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Was obtained in Trial 8 where the total cyclohexane conversion was 78% with 74% of the starting cyclohexane converted to oxygenate.

获得了审判8的总环己烷转化率78 %与74 %的转换开始环己烷氧化。

In the condition of 1 MPa O_2 and 413 K for 4 h, the conversion of cyclohexane is 16.9%, and the total selectivity of cyclohexanol and cyclohexanone is 93%.

在该反应条件下,环己烷的转化率为16.9%,环己酮和环己醇的总选择性为93%。

Also we observed in this study there is a direct proportional relationship between the cyclohexane conversion and the amount of catalyst initiator "NHPI".

此外,我们在本研究中观察到有直接的比例关系,环己烷转化率和催化剂用量引发" NHPI "。

The results indicated that higher phenol conversion and cyclohexanol selectivity could be obtained under the condition of higher temperature and pressure, and lower space velocity and methanol content, while phenol concentration had almost no effect on the reaction performance.

结果表明,较高的反应温度和压力以及较低的液体空速和甲醇含量有利于提高苯酚的转化率和环己醇的选择性,但是苯酚的浓度对反应性能的影响不大。

Under the suitable conditions of reaction temperature 170℃, 1.5 MPa air and reaction time 6 h, the conversion of cyclohexane and the total selectivity of cyclohexanone and cyclohexanol were 5.39% and 88.7% respectively.

在反应温度170℃,空气压力1.5 MPa,反应时间6 h的优化条件下,环己烷转化率与酮醇总选择性分别为5.39%和88.7%。

The commercial process of cyclohexane oxidation to cyclohexanone and cyclohexanol shows low conversion, poor selectivity, high-energy consumption and environmental pollution. It is of great academic and practical importance to study and develop highly efficient and environmentally friendly catalytic cyclohexane oxidation processes.

现有的环己烷氧化制环己酮生产工艺,存在转化率低、选择性差、能耗高以及污染环境的缺点,研究和开发高效、环境友好的环己烷催化氧化工艺具有重要的理论意义和实用价值。

Cyclohexane conversion of 33.7%,selectivity to cyclohexanone and cyclohexanol of 97.2%,cyclohexan...

在70℃和n(C6H12)∶n(H2O2)=1∶2条件下,采用两次加入过氧化氢的方式,环己烷转化率为33.7%,酮醇总选择性97.2%,n∶n=1.99,过氧化氢利用率37.1%。

It was found that manganese porphyrin had the highest activity, and a maximum 15.4% of cyclohexane conversion and 93.9% selectivity of cyclohexanone and cyclohexanol could be obtained under the suitable conditions.

结果发现,锰卟啉催化活性最好,在适宜反应条件下,环己烷转化率高达15.4%,环己酮和环己醇的总选择性约为93.9%。

The commercial processes of cyclohexane oxidation to cyclohexanone and cyclohexanol generally show many problems, such as low conversion, poor selectivity, complicated technology, high-energy consumption and environmental pollution. So it seems to be of great academic and practical interesting to study and develop highly efficient and environmentally friendly catalytic cyclohexane oxidation processes.

现有的环己烷氧化制环己酮和环己醇生产工艺普遍存在转化率低、选择性差、工艺复杂、耗能大和对环境污染严重等问题,这就使得研究和开发高效、环境友好的环己烷催化氧化工艺具有重要的理论意义和实用价值。

Under the conditions of n∶n = 1∶100,95 ℃ and 6 h,the conversion of nitrocyclohexane reached to 100% and the selectivity for cyclohexanone oxime was 84.2%.

在催化剂与硝基环己烷摩尔比为1∶100、反应温度95 ℃的条件下,反应6 h后的硝基环己烷转化率可达100%,环己酮肟选择性可达84.2%。

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