甲酸乙酯；邻苯二甲酰亚胺

Keywords acylhydrazone;sulfamic acid;N-aminophthalimide;fine chemical intermediate

酰腙； 氨基磺酸； N-氨基邻苯二甲酰亚胺；精细化工中间体

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。