连接物

The chelate structure was examined by AFM scaning, single strand structure at AFM gram is Ala-Gln, two combined single strand is Ala-Gln-Zn~(2+), and atomic radius of Ala-Gln-Zn~(2+)'s conjunctive atom is about 0.24 to 0.25nm, which is near to Zn~(2+), so the conjunction atom is Zn~(2+). Thus the coordination reaction and the molar ratio 2:1 is proved again.

原子力显微扫描指出，大量出现的单一弯曲链状结构是Ala-Gln分子，而两两组合连接的链状结构，则是Ala-Gln-Zn~(2+)螯合物，且连接两个链状结构、半径约为0.25nm的中心原子是Zn~(2+)，证明Ala-Gln与Zn~(2+)形成配位比为2：1稳定螯合物。

It is worthy of mentioning that complex 21 is the first (3, 4)-connected self-penetrating 3D polymer; complex 22 is the first two-fold interpenetrating trinodal 4-connected network with (64·82)(63·83)2(65·8) topology; complexes 23-27 all show three-fold interpenetrating networks, containing the rare (3, 4)-connected (63)2(64·8·10)3 net and the common diamond nets as well as α-Po nets.

值得注意的是，配合物21是第一个(3， 4)-连接的自穿插网格；配合物22是第一个二重穿插的三节点4-连接的(64.82)(63.83)2(65.8)拓扑网格；配合物23-27呈现三重穿插的网络结构，包括少见的(3， 4)-连接(63)2(64.8.10)3拓扑网格以及常见的金刚石网格和α-Po立方格子。

A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; a selectivity control agent comprising at least one silicon containing compound containing at least one C1-10 alkoxy group bonded to a silicon atom, and one or more activity limiting agent compounds comprising one or more aliphatic or cycloaliphatic carboxylic acids; alkyl-, cycloalkyl- or alkyl-ester derivatives thereof; or inertly substituted derivatives of the foregoing.

一种用于丙烯聚合的催化剂组合物，所述催化剂组合物包括：一种或多种齐格勒-纳塔主催化剂组合物，该主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体；一种或多种包含铝的助催化剂；选择性控制剂，该选择性控制剂包括至少一种包含硅的化合物，该化合物包括至少一种与硅原子连接的C 1-10 烷氧基；和一种或多种活性限制剂化合物，该活性限制剂包括一种或多种脂族或脂环族的单或聚羧酸类、其烷基-、环烷基-或烷基-衍生物、或上述惰性取代的衍生物。

A,an=not ab,abs=away ad,a,ac,ad,af,al,an,ap,as,at=to;at ambi=both ana=up ante=before anti=against auto=self be=do bene=good cata=complete cent=hundred circum=around co,com,con=together contra=against de=down,off dec,deka=ten dia=across dis=apart duo,di,twi=two dys=bad en=make ento=inside epi=upon equi=equal eu=good ex,ec,e=out fore=ahead hetero=different holo=complete homo=same hyper=above hypo=below in,il,im,ir=inside;not infra=below inter,intel=between intra,intro=within iso=same macro=big mal=bad medi=middle mega=giant meta=change micro=small mis=wrongly mono=one multi,poly=many neo=new nona,ennea=nine ob,oc,of,op=toward oct=eight omni=all orth=straight pan=all para=beside per=through peri=around post=after pre,pri=before prin=first pro=forward quad,tetra=four quint,penta=five re=back retro=back se=apart semi,demi,hemi=half sept,hepta=seven sext,hexa=six solo=alone sub,suc,suf,sug,sum,sup,sur,sus=under super,sur=over supra=above syn,sym=same tele=far trans,tra=across tri,ter=three un,ne,non=not uni=one ultra=beyond

