过渡元素

In this paper, on the basis of predecessor research,β-diketone derivative ligand, Pyrazolyl ligand and their eight transition metal complexes were synthesized.

本论文是在前人研究的基础上选择合成并表征了一种β-二酮类配体和一种多吡唑类配体及其八个过渡金属配合物，并解析了它们的单晶结构，进行了元素分析、红外光谱、紫外光谱等表征，并研究了它们的发光性能和热稳定性能。

The surface element of the material are not only changed, it is more important that electronic configuration of surface atoms have been changed remarkably, because of doping different metal ion.

我们在利用SPS和FISPS对过渡金属(M＝La，Cu，Co，Ni)复合氧化物系列的研究中发现，由于掺入不同的金属离子，不仅材料的表面元素发生了变化，更重要的是表面原子的电子组态也发生了明显的变化。

The analysis results show that the mother band and solidified layer are bonded through the transition layer formed by element diffusion.

经分析得知母带与凝固层的界面结合是靠元素相互扩散形成过渡区实现的。

In the fourth chapter, four new complexes of hydrazide of podophyllic acid with transition metals have been prepared. Elemental analysis, molar conductivity, IR,〓 NMR and TG-DTA were used to characterize them. The results show that general formula of the complexes is M〓(n=0 or 2). The ligand is linked through the carbonyl oxygen and the terminal nitrogen of the hydrazide base to the transition metal ions in bidentate mode.

第四章 合成了四种鬼臼酰肼的过渡金属配合物，通过元素分析、摩尔电导、红外光谱、核磁共振氢谱和热重-差热对配合物进行了表征，研究结果表明，配合物的组成为M〓（n=0或2），配体是通过羰基氧和肼基上的端氮以双齿形式与金属离子配位的。

Generally speaking, however, the number of discrete signals in animal repertoires seems to be limited (Green and Marler 1979; Moynihan 1970), although reliable repertoire estimates are hard to come by, especially when signals intergrade extensively. Explosive expansion of the repertoire becomes possible if elements of the repertoire can be recombined into new, meaningful utterances, as they are in human speech.

但是，总的来说，在动物的曲目当中，不相关的信号是有限的（格林和马勒1979；莫伊尼汉1970年），尽管可靠的统计难以获取，尤其当信号过渡段很广时，当剧目中的元素可以被重组为新的，有意义的话时，剧目的爆炸性扩张成为可能，就像是在人类语言中一样。

Iron-manganese cutan; matrix soil; manganese oxide; heavy metal element; soil geochemistry; 1.4 nm intergrade mineral; surface chemistry property

农业科技，农业基础科学，土壤学铁锰胶膜；基质土壤；氧化锰；重金属元素；土壤地球化学； 1.4nm过渡矿物；表面化学性质

In a preferred embodiment, M comprises two or more transition metals from Groups 4 to 11 of the Periodic Table.

在一个优选的实施方式中，M包含2种或多种选自元素周期表第4-11族的过渡金属。

After active carbon powder and alloy steel powder are added to the thermit, the self-propagating high-temperature synthesis reaction starts.

本文研究了合金化自蔓延陶瓷内衬复合钢管制造技术，即在铝热剂中加入活性碳粉或合金钢粉末，进行自蔓延高温合成反应，分析了碳和合金元素对复合钢管过渡层的影响。

The crustal sequence of Shexian ophiolites belongs to the transitional series behaeen calc-alkaline basalt and tholeiite and all through has similar trace elements and REE ratios and chondrite-normalized REE patterns, with high enrichment of large-ion lithophile elements and LREE.

