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还原电位

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Changes of physical characters and evaluation of wine processed by UHP were studied,the result is: the relative density, boiling-point,conductivity,redox potential,total acid and the taste and flavor of the wine were changed,the dioptre did not change.

通过对超高压处理后新鲜葡萄酒的感官变化及物理特性的研究,结果表明:超高压处理对葡萄酒的相对密度,沸点,电导率,氧化还原电位,总酸含量以及口感风味均有一定的影响,对葡萄酒的对折光度不影响。

The results showed that the maximum UV absorption wavelengths of those 1,3,4-oxadiazole derivatives in dichloromethane were in the range of 268~327 nm, and their maximum photoluminescent wavelengths in dichloromethane and solid film were located at 332~390 nm and 359~439 nm, respectively. The 1,3,4-oxadiao1e derivatives exhibit a first endothermal peak at 120~328℃ in the DSC heating process, and the symmetrical 1,3,4-oxadiazole derivatives display a higher melting temperature. The CV curves of those 1,3,4-oxadiazole derivatives indicate that the reductive potentials of the 1,3,4-oxadiazole derivatives are located at -1.03~0.98 V, and their LUMO(the lowest unoccoupied molecual orbit) energy levels are -3.71~-3.76eV.

结果表明,该类衍生物在二氯甲烷溶液中的最大紫外吸收波长在268~327nm范围,在二氯甲烷溶液和固体膜中的最大荧光发射波长分别在332~390nm和359~439nm范围;DSC分析结果表明,5个噁二唑衍生物的起始吸热峰位于120~328℃之间,其中对称结构的噁二唑衍生物显示了较高的熔融温度;由循环伏安图和相关计算结果表明,5个噁二唑衍生物的还原电位位于-1.03~-0.98V,其相应的最低非占有分子轨道能级在-3.71~-3.76 eV之间。

Upon CV and DPV experiments, the reduction and oxidation potential of these porphyrins were shown to be similar to each other. This suggests that different PAHs ethynyl substitutes would have similar effects on electrochemical properties of the porphyrin molecule.

在电化学探讨部份,接上不同多环芳香族取代基的紫质分子之氧化还原电位彼此都相当类似,表示这些紫质光敏剂的能隙相当接近,不同的多环芳香族取代基对於紫质分子的电化学性质影响程度相当接近。

In the serum bottle fermentation,potassium ferricyanide and dithiothreitol which did not have inhibition on fermentation,were selected as the oxidizing agent and reducing agent respectively.

在血清瓶发酵培养过程中,筛选出对发酵过程无抑制作用的氧化剂铁氰化钾和还原剂二硫苏糖醇作为发酵体系的氧化还原电位调节剂。

Without imidazole, holo proteins of these two mutants are unstable at the room temperature.

从光谱电化学实验得到的突变体蛋白氧化还原电位较之野生型蛋白质都有大幅度的负移,这也预示了突变体的功能变化。

The stronger and more coordinate bonds between anionic phenolate groups and Fe ions in higher oxidation state prevented the dissociation of central ions.

这些基团的引入提高了中心金属Fe的价态,并增加了配体的电子云密度从而调节了Fe的氧化还原电位

Photosensitizer ; solar cell ; phenolate ligand ; fluorescent spectra ; flash photolysis ; redox potential

光敏染料;太阳能电池;含酚配体;荧光光谱;闪光光解;氧化还原电位

For these experiments the redox potentials increased when hydrogen peroxide was added to the system and after decreased.

对于这些实验的氧化还原电位增加过氧化氢时被添加到系统中后下降。

The valence state and solubility of selenium in paddy soils, the dissolution equilibria of selenium and the valence changes of selenate in soil solution, the influences of redox potential and pH value on valence changes of selenium are discussed theoretically. A characteristic pH-Eh relationship is derived.

从理论上讨论了土壤硒的价态及其溶解性,土壤溶液中不同形态的硒的溶解平衡与可能存在的 Se的变价反应,土壤溶液中硒的价态转换的影响因素,特别是氧化还原电位与pH对淹水土壤溶液中硒的价态变换的影响。

For these experiments the measured variables were: redox potential, pH, temperature, concentration of organic and TOC.

对于这些实验的测量变量有:氧化还原电位,pH值,温度,有机和TOC浓度。

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