过渡络合物

This thesis is mainly about the research on the synthesis, structures and reactivity of di-or tri-metal bridging carbene and bridging carbyne complexes

过渡金属桥卡宾和桥卡拜络合物本身即为简单的金属原子簇化合物或是合成金属原子簇化合物的重要前体，在有机合成和烯炔烃的聚合和异构化等催化反应中有广阔的应用前景以及在某些过渡金属参与的反应的机理研究中具有重要的研究价值。

This thesis consists of three main parts of the research work on the syntheses, structures and reactivities of the olefin-coordinated transition metal carbene and carbyne complexes. In chapter 1, on the basis of our previous research works on the reacitivites of the cationic carbyne complexes of transition metals with metalcarbonyl anions, we explored the reactions of the cationic carbyne complexes of manganese (1) and rhenium (2) with polymetalcarbonyl anions, and developed a new method for the preparations of heternuclear trimetal bridging carbyne complexes.

本论文对烯烃配位的过渡金属卡宾和卡拜络合物的合成、结构和反应性能进行了研究，主要进行了如下三方面的工作：第一章在本小组过去的研究基础上，进一步考察锰和铼的阳离子卡拜络合物1和2与羰基金属阴离子化合物的反应，用来合成异核多金属桥卡拜络合物，发展合成多金属桥卡拜络合物的新方法和新路线。

The influence of a transition metal acetylacetone catalyst on the behavior, mechanism and product structure of the co-curing of epoxy and cyanate was studied by DSC and FT-IR.

应用DSC、FT-IR对乙酰丙酮过渡金属络合物催化促进的环氧树酯与氰酸酯共固化反应行为、历程以及固化物的结构特征进行了研究探讨。

B synthesis of β- diketone based side chain liquid crystalline random copolyphenylsisesquioxane and its metal complex.

此类β-二酮可作为高分子液晶中的介晶基元，并具有和大多数过渡金属离子形成络合物的能力。

Electron paramagnetic resonance spectrum is an effective tool to investigate the optical and magnetic properties of crys...

电子顺磁共振谱是研究掺过渡和稀土金属离子晶体及络合物的微观结构、光学和磁学性质等的有力工具。

The complex compound s of transition metal and periodate are classified; their preparation, composition and structure are analyzed.

对过渡金属高碘酸络合物进行分类，分析这些络合物的制备、组成和结构，介绍某些过渡金属高碘酸络合物的电子光谱、红外光谱和核磁共振谱。

The influence of the behavior, mechanism, product structure and relation of structure with properties for co-curing reaction of epoxy resin and cyanate ester system catalyzed by transition metal acetylaceton, etc. was studied.

研究了用乙酰丙酮过渡金属络合物等促进剂催化促进环氧树脂与氰酸酯(在氰酸酯欠量，适量和过量条件下)的共固化反应行为、固化反应的机理、固化物的结构特征以及结构与性能关系。

A2D iim ine nickel, palladium complexes and pyridine bisimine iron, cobalt complexes are discovered in recent years to be new generation late transition metal catalysts for olefin homogeneous poly merization and oligomerization.

A2二亚胺镍、钯络合物和吡啶二亚胺铁、钴络合物是近几年来发现的新一代烯烃均相聚合后过渡金属催化剂。

The resulting organometallics can react with many organic electrophiles,which can tolerate many functional groups. We have synthesized a class of organozinc species and apply them in ring opening of epoxides, affording cis-addition products.

但也因为反应活性低，常常需要在Lewis酸的存在下，或将有机锌试剂用过渡金属络合物转换为相应的有机过渡金属试剂后才可以与多种亲电试剂反应。

It was found that earlytransition metal monoxides ScO, TiO and VO do not form noble gas complexes, whilethe late transition metal monoxides coordinate one noble gas atom in forming thelinear NgMO(M=Cr, Mn, Fe, Co, Ni) complexes.

对于前过渡的ScO，TiO和VO分子，它们的9σ，1δ和4π价分子轨道能量很高，不能有效地与稀有气体原子形成络合物，而对于后过渡金属一氧化物则可以配位一个稀有气体原子形成直线型的NgMO(M=Cr，Mn，Fe，Co，Ni)络合物。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失