还原性

In this chapter, we report the synthesis of an alkyl imidazo lium salt supported chiral sulfonamide ligand and its use and recycling in enantiosel-ective reduction of prochiral ketones to optically active secondary alcohols.

在这里我们报道了一种离子液体接枝的磺酰胺手性配体以及在前手性酮的不对称还原反应中的应用，获得了较好的对映纯过量，实现了手性配体的回收和重复使用。

Preparation of the lateral chain-4-benzyloxy-3-hydroxy butyronitrile is introduced as the substrate, the REFORMATSKY reaction is performed, then obtains the dicarbonyl ester, in the structure of which containing a chiral hydroxyl group, then performs the chiral reduction, take off the benzyl group after the protection reaction with acetonylidene,then obtains the lateral chain by oxidation.

手性侧链醛的合成：采用-4-苄氧基-3-羟基丁腈作为底物，通过REFORMATSKY反应缩合得到含有手性羟基的二羰物酯，再手性还原，丙酮叉保护后氢解脱苄，最后氧化得到侧链醛。

It was found from structure-electrochemical studies of hemoglobin that (1) electroreduction induces the T→R transition with chirality transition and umbrella conversed effect;(2) electric field induces the secondary structural transition between two α helices, which is smilar to the denaturalization of the protein;(3) The electrochemical reaction mechanism of EC including T→R transition and parameters have also been obtained.

在血红蛋白的结构-电化学研究中发现：（1）电化学还原诱导血红蛋白的T→R构型转化，手性转化的伞翻转效应；（2）电场诱导血红蛋白的两种α螺旋二级结构间的转化，属于电场诱导血红蛋白的部分变性；（3）获得血红蛋白电化学还原的包括R→T转换的EC机理和参数

Ammonia and nitrate, ferrous ion, sulfide, various gases and organic acids are sequentially formed, corresponding to the activities of aerobic and facultatively anaerobic bacteria, sulfate-reducing bacteria, and methane-producing bacteria with the development of reduction reactions.

在还原过程中，随着好氧细菌、兼性厌氧细菌、硫酸还原菌和甲烷菌的活动，相继形成氨、硝酸根离子、亚铁离子、硫化物、气体物质及有机酸。

The UV-vis and redox data indcated that the molecular plane was destroied by meso ethyl.λ〓 hypsochromic 52 nm and W〓 increase. Redox potentials increase, too.

染料的UV-vis吸收光谱和氧化还原电位结果表明中位乙基的引入破坏了染料分子的平面性，使得染料的λ〓蓝移52nm，半峰宽增大；氧化、还原电位均升高。

Methods: NO-3 was restored with cadmium column assay and NO-2 was detected with leavy nitrogen assay. The primitive NO-3 and total restored NO-2(NO-3/NO-2) in plasma of patients with chronic hepatitis and cirrhosis as well as ET-1 with radioimmunology, ALT with Lai's assay were determinated.

取慢性乙型肝炎及活动性肝硬化患者血浆，用镉柱法还原NO-3，重氮法测NO-2，计算血浆中原有及NO-3还原后NO-2总和(NO-2/NO-3)，放免法测ET-1和赖氏法测定ALT。

Reducing agent carbon reduces oxide of cobalt, nickel and iron,and sulfuring agent Fe_2S forms trickles of matte at high temperature, inthe process of assembling and settling of trickles of matte slag is washed,reduced metals of iron, cobalt and nickel and sulphide in slag are enrichedin the matte to form cobalt matte and be separated from slag due to theirintimity to the matte, washing of the matte and their settling.

在高温下，还原剂碳将钴、镍、铁氧化物还原成金属，同时硫化剂硫铁矿形成锍滴，在锍滴聚集沉降过程中对炉渣进行&洗涤&，由于金属及金属硫化矿的亲锍性，锍体的&洗涤&作用及金属及金属硫化矿的沉降作用使被还原的钴、镍、铁金属及转炉渣中的金属硫化矿富集到锍体中，与转炉渣分离，形成钴冰铜。

Then we applied these chrial ligands to asymmetric borane reduction of w-bromoacetophenone and diketones.

将其应用于前手性单酮及二酮的还原中，其中双方酰化脯氨酸在1，6-二苯基-1，6-己二酮的还原反应中可获得最高为90％的ee值。

The first part is concerned with catalytic asymmetric borane reduction of aromatic ketones. Up to 83% ee could be obtained with 10 mol% Al3/BINOL2 complex as catalyst.

在不对称硼烷还原反应方面，利用BINOL作为掌性配位基与Al3组成催化系统还原芳香酮类，反应过程方便快速，最高可获得83%的镜像超越值，我们也推测了可能的反应机构并用以解释所得产物的立体化学组态。

P species, main as Ca-P and organic P forms, showing rego〓 pollution and karst area of lake watershed, inorganic P〓 related to Ca〓, Al〓, Fe〓 content in the overlying water, sediments is not a simple reservoir of dissolved phosphate and particle phosphate, near the interface, near 98% of total P existed as active forms, they may release to overlying water through reduction dissolution, deadsorption in the period of early diagenesis, only 2% of P as fixed forms, which mainly remained in the sediments, sediment was an important resource of nutrients of ovrelying water.

高原湖泊沉积物中的磷以有机磷和Ca-P形式存在为主，反映了高原湖泊流域污染和碳酸盐地区的整体背景，无机磷形式与水体吸附体Ca〓，Al〓和Fe〓的含量有关。底部沉积物不是溶解性磷酸盐和颗粒磷酸盐的长期储存场所，几乎有98%的磷是活性的形态存在，它们通过早期成岩作用在还原条件下还原，溶解和释放又重新回到上覆水体，只有2%的磷以固〓态的形式稳定保存于沉积物中，因此，沉积物为水体营养程度的重要来源。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。