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The condensation reaction,in which the yield of intermediate product after refining process was more than 90%,used iso-butylaldehyde and formaldehyde as materials,Et 3N as catalyst.The hydrogenation,in which the conversion of hydroxypivaldehyde and selectivity of NPG were respectively 99% and 95%,used Cu-ZnO as catalyst,and ethanol as solute,meanwhile in the hydrogenation,the impurity in material could also ...

缩合反应采用异丁醛和甲醛为原料,三乙胺为催化剂,在 60℃左右反应,缩合产物经减压蒸馏和结晶、干燥,得到收率为 90 %以上的中间体羟基戊醛;加氢反应采用自制的Cu -ZnO催化剂,乙醇为溶剂,在 15 0℃将HPA加氢生成新戊二醇,HPA转化率为 99%,新戊二醇收率在 95 %以上,而且HPA缩合反应的副产物在加氢反应中也转化为新戊二醇。

Culture tender leaves in culture medium of MS+2,4-D1.5mg/L+30g/L suger+0.7% agar pH5.8 for 20 days in darkness at 25℃, and then subculture to induced Ⅱ-type calli. Use forceps cutting the tissue to nubble with 2mm2, and put the tissue into Agrodacterium tumefaciens LBA4404 liquid supplemented with AS 100mg/L,then, co-culture 3 days, resume 7 days in MS+2,4-D1.5mg/L+30g/L suger+500mg/L cef, take to MS+2,4-D1.5mg/L+30g/L suger+100mg/L cef+10.0mg/L kanamycin culture 20 days in darkness. After that to make it polarize in MS+30g/L suger+100mg/L cef+10.0mg/L km. The percentage of km resistant callus was reached max after infection for 45 min, the average is 29.66%. Simultaneity, tender leave callus are infected 5 min by A. tumefaciens liquid in different negative pressure, and kept on 15 min in Agrodacterium tumefaciens liquid without negative pressure. Then screen out resistant callus and obtain transgenic plants. When the negative pressure is -0.05MP the percentage of km resistant callus was reached max, the average rate is 37.5%.

将心叶接种于MS+2.4-D1.5mg/L+30g/L 蔗糖,琼脂0.7%,pH5.8 培养基中25℃暗培养20d 后继代一次,诱导产生Ⅱ型胚性愈伤组织,用镊子将其夹碎成2mm2大小的小块,置入添加100mg/L AS 的根癌农杆菌LBA4404 菌液中,侵染时间为45min,共培养3 天后,转入MS+2.4-D1.5mg/L+30g/L 蔗糖+500mg/L Cef 培养基中恢复7天,再转入MS+2.4-D1.5mg/L+30g/L 蔗糖+100mg/L Cef+10.0mg/L Km 中,遮光培养20d后,置入其MS+30g/L 蔗糖+100mg/L Cef+10.0mg/L Km 分化,卡那霉素抗性愈伤组织获得率在侵染45min 时达到最大值平均为29.66%;同时以甘蔗心叶愈伤组织材料,通过循环水式真空泵,产生负压,设定不同的负压值,在农杆菌菌液中感染5min 后,在负压条件下继续侵染15min 后,筛选出抗性愈伤组织并获得转化植株,其中在负压为-0.05 时转化率达到最大值,其卡那霉素抗性愈伤组织获得率平均为37.5%。

While the conversion ofα-octene was 81.7%, and the yield of octane was 43.4% by single metal catalyst.

Pd单金属催化剂CTS-ACR16Pd催化的α-辛烯转化率81.7%,正辛烷产率43.4%。

At present, although the iodine as a catalyst, oleum as the solvent liquid phase partial oxidation of methane research is not adequate, but the reaction has higher yield and the conversion rate of the industrialized good prospects to enlarge production.

目前,虽然以碘为催化剂、发烟硫酸为溶剂的甲烷液相部分氧化反应的研究尚不充分,但是该反应具有较高的转化率和收率,工业化放大生产的前景良好。

The conversion rate under the optimum reaction conditions was 96%.

在此最优条件下测得转化率为96%。

When synthetic ammonia, if makes the catalyst with the osmium, may obtain the high conversion rate under not too high temperature.

合成氨时,如果用锇做催化剂,就可以在不太高的温度下获得较高的转化率

When oxygen is used as an oxidant, the conversion of EB is 40.4%, the selectivity is 91% at 400℃.

氧气作为氧化剂,400℃时,当乙苯的转化率为40.4%时,苯乙烯的选择性为91%。

With trimethyl,4-dodecylbenezyl ammonium chloride and 18-crown-6 as pase-transfer catalysts, the azidation of polyepichlorohydrin in poly and H2O were studied. The reaction discipline and mechanism were discussed. The results show that the system with trimethyl, 4-dodecylbenezyl ammonium chloride as phase transfer catalyst and PEG as medium is a safe and effective approach to glycidyl azide polymer preparation, and azidational ratio of PECH can reach 97% above within 15 h.

研究了氯化十二烷基苄基三甲基铵和18-冠-6为相转移催化剂时端羟基聚环氧氯丙烷在聚环氧乙烷和水为介质中的叠氮化反应,探讨了反应规律和反应机理,结果表明:以PECH为介质,十二烷基苄基三甲基氯化铵(TMDA-1)为相转移催化剂的反应体系,可在15h内使PECH叠氮化转化率达到97%以上,无主链断裂等副反应,是一条较为安全快速的制备叠氮粘合剂的方法。

Quaternary ammonium salt was used as catalyst for transporting phenoxide ion between two phases to give benzyl phenyl ether and its derivatives in multiphase system.

在多相体系中,以铵盐为催化剂合成苄苯醚及其衍生物,产率高达91%,转化率达到98 3%。

The conversion rate would decrease with the increasing concentration of phytosterol, but the total output would increase remarkably.

AD的转化率随着甾醇添加量的提高而有所降低,但总产量明显提高。

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