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Part one (chapter 1~4) is about the coppermediated biomimetic oxidation of naphthols and 2-naphthylamine.

中文题名氧化还原酶模型及在仿生有机合成中的应用副题名外文题名 The model of oxidoreductases and its application in biomimetic organic synthesis 论文作者谭端明导师许遵乐教授学科专业有机化学研究领域\研究方向学位级别博士学位授予单位中山大学学位授予日期2002 论文页码总数172页关键词模拟酶氧化还原酶仿生氧化铜胺络合物抗肿瘤药物馆藏号BSLW /2003 /O629 /5 本文包括两部分内容:第一部分(1~4章)为萘酚类和2-萘胺化合物在含铜化合物作用下的仿生氧化偶合反应研究。

It was found that tignite and its char have their NO re d uction efficiency higher than those of other coals and chars.The content of vola tile in coals,surface area of the chars and the content of metal catalyst in ash are all important factors affecting the NO reduction efficiency.

实验结果表明,褐煤及褐煤焦对NO的还原能力明显强于烟煤和烟煤焦,煤粉挥发分含量、煤焦颗粒的比表面积和煤灰中的金属氧化物含量都对NO还原有重要的影响。

Drugs of beta-hydroxy-beta-methylglutaryl coenzyme A reductase inhibitors family are usually used as a very effective lipid-lowering preparations but they simultaneously block biosynthesis of both cholesterol and ubiquinone Q10, which is an intermediate electron carrier in the mitochondrial respiratory chain. It is known that reduced form of ubiquinone Q10 acts in the human LDL as very effective natural antioxidant.

HMG-CoA还原酶抑制剂是非常有效的降脂药物,但它同时抑制胆固醇和辅酶Q的生物合成,而其中辅酶Q是线粒体呼吸链中的中间电子载体,其还原形式在人LDL中是有效的天然抗氧化剂。

The possibility to obtain the titanium nitride from this process was asserted by thermodynamical analysis and by the means of X-ray diffraction and SEM.

首先,对钛白粉、活性碳用碳热还原反应合成氮化钛进行了热力学分析,证明了碳热还原反应合成氮化钛的可行性。

The mainly conclusions in our research are as flowing: tungsten trioxide powders with 100 nm primary particle are obtained by spray drying,calcination and wet milling process, and an average size of quadric particle composed of agglomerated particles is 0.64 μm; tungtsen powders with 39 nm grain size and 60 -100 nm primary particle are produced directly from previous tungsten trioxide using one step reduction in hydrogen at 700℃, and an average size of quadric particle of tungsten powder is 2.91 μm; tungsten trioxide and copper tungstate compound powders with 100 nm - 200 nm primary particle are produced using ammonia metatungsten and copper nitrate as raw materials by spray drying,calcination and wet milling process;the compound powders are transformed completely into tungsten and copper compound powders by reduction in hydrogen at 700℃,in which tungsten grain size is 59 nm and copper grain size is 51 nm; primary particle size of compound powders is 80 - 120 nm,and an average size of agglomerated quadric particle is 1.86 μm; tungsten nitride powders with 35 nm grain size are prepared from tungsten trioxide powders by nitrogen treatment thoroughly in pure ammonia at 650℃, and an average size of agglomerated quadric particle is 0.64 μm in normal temperature.

研究结果表明:采用喷雾干燥—焙烧—球磨工艺可以制备出粒度约为100nm的WO_3粉体,它们在团聚后形成的二次颗粒平均粒度为0.64μm;采用一步直接氢还原方法可在700℃下从上述WO_3粉体制备出晶粒尺寸为39nm的、一次颗粒粒度为60-100nm的W粉体,其二次颗粒的平均粒度为2.91μm;以偏钨酸铵、硝酸铜为原料,采用喷雾干燥—焙烧—球磨工艺可制备出一次粒度为100-200nm的WO_3和CuWO_4混合粉体;采用氢还原工艺可在700℃下将这种粉体完全转变为W、Cu复合粉体,其中W的平均晶粒粒尺寸为59nm,Cu的平均晶粒尺寸为51nm;复合粉体的一次颗粒尺寸为80-120nm,在常温下团聚后形成的二次平均粒度为1.86μm;采用纯氨氮化工艺可以在650℃下由WO_3粉体制得WN,其晶粒尺度为35nm,在常温下团聚后的二次平均粒度为6.4μm。

Having reviewed a large number of relevant literature in detail, combined with some research achievements at sandstone type uranium deposits in China and abroad, The authors try to make an overview of the role of sulphides, particularly the pyrite, in the reduction, precipitation and concentration of uranium at the redox front of sandstone type uranium deposits.

作者通过大量的相关文献的调研,结合国内外在砂岩型铀矿研究方面取得的成果,对硫化物,特别是黄铁矿在砂岩型铀矿氧化-还原前锋线附近铀还原、沉淀和富集过程中所起的作用提出了自己的认识。

A new method of two-dimensional electrophoresis is introduced, and applied to analyze protein subunits.

摘要介绍了还原条件与非还原条件双向电泳法,并应用此方法研究了种子蛋白质亚基结构。

The reductive hydrogenation of sterols is stronger downward with the depth,and that is much stronger in Site 8 than in Site 17 due to the different sedimentary circumstances.

随着沉积深度的增加,甾烯醇的加氢还原作用越强,且由于两个站位不同的沉积环境,8站位甾烯醇的加氢还原作用更强。

At the same time, the conversion efficiency of NO〓to N〓 was improved by plasma and the selectivity to N〓 formation was enhanced from 1.1% to 1.53%. 4. TPR experiment of simultaneous removal of PM and NO〓 were carried out by plasma/catalysis techniques. The PM was obtained by putting the γ-Al〓O〓 spherules in the diesel exhausts.

选用75%负荷工况挂烟得到的PM的程序升温反应试验结果显示,CO〓和N〓产生在相同的温度范围,表明PM的氧化和NO〓还原同时发生,而且是NO〓和PM的相互作用的结果,并且,PM燃烧得到的程序升温反应曲线是双峰曲线,NO〓在低温段和高温段分别被可溶性有机物SOF和干碳烟DS还原

The experimentally identified math-model of iron ore reduction in moving bed is developed to describe the practical process in industrial reactor.

提出了一个移动床还原过程的数学模型,并由实验证实,这一模型也能描述实际工业规模的铁矿石移动床还原反应器。

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