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连二亚硫酸钠

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NaHCO3 (0.1 M) buffered 0.1 M sodium dithionite (Na2S2O4) at 40 °C was used to release soluble reactive PBD from FeIII oxyhydroxides under low redox conditions.

碳酸氢钠( 0.1米)缓冲0.1米的连二亚硫酸钠( Na2S2O4 )在40 ° C被用来释放可溶性反应PBD从FeIII oxyhydroxides低氧化还原条件。

The reaction of polyfluoroalkyl iodides with 4-pentenoic acids in the presence of sodium dithionite at room temperature in aqueous acetonitrile solution [CH〓CN: H〓O=3: 1 ] to gave the corresponding adducts, the latter could form γ-lactones 31~51 in the same medium in 62~92% yield.

室温下,在乙腈/水[3:1]的介质中,多氟烷基碘化物在连二亚硫酸钠的存在下与4-戊烯酸及其在2或3位上具有取代基团的衍生物进行反应,反应2~5h,起先生成两者的加成物,该加成物无需分离,在同一介质中,可进一步反应得到相应的多氟烷基取代的γ-丁内酯31~51,产率62%~92%。

To prepare THFA from folic acid , catalytic hydrogenation and high-pressure hydrogenation, reduction by borohydride and reduction by dithionite were investigated. Especially, the technology of catalytic hydrogenation and reduction by borohydride were optimized.

本文研究了常压氢化法、加压氢化法、硼氢化物还原法及连二亚硫酸钠还原法制备四氢叶酸,并优化了常压氢化法、硼氢化物还原法的工艺条件。

The influence of each condition on the reaction speed and yield was studied, and the optimal conditions were: the ratio of the amount of substance of aromatic amine and heptafluoro-isopropyl iodine was 1:1.1~1.5, the amount of substance of sodium dithionite, sodium bicarbonate, aniline compounds were respectively 1.1~1.3, the amount of substance of phase transfer catalyst TBAB and aniline compounds was 0.05~0.1, the concentration of aniline compound was 0.5~1.0 mol/L, reaction temperature was 10~20 ℃, and the solvent was aether.

最佳结果为:芳胺与七氟异丙基碘的物质的量比1:1.1~1.5,连二亚硫酸钠、碳酸氢钠与苯胺的物质的量分别为1.1~1.3,相转移催化剂四丁基溴化铵与苯胺的物质的量比在0.05~0.1,溶剂总用量使苯胺浓度在0.5~1.0 mol/L;反应温度10~20℃;溶剂采用乙醚。取代基供电子性越强,反应时间越短,产率越高;氨基的对位优先反应,氨基的邻位较难发生反应;且七氟异丙基总是优先取代在芳环电子云密度较高的位置上。

The reaction of polyfluoroalkyl iodides with 4-pentenoic acids initiated by sodium dithionite was realized to give polyfluoroalkyl substituted lactones.

我们研究了多氟烷基碘代烷与4-戊烯酸类化合物等在连二亚硫酸钠引发下的反应,得到了氟烷基取代的内酯化合物,我们将该反应称为氟烷基化内酯化反应;并建立了一个利用该反应合成含氟内酯的新方法,首次利用氟烷基化内酯化反应进行高立体选择性双环含氟内酯及手性含氟内酯等的合成,已合成含氟内酯新化合物50余种。

However, the sulfonate CF3CFBrOCF2CF(CF3)O(CF2)2SO3Na reacted with sodium dithionite to give only the hydrodebromination product.

7的水解产物CF3CFBrOCF2CF(CF3)O(CF2)2SO3Na(11)与连二亚硫酸钠反应只得到氢化脱溴产物。

Aniline compounds containing heptafluoroisopropyl was synthesized through taking sodium dithionite as evocating agent, and introducing heptafluoroisopropyl by free radical electrophilic substitution on benzene ring.

连二亚硫酸钠为引发剂,在苯环上通过自由基亲电取代反应引入七氟异丙基,合成了一系列含七氟异丙基的苯胺类衍生物,研究了各种条件对反应的速度和收率的影响。

Polyfluoroalkyl iodides could react with unsaturated olefin acids in the presence of sodium dithionite by radical addition to give adducts. It was found that these adducts could form polyfluoroalkyl substituted γ or δ-lactones due to intramolecular nucleophilic substitution in the alkali solution.

研究发现:多氟烷基碘化物在连二亚硫酸钠存在下与不饱和烯酸经自由基加成得到的产物,能在碱性条件下进行分子内亲核取代反应形成五元或六元环的含氟内酯类化合物。

Methods The cardiac myocytes model of myocardial ischemia reperfusion injury was induced with sodium dithionite (Na2S2O4). The primary cultured cardiac myocytes of SD neonatal rats were randomized into six groups: normal group, model control group, high-dose β-asarone (25 μg/mL), middle-dose β-asarone group (12.5 μg/mL), low-dose β-asarone group (6.25 μg/mL) and medium group.

采用连二亚硫酸钠(Na2S2O4)建立心肌细胞MIRI模型,将原代培养的SD大鼠乳鼠心肌细胞分6组:正常对照组、MIRI模型组、β-细辛醚高、中、低剂量组(25, 12.5, 6.25μg/mL)、基质组。

The changes of total reducing substances, oxalate extractable Fe, dithionite citrate bicarbonate extractable Fe and phosphorus adsorption in oxic and anoxic layers of two paddy soils during 6 week flooding were examined under laboratory conditions.

在实验室条件下对两种水稻土在为期 6周的淹水过程中,其氧化层和还原层土壤中还原物质总量、草酸盐可提取铁、连二亚硫酸钠-柠檬酸-碳酸氢钠可提取铁和磷吸附的变化进行了研究。

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