选择反应

The author has studied the kinetics of hydrogenation of a,β-unsaturated aldehydes andketones such as cinnamaldehyde and 2-butylene cyclopentanone,β-ionone over amorphousalloy NiB catalyst at atmospheric pressure of H2 as well as effects of reaction conditions onthe kinetics.

作者以肉桂醛和2-亚丁基环戊酮、β-紫罗兰酮为代表重点研究了非晶态NiB催化α，β-不饱和醛酮常压下选择加氢的反应动力学。常压下该反应是准一级反应。

The formation of our 1D nickel wires can be ascribed to the cooperative effect of the reaction rate and magnetic field.The reaction rate in the system is controlled mainly by adjusting the reactant concentration when other reaction conditions are fixed.When the concentration of Ni~(2+) is low,the reaction rate is correspondingly slow,so the complex[Ni(N_2H_4)_x]~(2+) preferentially migrates to the magnetic line of force since paramagnetic metal ions are attracted toward the maximum field.

当反应物Ni~(2+)浓度较低时，反应速率相对较慢，[Ni(N_2H_4)_x]~(2+)优先选择迁移到磁力线附近并且沿着磁力线方向排列，导致电极电势增大，于是[Ni(N_2H_4)_x]~(2+)的化学还原反应也是沿着磁力线发生，结果导致了镍纳米线的形成。

Furthermore the expressions of nonelastic displacement response spectra were also given.

为研究其抗震设计方法，选择了35次地震，212组近断层地震记录作为统计样本，根据得到的平均弹性位移反应谱，给出了近断层地震设计弹性位移反应谱表达式，并在此基础上，给出了近断层地震设计非弹性位移反应谱计算公式。

We report here creativity using compound solvent as solvent is the unique of the new technology on the basic of perpendicularity experiments and with the actual situation of our country, the effect of reaction temperature, reaction time, rate of material were optimized. Rate of yield can reach beyond 98% and this technology has successfully applied in practical production with the output of 300t per year.

解决以上两个问题是改进得克隆生产工艺的关键，本文针对上述问题，并且结合我国实际情况，在正交试验的基础上创造性的选择了复合溶剂，改进了得克隆的生产工艺，确定了最佳的投料比、反应温度、反应时间等反应条件，溶剂可以循环利用，并且得到了98％以上的高产率。

And on the basis of mono-factor test, using COD decreasing rate and decolour rate as targets, six factors affecting catalytic effect were selected to proceed L9(34) orthogonal experiments. The conclusion of primary and secondary factors was drawn and the turn was : kind of catalyst-amount of catalyst-pH value-temperature-amount of H2O2-amount of air . The optimization were determined to be : initial pH value : 5.5 ; temperatare : 90 C; amount of H2O2: lml/400ml waste water ; kind of catalyst: AC3 ; inciting small amount of air ; amount of catalyst: 125g activated carbon to 500g stone .

并在单因素试验的基础上，以废液COD去除率和脱色率为指标，选择废液初始pH值、反应温度、启动剂用量、催化剂类型、鼓空气量、催化剂加入量为因素，进行L_9(3~4)正交试验，确定影响因素因素的主次关系为：催化剂类型→催化剂加入量→废液初始pH值→反应温度→启动剂量→鼓空气量；最佳处理技术条件为：废液初始pH5.5；反应温度90℃；启动剂量1ml／400ml废液；AC3型催化剂；鼓小流量空气；炭石比125g／500g。

The results of in situ DRIFTS on propylene oxidation show that the allyl species originated from α-H abstraction of propylene were located at the wavenumbers of 1454 cm~(-1) and 1427 cm~(-1). The rate-determining step is the abstraction of an α-H abstraction from a lattice oxygen linked to a bismuth ion to form a π-allyl intermediate coordinated to a molybdenum ion. The metal-oxo group then attacks the allyl intermediate forming a σ-bonded oxygen-allyl species, which is in a rapid equilibrium with the π- bonded species. The σ-bonded species then transforms to acrolein by further abstraction of α-H. Such species as formate, carboxylate, carbonate transform to deep oxidation products. The acetone was derived from propylene by an enolic species at lower temperatures.

丙烯氧化反应体系的原位漫反射红外光谱研究结果表明，由丙烯脱氢生成的烯丙基中间物种吸收峰在1454cm~(-1)和1427cm~(-1)处；基于此提出了较完整的丙烯氧化反应网络：丙烯选择氧化生成丙烯醛主要经历丙烯脱除甲基上的一个H，生成烯丙基物种，该物种嵌氧生成σ-O络合物，脱氢得到丙烯醛前驱体，脱附生成丙烯醛；完全氧化产物是由催化剂表面上生成甲酸盐、羧酸盐、碳酸盐等形式的中间物种转化而成；较低反应温度下丙烯氧化生成丙酮，通过烯醇式中间物种氧化生成丙酮前驱体得到。

Oxidation of alkenes catalyzed by metalloporphyrin imidazolium salts in the presence of N-hydroxyphthalimide and isobutyraldehyde as co-catalysts provided the epoxidation product at room temperature. And the solvent with a weak coordinating ability such as acetonitrile gave the best result.

金属紫质咪唑盐於烯类的氧化催化反应上，若与NHPI及异丁醛共催化，可在室温进行环氧化反应，反应溶剂选择具有弱配位能力的乙腈，则可获得较佳结果。

The choice and technology of the phosphation reagent were investigated.

在合成中对磷酸化试剂的选择及制备工艺进行了考察，研究了反应温度，反应时间，反应物与磷酸化剂的摩尔比对磷酸单酯含量的影响。

A desulfurization method is proposed for the removal of sulfur compounds from FCC gasoline by alkylation reaction of thiophenic sulfur with olefins over acid catalysts, and the higher boiling sulfur-containing products are removed by fractional distillation.

选择以噻吩的甲基取代衍生物(包括 2-甲基噻吩、3-甲基噻吩及 2，5-二甲基噻吩)与异丁烯的烷基化反应为模型反应，考察了经三氯化铝气相固载法改性的 CT175 树脂催化剂催化噻吩的甲基取代衍生物与烯烃的烷基化反应性能。

These five zones are as follows: the zone of the reaction synthesis of TiC, the zone of reaction completion, the zone of the growth and homogenization of TiC, the zone of ideal structure and the zone of coarsened TiC particulates.

结果表明：适当提高合金熔体的等温反应温度并选择理想的反应时间，可获得尺寸细小、数目较多且分布均匀的原位TiC颗粒；当合金熔体中TiC的合成反应基本完成时，凝固速度对组织中TiC颗粒的数量和尺寸的影响不是很大。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

If you have any questions, you can contact me anytime.

如果有任何问题，你可以随时联系我。