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It is in favor of high oleic acid content in the production of biodiesel,thus erucic acid have adverse effects.

该体系也可催化含水原料生物柴油,在反应体系中水含量达25%时,仍可获得61.97%的转化率

At the same time,we found that the conversion rate decrease with the water content increase,lower conversion rate;it is in favor of high oleic acid content in the production of biodiesel, thus erucic acid have adverse effects.

同时还发现,水对该反应有抑制作用,随着其含量增加,转化率降低;油酸对该反应有促进作用,而芥酸有不利影响。

The absorbency changes of both thiol and vinyl functional group were monitored independently by FTIR spectrometer during vinyl silazane photopolymerizing with ethanedithiol, Based on the results,the kenitics of reaction was studied and the convertion of both thiol and vinyl functional groups were investigated.

采用傅立叶变换红外光谱法跟踪巯基和乙烯基吸光度的变化,跟踪测定了光聚合反应过程中巯基和乙烯基的转化率,研究了乙二硫醇/乙烯基硅氮烷体系的光聚合反应动力学。

The synthesis of sucrose ester containing ethanoyl and oleoyl was performed by transesterification between sucrose octaacetate and ethyi oleate in organic solvents, using lipases Novo435 as the catalyst.

在有机溶剂中,以脂肪酶Novo435为催化剂,蔗糖八乙酸酯与油酸乙酯通过转酯化反应合成了同时含有油酸酰基和乙酸酰基的混合型蔗糖酯,当蔗糖八乙酸酯与油酸乙酯的物质的量之比为1:1时,油酸乙酯的转化率达95%。

Activity-stability experiment for the liquid phase alkylation of benzene with ethylene was proceeded for 2000hrs, the average values of ethylene conversion, ethyl-benzene selectivity and ethylation selectivity were 100%, 94.5% and 99.0% respectively.

进行了苯和乙烯液相烷基化的2 000 h 活性稳定性试验,乙烯转化率、乙苯选择性、乙基化选择性分别平均为100%、94.5%和99.0%。

Moreover, how to improve hydrogen production rate and substrate conversion efficiency is also important in the research of fermentative hydrogen production, which is also the key factor to realize industrialization.

产氢的稳定性和持久性是发酵产氢中一直存在的问题,如何在稳定持续产氢的基础上提高产氢的速率和转化率是发酵产氢研究中的重要内容,也是能否实现产业化应用的关键性因素。

Under the optimal reaction conditions of 0.5MPa pressure, at 150℃, H2 gas flow rate of 5000 mLh^(-1) and liquid flow rate of 5.0mLh^(-1), the conversion of furoic acid, selectivity to methyl tetra-hydro-furan formiate and yield of methyl tetra-hydro-furan formiate can reach 99.0%, 98.2% and 97.2%, respectively.

结果表明:在0.5MPa,150℃,氢气流速5000mLh^(-1),液体流速5.0mLh^(-1)(氢油比为50)时,呋喃甲酸转化率为99.0%,四氢糠酸甲酯的选择性98.2%,产率97.2%。

It is found that conversion of furfuryl alcohol was higher than 99%,and THFA yield and selectivity achieved or were close to 97%by using catalyst Ⅱ with a small quantity of promoters.

对于含少量助剂的镍催化剂Ⅱ,在393 K、4.0 MPa和空速0.25 h\+\{-1\}时,糠醇转化率可达99%以上,四氢糠醇收率和选择性都达到或接近97%。

The THFA yield and selectivity were 2.0%higher than those by using catalyst Ⅰ without promoter,3.0%higher than those by using Raney nickel catalyst under the same reaction conditions and furfuryl alcohol conversion.

在相同反应条件和糠醇转化率条件下,四氢糠醇收率和选择性均比没有助剂的镍催化剂Ⅰ高2.0%,比骨架镍催化剂高3.0%。

The hydrogenation and methyl esterification of furoic acid over Pd-Ni/γ-Al2O3 catalysts was investigated in fixed bed micro-reactor under different conditions such as reaction temperature,pressure,H2 space velocity,space velocity of furoic acid and methol,ratio of H2 and furoic acid and so on.

以糠酸、甲醇、氢气为原料,采用连续流动固定床微反应器,Pd-Ni/γ-Al2O3为催化剂,使糠酸一步加氢甲酯化生成α-四氢糠酸甲酯。研究了反应的温度,压力,气、液体流速,进料流量等因素对催化反应的影响。结果表明:在1.5MPa,250℃,氢气空速3300 h-1,液体空速3.0 h-1(氢油比为50)时,糠酸转化率为96.6%,四氢糠酸甲酯的选择性97.2.0%,产率94.0%。催化剂稳定性较好,连续运转280小时后未见活性下降。该反应体系活性高,选择性好,反应压力低,催化剂性能稳定,操作简单,产物易分离

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