成年人学英文的第一课和第二课刊出后，有数位读者写E-mail给我。有一位说道：「一篇文章的每一个单字都查到解释了，但整篇文章就是看不懂，怎麼办？」另一位说：「我的文法很差，没办法写完整的英文句子，要如何补救？」当发音和字汇都掌握住学习要领之后，剩下的就是「读」和「写」了，这才符合学习英文的正确步骤：听→说→读→写。台湾传统的学习方式由「写」开始，再「读」，然后才「说」，最后再去补救「听」力，可以说是背道而行，难怪效果不彰。那麼学习「读」的要诀是什麼呢？当然最重要的是能够了解整个句子的涵义。记得初中的时候背了很多文法规则，考试的分数虽然很高，但是对「读」的能力没有帮助。连那个时候流行的「英语九百句型」，也从来没有耐心读完过。然而我们今天能够看懂中文的文章，难道是因为我们熟悉中文的文法吗？答案是否定的。同样地，一个美国人虽然能阅读报纸，但是要求他做「英文文法分析」，他可能也会傻眼。英文的句子其实不需要去靠文法书中的规则去了解，文法书只应当作参考书，在有疑惑的时候才去查阅。平常应养成「约定成俗」的习惯，就是看别人怎麼用，然后「依样画葫芦」，日积月累，文法规则就化为无形了。因此，要训练「读」的技巧，不应该是靠文法规则，而是要多读。但是在读之前，要具备「了解句子」的基本能力，这就是我们的第三课─了解英文句子的要诀。了解英文句子的关键，在於先抓住「主词」和「动词」。看到一句很长的英文句子，不要害怕：先找主词，再找动词。动词如果是「及物动词」，再去找「受词」。主词、动词、受词之外，剩下的通通当做修饰语，有的修饰主词，有的修饰动词，有的修饰受词，有的修饰全句；任何两个完整的句子都可以用连接词连接起来。以上简单几句话，就是了解英文句子的基本观念。了解英文句子的第二步是熟悉英语的五种基本句型，其中前两种与不及物动词有关，后三种与及物动词有关。以下的句子中，用大括号表示{主词}或{受词}，中括号表示，剩下的部份都是修饰语。第一种与不及物动词有关的基本句型叫做「简单不及物句型」（Intransitive Verb，简称I），请背住以下五个句子

In this chapter, the folate-EDA was covalently connected with heparin- campotothecin by carbodiimide activation to get a folate-heparin-campotothecin conjugate.

以乙二胺作为连接臂，通过酰胺键将氨基化的叶酸与肝素-喜树碱复合物连接起来，制备了一种叶酸偶联的肝素-喜树碱复合物。

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions（0-D chain）; complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物，并用X-射线单晶结构分析方法确定了晶体结构，分别为： [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构；配合物2借助水分子形成一维链状结构；配合物3、4、5、6是以H4btc为第一配体、phen为第二配体，通过水热法合成的配合物，其中，Co2+、Ni2+、Cu2+为中心离子；配合物3中的二价钴离子具有相同的配位环境，不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境，在配合物4中，一维链通过H4btc上的羧基形成一个二维层结构；配合物5、6是借助H4btc上的羧基形成的一维链状结构；配合物7、8属于异质同晶结构，它们的分子通过分子间氢键形成三维网状结构，H4btc上的羧基失去2个质子，作为一个二价负离子起到电荷平衡作用。

Further study of the interaction between NodD and naringenin by FRET technology is underway.

通过对naringenin分子上六个不同位点，不同性质，长度连接链以及母体和荧光团之间两种连接方式的11个荧光标记物的合成以及生物活性评价，我们找到了一个荧光标记物，它保留了野生型naringenin约20％的活性，并将其用于根瘤菌固氮过程的研究，发现该荧光标记物能够顺利进入根瘤菌活细胞中，为下一步通过FRET技术研究naringenin和NodD蛋白之间的相互作用打下了基础。

Adjacent helical chains are racemic. The Ag atom is linked to two nitrogen atoms of the 2-pyridyl and 4'-pyridyl groups from two different 2,4'-bpy ligands as well as to the oxygen atom of the counterion. In 17 and 19, the adjacent helical chains are linked to wavy two-dimensional network structures by the nitrate counterions.

相邻的螺旋链间是外消旋的，Ag 原子与分别来自两个不同2，4'-联吡啶的2-吡啶基和4'-吡啶基的氮原子以及阴离子的氧原子配位，在配合物17和19中，相邻聚合螺旋链被硝酸根离子桥连接起来，变成了一个波浪形的二维网络结构；配合物18是首次通过无桥连配体支持的Ag ××× Ag键将相邻螺旋链连接成二维非穿插的网络结构。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

These improvements included, widening and re-paving the footways with York Tone buff coloured paving. Replacing and reorganising the street furniture into one neat line behind the kerb to leave an unobstructed walkway for pedestrians. Relocating telephone booths to the sidestreets. Closing off selected sidestreets to provide a more continuous footway enhancing pedestrian safety and preventing restricted traffic from entering the street. Erecting new, dual purpose lighting covering both the carriageway and footway from one post. The posts also included attachments enabling banners to be put up. Creating bus lay-bys….

这些改进包括很多方面：拓宽并用浅黄的约克色调重铺人行道；重新组织摆放街边摆设，使砌边石后面的街道干净整洁，以便给行人留出无障碍物的通道；把电话亭挪进小巷安置；有选择地封闭一些小巷，从而提供一条更连贯的人行道，既保障了行人的安全，也避免了一些受限制的车辆进入大街；建立新的双重目的的照明系统，从一根电线杆上瑶同时照射车道和人行道，这些电线杆上还要有能安置旗帜横幅的连接物；修建公共汽车的路边停车处，等等。

And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47：5 法老对约瑟说，你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法，同时，采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。