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Reductive dechlorination of chlorinated Endocrine Disrupting Chemicals in Water by metallic catalytic reduction was studied for further understanding the application of palladiumized iron-scrap bimetallic catalytic reduction technology in treating high molecular weight and structure complicated refractory chlorinated organic pollutans, especially, the reductive dechlorination reaction of the three chlorinated EDCs: 2,4-dichlorophenoxyacetic acid(2,4-D), Hexachlorocyclohexane, and chlordane.

通过研究水体中有机氯类环境内分泌干扰物在金属催化还原体系中的还原脱氯反应,考察了铁屑镀钯双金属催化还原技术在处理水体中大分子量复杂结构的难降解氯代有机污染物的应用,着重研究了水体中2,4-二氯苯氧乙酸(2,4-D)、六六六和氯丹三种有机氯类环境内分泌干扰物在Pd/Fe催化还原体系中的还原脱氯行为。

A new concept of turning line of reduction parameters and its determination method is put forward in this paper for analyzing the isopleth diagram showing the relationship between reduction degree and reduction parameters in reduction of compressed scale lump containing carbon, and the method of optimal selection for reduction parameters is obtaine

应用文章提出的还原参数界线概念及其确定方法对铁鳞配焦压块还原过程中反映还原参数与还原指标关系的等高线图进行分析,得出还原参数优化选择的具体方法。

It was found that low hydrogen purity and high moisture content of the hydrogen used for deoxidation was the main cause. Countermeasures such as exhausting 90% of the waste gas from the deoxidation process to hydrogen recompression system to reduce the water content in deoxidation zone, and using hydrogen from PSA unit to replace recycle hydrogen to increase the hydrogen purity, were adopted.

参考UOP公司及其它重整装置的经验,对重整催化剂还原工艺进行了改进,将90%的还原废气排入增压氢系统,可有效降低还原区的水含量;用PSA氢替代循环氢,可进一步提高还原区氢纯度,从而提高还原反应速度,改善再生催化剂的性能,使重整反应的芳烃产率有所提高。

The result of thermodynamic calculation shows that the reduced products of V_2O_5 carbothermic reduction is the carbide of vanadium,the system of silicothermic reduction should add CaO, aluminothermic reduction can reach a reduc- tion rate of 99%,the reduction ability of Al is more effective than that of C and Si.

热力学计算结果表明,V_2O_5碳热还原产物是V的碳化物;硅热还原体系中需配加CaO;铝热还原可以得到99%的还原率,Al的还原能力比C和Si都要强。

In the paper, some factors influencing the effect of reduction including the anodic material, the cathodal material, the area ratio of cathode to anode and the kind of electrolyte have been investigated and screened out. The result showed that under the same reduction conditions, the reduction of Cr6+ has better effect to use lead-antimony alloy as anode, iron plate as cathode, which area ratio is 7:1 and potassium sulphate as electrolyte.

本文首先对影响电解还原效果的阳极材料、阴极材料、阴阳极面积比和支持电解质加入的种类等因素进行了研究筛选,结果表明:在同样电解还原条件下,实验中阳极采用铅-锑合金,阴极采用铁板,阴阳极面积比取7∶1,支持电解质取为硫酸钾时,具有较好的Cr~(6+)还原效果;同时在采用铅-锑合金作阳极的条件下,通过正交实验,对影响直接在碱性介质中电解还原低浓度含铬废水的其他因素进行了研究,即研究了在电化学还原过程中,Cr~(6+)的初始浓度、极板间距、支持电解质的加入量、搅拌情况等因素对还原效果的影响程度,确定出了主要的影响因素。

Study shows that environment evolution and eustatic change of Holocene in this area may be divided into 6 stages:① early stage of early Holocene, 9 100~10 900 aBP,when sea level was low and this area was an oxidizing environment or oxidizing-reducing transition environment;② late stage of early Holocene, 8 000~9 100 aBP, sea-level rising,...

研究表明,本区全新世环境演化分为6个阶段:①早全新世早期,10900~9100aBP,海平面较低,尚未淹没本区,为近岸氧化环境或氧化—还原过渡环境;②早全新世晚期,9100~8000aBP,海水上涨,本区时淹时退,为浅海或潮坪环境,生物钻孔发育;③中全新世主体,8000~4150aBP,海平面快速上升,完全淹没,Fe2+/Fe3+介于0.7395~1.9123之间,为全新世中最高段,表明还原程度强、全球气候变暖;④中全新世后期,4150~2850aBP,海水有所下降,仍为浅海环境,Fe2+/Fe3+较高,多在1.0以上;⑤晚全新世,2850~1310aBP,海平面进一步下降,本区时常暴露,其中2150~1310aBP以还原环境为主,为潮下带,2150~2850aBP以氧化—还原过渡环境为主,为潮间带;⑥1855AD以来,海平面基本稳定,稍有上升,为现代黄河三角洲沉积时期。本区全新世至少存在5期冷热交替的旋回性气候变化。

The nanocrystalline film was composed of a three-diminsional network of interconnected particles.Reodx behavior and electrocatalytic activities of the Ti/nano-TiO2 electrode were investigated by cyclic voltammetry from oxalic acid and nitrobenzene to glyoxalic acid and p-aminionphenol. The Ti/Ti redox system,as a medium,shows highly electrocatalytic activities and stable characteristic to indirect electroreduction of organic compounds(e.g.:oxalic acid and nitrobenzene).

循环伏安法研究了纳米TiO2膜电极对草酸还原为乙醛酸、硝基苯还原为对氨基苯酚反应的电催化活性,结果发现纳米膜中的Ti/Ti氧化还原电对起一种中介作用,可使有机物如草酸和硝基苯间接电还原,且电极催化活性高,性能稳定。

Colloidal gold was reductively prepared by sodium citrate,sodium citrate-tannin,ascorbic acid and sodium borohydride respectively.And corresponding gold particles size,morphology,dispersion,and stability of the samples were characterized and compared.

分别采用柠檬酸钠还原法、柠檬酸钠-鞣酸还原法、抗坏血酸还原法、硼氢化钠还原法4种方法制备了粒径为十几纳米的胶体金,并对制得的纳米胶体金粒径大小、分散度、稳定性及形貌进行了表征和比较分析。

On these grounds, a new method, the divided steping reduction, was put forword to prevent sticking phenomenon for pre-reduced fluidized-beds of smelting reduction, i. e. concentrate is reduced under the temperature and composition of gas first for the thick morphology of iron, to a certain metallized rate, and then for the whiskery morphology of iron.

据此,提出了一种新的旨在预防熔融还原预还原流化床粘结现象的措施——分段还原法,即先将铁精矿置于铁以致密状析出的温度和气氛下还原至一定的金属化率,而后再在铁晶须析出的温度和气氛下进一步深还原。

State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, ChinaSoil and sediments are anoxic and anaerobic environment, often containing high levels of Fe due to the interaction of iron reducing bacteria with iron oxide minerals which are widely present in subsurface.

在土壤和沉积物的自然厌氧环境中,铁氧化物可被铁还原菌等微生物异化还原产生Fe,形成的Fe/铁氧化物表面结合铁系统具有还原活性,可使有机污染物还原转化。

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