过氧

Carboxylic acid was peroxidized in organic solvents catalyzed by lipase and glycidol was synthesized from allyl alcohol catalyzed by acid peroxide.

利用脂肪酶在有机介质中催化制备过氧酸，丙烯醇在过氧酸的作用下发生环氧化反应生成环氧丙醇。

Several transient compounds were synthesized by the homo- and heterogeneous reactions of reactive halogen compounds, In-situ ultraviolet photoelectron spectroscopy and photoionization mass spectroscopy as well as theoretical calculations were used to study their molecular structures, stability and molecular orbital properties, their electronic structures and geometric structures were obtained for the first time; Simultaneously, the electronic structure and thermal dissociation of acetyl peroxynitrate and trifluoroacetyl peroxynitrate which have great importance in the atmospheric chemistry were studied; The substituent effects of series of halopyridines and halothiophenes were studied by the ultraviolet photoelectron spectroscopy method for the first time. The atmospheric chemical reaction between peroxyacetyl radicals with IO radicals as well as the dissociation of the most stable isomer of CH3COIO3 were calculated by density functional theory, it was found that the CH3COOIO2 isomer may be act as a new reservoir of inorganic iodine in the stratosphere.

通过活性卤素的系列均相与非均相化学反应合成了几种瞬态物种，采用原位紫外光电子能谱和光电离质谱结合量子化学理论计算对化合物的分子结构、稳定性以及分子轨道特性进行了研究，首次获得了这些物种的电子结构和几何结构的信息；同时研究了大气中有重要作用的乙酰过氧硝酸酯和三氟乙酰过氧硝酸酯的电子结构性质及热解过程；采用紫外光电子能谱手段首次研究了系列卤代吡啶和噻吩的取代基效应；通过量子化学理论计算研究了乙酰基过氧自由基与IO自由基的大气化学反应及其最稳定异构体CH3COOIO2的解离，发现该物种可能是无机碘化合物在平流层中的储库物种。

To prevent epidemical disease prevalence caused by microorganisms in indoor air, a study was carried out to investigate the effect of ventilation, peracetic acid and ozonization on microorganisms reduction in the indoor air within a campus. The experimental results indicated that ventilation was an effective measure in reducing indoor air microorganisms with economy and simple operation.

为了防止室内空气微生物导致的传染病发生，对某校园室内的空气进行通风、过氧乙酸和臭氧灭菌降低微生物的实验研究结果表明，通风可以有效地降低室内微生物的浓度，是最为经济和易行的措施；过氧乙酸灭菌效果好，持续时间较长，可在不易实施通风情况下采用过氧乙酸灭菌；臭氧具有迅速杀菌的效果，使用时要与人保持一定距离，最好超出 1m。

NMR and ESI-MS techniques were used to study the interactions between diperoxovanadates and small organic molecules such as pyridine, imidazole, arginine, picoline ester, and picoline amide. Spectroscopic methods were established to explore this type of interactions.

在合成数种双过氧钒化合物的基础上，利用多种NMR技术结合ESI-MS等谱学方法系统研究了双过氧钒化合物和咪唑、吡啶、取代吡啶、精氨酸、皮考啉酯以及皮考啉酰胺等有机配体的相互作用，建立了一套适合研究过氧钒化合物与有机小分子相互作用的谱学方法。

Analysis based on the experimental results demonstrated the plausible reaction mechanism is that vit C first converts Cu(superscript 2+) to its reduced state and vit C becomes vit C radical itself, thereby stimulating the formation of peroxyl and alkoxyl radicals, and bimolecular reaction of peroxyl radicals results in (superscript 1)O2 production in the systems studied.

根据实验观察的结果，分析了这一体系中(上标 1)O2形成的可能途迳，认为首先是维生素C将Cu(上标 2+)转变为还原态，而自身失去一个电子转变为维生素C自由基，从而刺激了过氧自由基和烷氧自由基的形成，过氧自由基的双分子反应很可能就是体系内(上标 1)O2产生的反应机制。

Then peracetic acid was employed as oxidant to prepare POSS-epoxide and the epoxy value can be controlled by reaction temperature.

而后，又以过氧乙酸为氧化剂，制备了带有环氧基团的多面体低聚硅倍半氧烷分子，并可通过反应温度控制其环氧值。

The properties, production methods and developing prospects of sodium percarbonate were described in this paper,and the situation of making and developing standards of sodium percarbonate for industrial and food use were also put forward.

综述了过氧碳酸钠的性质、生产方法与发展前景以及工业过氧碳酸钠和食品添加剂过氧碳酸钠标准的制修订情况。

Four main parts were included in this dissertation:(1) Precise measurement of Gvalues of hydrogen peroxide in the reactions of flavonoids with superoxide anion andα-hydroxy ethyl peroxyl radicals;(2) Kinetic studies of the reactions of typicalflavonoids with α-hydroxy ethyl peroxyl radicals;(3) HPLC-MS analysis of theproducts after γ-irradiating rutin ethanol solution saturated with air, a reactionmechanism was proposed;(4) Preliminary investigation on the reaction between rutinand peroxynitrite.

本论文的内容主要包括四部分：(1)黄酮类化合物在与超氧阴离子自由基以及α-羟乙基过氧自由基反应的过程中生成的过氧化氢G值的准确测定；(2)几种典型的黄酮类化合物与α-羟乙基过氧自由基的反应动力学研究：(3)空气饱和芦丁乙醇溶液经γ-辐照后产物的HPLC-MS分析及反应机理推测；(4)对芦丁与过氧亚硝酸盐的反应做了初步的探索。

Active hydrogen atom and oxygen ion form Hydroperoxy radicals which surround the positively charged biological contaminants, and then react with three hydrogen elements of its protein structure, destroying and detoxicating the biological contaminants nature.

活性氢和氧离子(O2-)形成的氢过氧自由基，会包围着带正电荷的生物污染物，每一枚黏附在污染物表层的氢过氧自由基，会与其蛋白质结构中三个氢元素产生反应，完全破坏其结构，变成无毒状态。

A common initiator used to start chain growth polymerisation. It undergoes a decomposition reaction at the peroxide bond.

过氧化二苯甲酰：用于引发链增长聚合的常用过氧类引发剂，引发时过氧键断裂分解。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。