歙县蛇绿岩壳层组合属于钙碱性和拉斑玄武岩间过渡系列，具类似的微量及稀土元素比值和稀土元素配分模型，且大离子亲石元素和LREE高度富集。

Through designing of composition and structure of the bioactive graded coating,innerstress and its distribution in the coating were analyzed and calculated, the resultsshowed that when composition distribution coefficient n was 1.5, a reasonable stressdistribution could be got, that was at the beginning of deposition the suspension containingrichly BG granules was used so that a rich BG granules layer, a good transitional layerbetween BG layer at the bottom and the coating could be obtained at the titanium alloy side,the bottom of the coating; the stress value near the interface and surface and its character,pressure stress or tensile stress, were decided by the character of its composition itself.Changing composition distribution coefficient n could only change the variation tendency ofstress in the coating, but did not change the stress distribution rule in the coating. Thethinner the coating is, the sharper stress variation in the coating is, which does not mean thatthicker coating is better because the thicker the coating is, the little the permitteddeformation of coating is, so the coating thickness should be thinner, for example, about50μm for bending applications, but for applications only bearing pure shear stress, such asroot of tooth implant, the coating can be thicker little, for instance, about 80～100μm. The study on electrification characteristic and electrophoresis deposition of HAand BG granules in aqueous and non-aqueous solution system found that EPD almost didn'toccur in aqueous solution system. However, because HA granules take position charges inabsolute alcohol, a homogeneous EPD be carried out on the cathode titanium alloy slice, but taking negative charge in absolute alcohol the BG granules not be deposited on the cathode. A guided HA crystallizing, 100～300nm, on surface of the BG granules be realized by metathetical reaction, which cover BG granules with HA microcrystals and make the covered BG granules taking position charges in absolute alcohol, sequentially realize the EPCD of the BG and HA granules on the cathode, so it is feasible to make a titanium alloy/BG/HA bioactive graded coating by making use of EPCD technology. The corrosion experiment of rich boron bioglass coating and plasma spray coating showed that split phase, rich boron and rich silicon phase, occurred during its preparation. In basic medium the corrosion behavior of 〓 BG coating showed uniformity corrosion, the corrosion mostly occurred at rich boron phase area, therefore batch formula design of BGshould avoid the occurring of split phase. The corrosion appearance of plasma spray coatingappeared a non-uniform corrosion, mostly occurred at the edge of the laminated HA moltendrops, and emerged an accelerated corrosion tendency, which will easyly lead to corrosioncrackles extending to the interface and the happening of osmotic interfacial corrosion, thatmay be one of the major reasons leading to the coating cracking-off in the later period. Thetesting results of thermal expansion coefficient of 〓 and 〓BG showed the thermalexpansion coefficient of 〓 BG matched with that of titanium alloy better, and 〓 BG couldsinter with titanium alloy into densification enamel layer at low temperature (720℃).

将Ti6Al4V合金在1000℃下进行真空热处理会降低其力学性能，且合金内的V元素会向表面富集，因此，钛合金真空热处理和表面涂层的烧结温度不能过高，即应低于其相转变点；通过对生物活性梯度涂层的组成和结构的设计，分析和计算了梯度涂层内的应力大小和分布，结果表明：对于本研究，当成分分布系数n=1.5时，可以获得较合理的涂层力学性能，即在沉积开始时，采用富含BG颗粒的悬浮液，以便在钛合金侧获得同底层BG有良好过渡的富BG涂层；梯度涂层界面和表面的应力大小、性质由材料组成本身的性质决定，改变成分分布系数，只能改变涂层内应力变化的趋势；涂层的厚薄不影响涂层内的应力分布规律，但涂层越薄，涂层内的应力变化越快，但这并不意味着涂层越厚越好，因为涂层越厚，涂层允许的变形越小，对于应用于弯曲受力部位的涂层而言，涂层应薄一点为好(50μm)；而对于仅纯受剪切应力的部位，如牙根种植体，涂层可适当加厚(80～100μm)；通过对HA和BG颗粒在水溶液体系和非水溶液体系中的带电特性和电泳沉积的研究发现，它们在水溶液体系中很难发生电沉积；在无水乙醇溶液中，HA颗粒带正电，可在阴极钛合金片上发生均匀的电泳沉积，而BG颗粒则带负电荷；利用复分解反应法，可以制得100～300nm的HA，通过诱导HA在BG颗粒表面结晶，可对BG颗粒进行表面包覆，获得了被HA包覆的BG颗粒，改变了BG颗粒表面的带电特性，使BG和HA颗粒在无水乙醇中均带上正电荷，从而实现了HA和BG颗粒在阴极上的共沉积。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失