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In this paper, twenty novel meso-substituted porphyrins of four series were designed and synthesized by increasing the conjugation of porphyrins or introducing substituents with high fluorescence quantum yield into the meso-position of porphine, and then red OLEDs were fabricated by doping porphyrins into a suitable host using ten porphyrins compounds and their electrolumin -escence properties were tested. The main contents and results were generalized as follows:Three meso-tetrakisporphyrins 4a-c and three conjugations of porphine-triarylamine linked by styrene 10a-c were synthesized and characterized by 1H NMR, MS, UV-vis spectra and fluorescence emission spectra.

本文通过增大卟啉分子的共轭结构或将具有高荧光量子产率的基团连接到卟吩环的中位得到了四类共20个新型的卟啉化合物,并选取其中10个化合物制备有机发光器件来考察材料的电致发光性能,具体内容包括以下几个部分:设计合成了3个中位直接被三芳胺取代的卟啉化合物4a-c和3个通过苯乙烯连接的卟吩-三芳胺共轭体10a-c,通过核磁氢谱、质谱、紫外吸收光谱和荧光发射光谱表征了新化合物的结构。

Adjacent helical chains are racemic. The Ag atom is linked to two nitrogen atoms of the 2-pyridyl and 4'-pyridyl groups from two different 2,4'-bpy ligands as well as to the oxygen atom of the counterion. In 17 and 19, the adjacent helical chains are linked to wavy two-dimensional network structures by the nitrate counterions.

相邻的螺旋链间是外消旋的,Ag 原子与分别来自两个不同2,4'-联吡啶的2-吡啶基和4'-吡啶基的氮原子以及阴离子的氧原子配位,在配合物17和19中,相邻聚合螺旋链被硝酸根离子桥连接起来,变成了一个波浪形的二维网络结构;配合物18是首次通过无桥连配体支持的Ag ××× Ag键将相邻螺旋链连接成二维非穿插的网络结构。

The connecting and disassembling construction body of the monitor mechanism includes three parts.

本发明的显示器机箱连接和分解构造体的前罩和后罩在连接后,可以非常容易地拆开。

In a radio wave absorber (10), four hollow tetrahedrons (20) each of which has one open surface are connected such that a surface (20a) opposed to the open surface of the hollow tetrahedron (20) forms a side of a hollow pyramid (22). The radio wave absorber (10) is composed of a radio wave absorbing member shaped like a thin plate.

该电波吸收体(10)呈按照下述方式连接而形成的形状,该连接方式为将4个一面开口的中空四面体(20)以开口面相对的面(20a)作为中空棱锥(22)的侧面的方式形成。

In the coordination polymer,with the formates as space linkers,two types of copper centers are joined together to form three-dimensional frameworks.

在该配位聚合物中,通过甲酸根作为连接配体将两种铜配位中心连接起来形成三维网状框架结构。

The joinings of graphite,SIC ceramic and 3D-C f /SiC composites were obtained by using silicone resin as a precursor at 800-1400℃.Effects of the curing and pyrolysis process of SR,pyrolysis temperature,holding time and heating rate on the joining were especially studied.

由硅树脂作为先驱体,在高温(800-1400℃)转化陶瓷结合层对石墨、SiC陶瓷及3D- C f/ SiC复合材料进行了连接实验,着重探讨了硅树脂固化裂解过程、裂解温度、保温时间及升温速率对连接性能的影响。

Some valuable conclusions were drawn and shown as following: Three models were brought forward, i.e. 6DOF rigid-connected model, 8DOF rigid-jointed model and 12DOF non-rigid connected model. The basic dynamic properties of the system, the relative motion between parafoil and payload, and some geometric parameters'effects on the system dynamics were analyzed and summarized.

分别建立六自由度刚性连接模型、八自由度刚性铰接模型和十二自由度非刚性连接模型,着重分析了系统的基本运动特性、回收物-伞体间的相对运动特性,以及主要设计参数对系统性能的影响;并将不同复杂程度的模型进行对比,分析了各种模型的特点和适用范围。

Blood-brain barrier in tumors and peritumoral oedematous regions had the same variations in ultrastructure.

瘤体和瘤周水肿区血脑屏障超微结构变化无明显差异,内皮肿胀,毛细血管腔狭小,胶面有稀疏的绒毛样突起,内皮为无孔型,胞质内胞饮泡较多,内皮紧密连接增长,细胞连接间隙增宽,基膜完整,胶质膜缺损。

According to the experience of the research of the indoles alkaloid, we designed a series of novel compounds which contained indoles heterocyclic as the flat aromatic group, benzyloxy substituent at indoles 6 site as the nonhydrophilic group tail, carboxylic derivatives and TZDs bioisosterism substituent at indoles 2 site or 3 site as the hydrophilic group head.

于是根据我们课题组多年来对吲哚生物碱研究的经验,我们设计了以吲哚作为中间平面芳环体系,6位连接苄氧基作为疏水尾部,2位或3位连接羧酸及其衍生物、噻唑烷二酮及其电子等排体的一系列化合物。

Normative references GB 150 steel pressure vessel GB 152.1 ~ 152.4 fastener hole and Shen Kong GB 196 commonDast Gate Valves thread of basic dimensions (diameter l ~ 600mm) GB 197 common thread of tolerance and fit (diameter of 1 ~ 355mm) GB 798 live bolt GB 897 stud bm = ld GB 898 stud bm = 1.25d GB 901 Dlass B and other long stud GB 5782 Hexagon head bolts B and B class GB 5796.1 ~ 5796.4 Dl 150, 300, 600 Lb Dast Steel Gate Valvestrapezoidal thread GB 6175 2 Hexagon nut B and B class GB 9112 types of steel pipe flanges GB 9113.1 ~ 9113.26 Integral steel pipe flanges GB 12220 Universal Valve Logo GB 12221 length of theDl 900, 1500 Lb Dast Steel Gate Valves valve structure of metal flange GB 12222 Multi-turn valve actuator attachment GB 12224 General requirements for steel valves GB l2228 General Valve carbon steel forgings GB 12229 Universal Valve carbon steel castings GB 12230 Universal Valve austenitic steel castings GB / T 12252 General requirements valve supplier ZB Jl6 006 test and test valve 原文来源:http://www.1zhafa.com

引用标准 GB 150 钢制压力容器 GB 152.1~152.4 紧固件通孔及沉孔 GB 196 普通螺纹基本尺寸(直径l~600mm) GB 197 普通螺纹公差与共同(直径1~355mm) GB 798 活节螺栓 GB 897 双头螺柱bm=ld GB 898 双头螺柱bm=1.25d GB 901 等长双头螺柱 B级 GB 5782 六角头螺栓 B和B级 GB 5796.1~5796.4 梯形螺纹 GB 6175 2型六角螺母 B和B级 GB 9112 钢制管法兰类型 GB 9113.1~9113.26 整体钢制管法兰 GB 12220 通用阀门标记 GB 12221 法兰连接金属阀门结构长度 GB 12222 多回转阀门驱动装配的连接 GB 12224 钢制阀门一般要求 GB l2228 通用阀门碳素钢锻件技术条件 GB 12229 通用阀门碳素钢铸件技术条件 GB 12230 通用阀门奥氏体钢铸件技术条件 GB/T 12252 通用阀门供货要求 ZB Jl6 006 阀门的试验与检验

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