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The content of Ni〓 in the reduced catalysts and the amount of dialkylmethylamine as main by-product in the amination products were closely related.

将催化剂的还原性能和催化剂进行胺化评价反应的选择性数据进行关联,发现催化剂的选择性和CuO的还原性能无关,而和NiO的还原程度密切相关。

As temperature increased from 40 to 70℃, ferric reduction capacity of microorganism biocoenosis from Jilin, Tianjin and Hunan paddy soil were restrained to a certain extent. Adding AQDS could increase ferric reduction rate of microorganisms biocoenosis from Jilin, Tianjin and Sichuan paddy soil significantly. In axenic culture treatment of 6 kinds of bacterial strain experiments from Sichuan and Jiangxi paddy soil, a bacterial strain was suitable to 50℃.

于40~70℃升温处理后,来源于吉林、天津和湖南水稻土微生物群落的铁还原能力受到一定程度抑制;添加AQDS可显著增加来源于吉林、天津和四川水稻土的3种微生物群落的铁还原反应速率;在6株铁还原菌的纯培养试验中发现了1株更适于在50℃下生长的菌株。

5 kinds of paddy soil treatments were studied, then each microorganism biocoenosis was extracted or bacterial strain was dissociated. Artificial synthesis ferric oxide was considered only electron acceptor, which inoculated soil leaching liquor or bacterial strain with reduction function in mineral salt culture system under anaerobic constant temperature condition. After different temperature treatments towards leaching liquor, temperature was controlled and AQDS added into culture system in order to discuss the effect of temperature and AQDS on ferric oxide microorganism reduction process.

采用5种水稻土为供试材料,分别提取微生物群落或分离铁还原菌株;以人工合成氧化铁作为惟-电子受体,在无机盐培养体系中接种土壤浸提液或具有铁还原功能的菌株,厌氧恒温培养;通过对接种液的不同温度处理(40, 50, 60, 70℃)、对培养温度的控制(30和50℃)以及向体系中添加AQDS,探讨温度及AQDS对氧化铁微生物还原过程的影响。

The influence of the ore fineness and the reductant content on the deoxidization process was studied.

摘 要:以生物制剂KZSH01作为还原剂与铁锰多金属矿发生氧化还原反应,研究了铁锰矿的细度和还原剂的含量对还原效果的影响,考察了还原过程中温度和物相的变化,探讨了H2SO4用量对Mn和Zn浸出效果的影响。

He hypothesis has been proved by SEM and TEM. The characterization of TPR and XPS showed that there had reduction process of oxide species before crystallization, and the reduced species and metalloid content increased generally on the surface of catalysts.

PR和XPS表征证实在负载型非晶态合金Ni-P/TiO〓的晶化温度前,有金属氧化物种的还原过程,还原后,催化剂表面的还原态物种增多,类金属相对含量普遍增加。

Each of them exhibited sensitive reduction responses of nitryls. It was found that the reduction peak of nitryl of the position 4-nitrate group of 2,4-dinitrophenol showed great difference from that of the position 5-nitrate group of 2,5-dinitrophenol. The difference between the two reduction potentials was as large as 180 mV.

在pH=5.0、0.1mol/LNaAc-HAc缓冲体系中,2,4-二硝基苯酚和2,5-二硝基苯酚在碳纳米管修饰电极上出现灵敏的硝基还原峰,其中2,4-二硝基苯酚分子中四位硝基的还原峰和2,5-二硝基苯酚分子中五位硝基的还原峰显示出明显差异,二者峰电位差达180mV。

A process for reducing nitryl with unstable guanyl on para-position of benzene ring into azyl features that active metal reacts on organic acid and solvent at ordinary temp. and pressure to reduce N-(2 or 3-M, 5 or 6-M',4-nitrophenyl)-N',N'-dimethyl acetamidine into N-(2 or 3-m, 5 or 6-M', 4-aminophenyl)-N',N'-dimethyl acetamidine, where M=H,-R,-OR,-COOR (R=H, C1-C6); and M'=H,-R,-OR,-COOR (R=H, C1-C6). Its advantages include reduced by-reaction and high reducting rate up to 80%-95%.

本发明是将苯环上对位带有不稳定脒基的硝基还原为氨基的方法,采用活泼金属,如:锌或锡,与有机酸和适当的溶剂,在常温、常压下发生反应,将N-(2或3-M,5或6-M',4-硝基苯基)-N',N'-二甲基乙脒还原为N-(2或3-M,5或6-M',4-氨基苯基)-N',N'-二甲基乙脒,其中M=H,-R,-OR,-COOR(R=H,C1-C6),M'=H,-R,-OR,-COOR(R=H,C1-C6),减少了副反应,使还原收率达到80%以上,最高可达95%以上,更适用于工业化生产。

This paper introduces the major equipment of the polysilicon reducing furnace electrical system ,and emphasizes the working prin-ciples of preheating voltage regulator and reducing voltage regulator.

介绍了多晶硅还原炉电气系统的主要设备,着重分析了预热调压器和还原调压器的工作原理,并且提出了一种新型的还原调压器设计思想,减少了谐波含量,提高了功率因数。

The overall yield was 43.6%.The yield of reduce of ester was increased nearly one times than the past method because of KBH4-LiCl as the reducing agent instead of NaBH4. Changing the reaction conditions of bromization, the one-way yield enhanced 30%. The yield of reduce of the bromide was added by one times by improving the process. Tefluthrin was achieved by the catalytic esterification of DCC and DMAP.

优化后工艺对四氟对苯二甲酯的还原采用了廉价高效的还原试剂KBH4-LiCl,使收率比NaBH4法提高了近一倍;对溴化反应条件进行了优化,单程收率提高了30%;对溴化物还原条件的优化,使其收率提高了近一倍;采用了催化剂DCC和DMAP合成了最终产品七氟菊酯。

This article reviews three kinds of methods for manufacture halogenated aromatic amine ,and the strong and weak points of the three reduction methods are pointed out.

本文综述了由卤代芳硝基物还原制备卤代芳胺的三种方法,并对几种还原方法的优缺点进行了对比和讨论,得出水合肼还原具有很好的应用前景。

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