轭

The chiralMn complexes, especially Jacobsenscatalyst, display high enantioselectivity for asymmetric epoxidation of conjugated cis-di-, tri-and some tetrasubstituted prochiral alkenes in the NaClO biphasic system, but the epoxidationreaction generally requires a long reaction time even in the presence of an axial ligand.

在NaClO两相体系中，手性Mn配合物，尤其是Jacobsen催化剂，对共轭顺式二取代、三取代和部分四取代烯烃的不对称环氧化具有高的对映选择性，然而即使存在轴向配体，环氧化反应也通常需要长的反应时间。

The chiralMn complexes, especially Jacobsen\'scatalyst, display high enantioselectivity for asymmetric epoxidation of conjugated cis-di-, tri-and some tetrasubstituted prochiral alkenes in the NaClO biphasic system, but the epoxidationreaction generally requires a long reaction time even in the presence of an axial ligand.

在NaClO两相体系中，手性Mn配合物，尤其是Jacobsen催化剂，对共轭顺式二取代、三取代和部分四取代烯烃的不对称环氧化具有高的对映选择性，然而即使存在轴向配体，环氧化反应也通常需要长的反应时间。

The conclusion was drawn that the tetrazine ring and amino group in the DAAT structure were in a plane and were able to build a conjugated π-bond, the calculated fre-quency and intensity were consistent with the experimental values in IR spectra, all thermal energy, thermal capacity and entropy would increase with the increase of temperature.

结果表明： DAAT分子结构中偶氮基两侧的四嗪环和氨基基本在同一个平面上，形成一个大的共轭π键；红外谱计算频率和强度与实验结果整体吻合较好；热能、热容和熵均随温度的升高而增大。

Influence of properties of substituents on different reaction steps of various tetrazole derivatives has been approached as well.

研究了取代基性质对不同异构体和不同热解步骤的影响，发现四唑衍生物与相应的叠氮化合物之间存在平衡，吸电子取代基有利于平衡向生成叠氮化合物方向移动，取代基通过场效应和共轭效应影响5-取代-1H四唑的开环反应。

The shape and size of the cluster can be adjusted.πconjugate aryl alkynyl thio ethers containing thiomethyl in the end are important compounds. We can use such compounds to get some functional molecules that have good assemblied effect, especially in controlling the shape and the size of the cluster.

设计并合成一些形态多样的π共轭系多-SCH_3功能基的芳炔硫醚类分子对获得一些具有良好组装效果，尤其是能够控制团簇形态或控制团簇尺度有用的功能分子有着重要的理论和实际意义。

The results indicate that the PPV oligomer with biphenyl bridge is a cross form between two chains and tortuose derivative in the same chain. It reduces molecular symmetry and weakens %π-π% stacking effect among conjugated molecules in solid. This is perhaps the important factor that light-emitting diodes can increase fluorescence quantum efficiency.

结果表明，联苯桥联后的PPV齐聚物在结构上形成了链间交叉链内扭曲的构象，这种交叉扭曲的构象降低了分子的对称性，减弱了共轭分子在固体中的π-π堆积作用，这可能是减少荧光猝灭效应，提高固体发光器件效率的重要原因。

Two analogues of Trichosanthes trypsin inhibitor I with the Cys14- Cys26 or Cys8- Cys20 disulfide bonds replaced by Tys or Phe and two negative control analogues substitution serine for cysteine at 14 and 26 or 8 and 20 positions were synthesized, respectively. The C14F-C26Y mutant had 1/140 inhibitory activity of native Trichosanthes trypsin inhibitor I to trypsin.

第二章是对天花粉胰蛋白酶抑制剂的两对二硫键的作用进行了研究，二硫键在蛋白质的折叠和功能中有重要的作用，芳香族氨基酸的芳环之间形成π-π共轭能否部分补偿二硫键的作用？

This study is design and preparation of active peptide analogues of mung bean trypsin inhibitor Lys fragment, Trichosanthes trypsin inhibitor I, carcinoembryonic antigen peptide and aspartame using solid and liquid phase peptide synthesis methods.

本论文研究活性多肽类似物的设计、制备和功能，分为四个部分，采用多肽固相和液相合成的方法，分别合成了活性多肽绿豆胰蛋白酶抑制剂 Lys片段长链16肽、天花粉胰蛋白酶抑制剂、癌胚抗原肽、甜味肽等一系列类似物，并测定了这些类似物的生物活性，有以下新的研究结果：1、furin酶抑制剂的设计、制备和功能；2、芳香氨基酸芳环之间的π-π共轭能部分补偿二硫键的作用；3、癌胚抗原肽Gly4被L-Pro替代可增加与HLA-A2分子的结合；4、肽键对甜味肽保持甜味是必须的。

The structural and electronic analysis indicates that the GeCNN (5) possesses a conjugate triply bonded structure |Ge≡C—N≡N|.

几何和电子结构分析表明， GeCNN (5)具有共轭三键结构： Ge≡C—N≡N：。

Valves should never be operated with unlubricated stem threads or yoke sleeves.

阀杆螺纹或轭架套筒没有润滑的阀门绝对不应该操作。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

If you have any questions, you can contact me anytime.

如果有任何问题，你可以随时联系我。