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In the development of reduction clearing agent, first we selected several surfactants according to the capacity of removing the oligomers and good emulsification, then mixed these activators and obtained washing agent W. Mixing the agent H and washing agent W, the reductive clearing agent WS was acquired.

还原清洗剂的研制中,以分散性好、对低聚物有去除作用以及良好的乳化能力为基准,选取了几种表面活性剂,然后对选取的表面活性剂进行复配,得到了助洗剂W;将还原剂H与助洗剂W复配,得到了还原清洗剂WS。

According to the strong reducibility of lithium aluminium hydride and asymmetric selectivity of binaphthol,the authors reduce camphor into D-borneol by using D-binaphthol modified lithium aluminium hydride as chiral reagent.

根据氢化铝锂的强还原性和联萘酚的不对称选择性,用右旋联萘酚改性过的氢化铝锂为手性试剂,把樟脑还原成右旋龙脑。

This paper introduces the new concept—— electrode potential axis used in the electrochemical redox reaction.

介绍了一种电化学中氧化还原反应的新概念——电极电位轴,它对电池的电动势、极性、电子流动方向以及相关的化学反应的描述很直观,是一种较为理想的判断氧化还原反应的方法。

Part Ⅰ The Research of Chiral Phosphorus Catalysts in the Enantioselective Borane Reduction of Prochiral Ketones ABSTRACT In this paper, the preparation of varied types of chiral phosphorus ligands and their applications as catalysts in the asymmetric borane reduction of prochiral ketones were investigated.

第一部分对映选择的潜手性酮的硼烷还原反应中手性磷催化剂的研究本文研究了多种不同类型的手性磷配体催化剂的合成及其在酮的不对称硼烷还原反应中的应用。

The best results 98% ee, 94% ee and 59% ee were obtained in silylcyanation of aldehydes, borane reduction of prochiral ketones and ketimines, respectively.

醛的硅氰化反应ee值最高达到98%,酮的硼烷还原反应ee值达94%,而亚胺的硼烷还原反应ee值只有59%。

Then we applied these chrial ligands to asymmetric borane reduction of w-bromoacetophenone and diketones.

将其应用于前手性单酮及二酮的还原中,其中双方酰化脯氨酸在1,6-二苯基-1,6-己二酮的还原反应中可获得最高为90%的ee值。

The first part is concerned with catalytic asymmetric borane reduction of aromatic ketones. Up to 83% ee could be obtained with 10 mol% Al3/BINOL2 complex as catalyst.

在不对称硼烷还原反应方面,利用BINOL作为掌性配位基与Al3组成催化系统还原芳香酮类,反应过程方便快速,最高可获得83%的镜像超越值,我们也推测了可能的反应机构并用以解释所得产物的立体化学组态。

Thirty-one new chiral phosphorus compounds have been synthesized starting from D-camphor,-alpha-phenylethylamine,-Betti base,-1-(4-nitrophenyl)-2-amino- propane-1,3-diol, L-amino acids (such as serine, phenylalanine, proline etc.) and their application as organocatalysts in asymmetric trimethylsilylcyanation of aldehydes and asymmetric borane reduction of prochiral ketones and ketimines were investigated.

该项目从D-樟脑、-alpha-苯乙胺、-Betti碱、-氯酶胺、L-氨基酸(如丝氨酸、苯丙氨酸、脯氨酸等)出发合成了31个新的手性磷化合物,研究了它们作为有机催化剂在醛的不对称硅氰化反应、潜手性酮的不对称硼烷还原反应以及亚胺的不对称硼烷还原反应中的催化效果。

At first, the initial COD/SO4^2- ratio and pH value were determined, and then the capability of different immobilized carders was investigated by batch experiments.

本工作以提高SRB的还原活性为出发点,通过间歇式实验首先确定适宜的初始COD/SO4^2-比值和pH值,进而探讨固定化载体对SRB还原性能的影响。

The assimilation of nitrate by microorganism is catalysed by nitrate reductase and nitrite reductase.

而硝酸盐同化是通过硝酸还原酶及亚硝酸还原酶而进行的。

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