轭

It bas been discovered that the carboxylic ester rare earth salt is superior to the organotin in antidehydrochlorination, and inferior to the organotin in antioxidation through following the tracks of carboxide group and conjugated double bond with the help of infrared spectroscopy and ultraviolet-visible spectroscopy.

借助于红外光谱和紫外／可见光谱，通过跟踪光老化过程中羰基基团和共轭双键的变化，发现羧酸酯稀土的抗脱HCl能力优于有机锡，但抗氧化能力不如有机锡。

Applying the conjugate gradient method, an iterative algorithm is presented to solve the constrained matrix equation AXB+CXD=F over centrosymmetric matrix X and its optimal approximation.

应用共轭梯度思想，给出了求解约束矩阵方程AXB+CXD=F的中心对称解及其最佳逼近的迭代算法。

New flexible ligand derived from this achiral biphenylbackbone was applied in Cu-catalyzed enantioselective 1,4-conjugate additionsof Et_2Zn to chalcone.

进一步衍生得到的非手性联苯型P，N 配体，在Cu催化Et_2Zn对查耳酮的1，4-共轭加成反应中也进行了考察。

In the Cu-catalyzed enantioselective 1,4-conjugate addition of diethylzinc to acyclic enones, the reaction conditions, such as the amount of diethylzinc, solvents, temperature and the reaction time, were investigated in detail with 9a as the standard ligand and chalcone as the typical substrate.

考察了Et_2Zn量、溶剂、反应温度和反应时间等因素对反应的影响，得到了配体与Cu的摩尔比为2.5、1.5倍Et_2Zn用量、甲苯为反应溶剂、-20℃下反应6小时为不对称催化1，4-共轭加成的优化反应条件。

When heated , PVC may lose hydrogen chloride and form a chromophoric conjugated polyene structure.

当受热时，PVC可能失去氯化氢并形成一种有色的共轭聚烯结构。

Generally, its difficult to determin VPA in serum with HPLC because VPA lacks nitrogen and a ring moiety and therefore has no chromophoric characteristics.

丙戊酸缺乏氮和共轭环，因此紫外吸收弱，一般HPLC法难以实现。

The molecule has a typical D-π-A structure with terminal units of electron donor and accepter groups. The triphenylamine group, as the electron donor, is connected to the oxadiazole group which is the electron accepter through the cinnamene group.

该分子具有典型的D-π-A型推拉电子结构，三苯胺基团作为给电子基通过苯乙烯共轭链桥接到吸电子基1，3，4-恶二唑基团。

The secondary amine conjugated to 1,8-naphthalimide could be deprotonated by Zn2+, and as a result, large red shifts in both absorption and fluorescence spectra were obtained, from which one could sense Zn2+ colorimetrically and ratiometrically.

锌离子与 ZnRF1-2的作用能够脱去共轭氮原子上的氢，从而使得荧光光谱和吸收光谱发生红移。

Computer-simulated results show that the introduction of acetylene bridge,which electron cloud is columned,reduced the space block between molecular functional groups.In the acetylene-bridged system,the functional groups can keep relatively free rotation,which resulted in that the conjugated electronic cloud are influenced,and then influenced on the properties of the compounds.

计算模拟结果证明，炔桥的引入降低了星状分子的核单元官能团和臂单元官能团之间的空间位阻，使得官能团可以比较自由的旋转，从而对核-臂之间的电子云共轭产生影响，继而影响到该系列化合物体系的各种性能。

The security of a braid public key cryptosystem can't depend only on the hardness of conjugacy problems.

辫子群上公钥密码系统的安全性不能仅仅依靠共轭问题的难解性。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！