转化率

And among substrates including 2'-chloroacetophenone, 3'-chloroacetophenone, 4'-chloroacetophenone and 3-chloropropiophenone, the highest productivity of the reduced product with S. cerevisiae B5 was observed for 2'-chloroacetophenone.

许多研究者都在致力于研究和开发产物转化率高、手性选择性好的手性化合物合成路线，其中生物转化法由于其温和的反应条件及高度的手性选择性而受到人们的青睐。

Catalytic activities of phosphotungstic acid for liquid-phase nitrations of benzene,toluene and chlorobenzene were studied.

研究了磷钨酸对苯、甲苯和氯苯液相硝化反应的催化活性，考察了反应温度、反应时间、硝酸与芳烃摩尔比对芳烃转化率和产物选择性的影响。

It is demonstrated that the chiral quaternary ammonium salts catalysts exhibit promising catalytic properties for the substrate. Part III: The synthesis and the characterizing of the macroporous aminomethyl resin-supported cinchona alkaloid complexes and the study on its catalytic properties The part consists of two subsections. the macroporous aminomethyl resin -supported cinchona alkaloid complexes were synthesized by the stuff (cinchonine, quinine and macroporous aminomethyl resin). Their structures were characterized by means of elemental analysis, XPS, TG/DTA; the chiral polymer-supported complexes were first used as catalysts for the reduction of ketones. Their catalytic properties for the reduction processes were investigated. The comparison of the products e.e., the conversion of the substrate among different reduction processes was employed with determined by HPLC. The effects of the time, the temperature, the ratio of catalyst to substrate, reaction solvent as well as the recycle times were also discussed.

第三章聚-4-氨甲基苯乙烯负载金鸡纳碱金属络合物的合成与表征及其不对称催化性能研究本章分为两节，以辛可宁和奎宁及聚-4-氨甲基苯乙烯为原料，合成了4种聚-4-氨甲基苯乙烯负载金鸡纳碱络合物催化剂，并对它们的结构用元素分析、X-射线光电子能谱、TG/DTA等几种测试手段进行了表征；首次将所合成的手性高分子负载的金属络合物用于催化芳香酮不对称还原反应，详细研究了所得的手性高分子负载的金属络合物对不同底物的催化性能，用HPLC等分析手段定量检测了还原过程的底物转化率及其产物对映异构体选择性，并考察了反应时间、反应温度、催化剂和底物投料比、反应溶剂和循环次数对催化性能的影响。

The addition of citric acid also could increase the conversion.

在反应体系中加入柠檬酸可以提高反应的转化率。

A modified Raney Ni catalyst is developed to make citronellol from citronellal by hydrogenation in a lower pressure.

研制了适用于香茅醛在较低压力下选择加氢制备香茅醇的改性骨架镍催化剂，香茅醛的转化率达99。

Reductive conversion of geraniol to citronellol is adopted as a model reaction, and several factors in the reaction are discussed using gas chromatography method. The influence of n-hexane and butyl acetate, as organic solvents, on biocompatibility was studied; the influence of methanol, ethanol, glycol, n-butanol and 1-hexanol, as energy substance, on the transformation efficiency was compared, respectively; the catalysis capabilities of Baker's yeast, XST-KO yeast, LP yeast, alcohol yeast, dry yeast, Saccharomyces cerevisiae, Angel yeast and Meishan yeast were discussed. It has been proved that biocompatibility of n-hexane are much better than that of butyl acetate, and the hexane has been demonstrated the most effective in terms of the influence on biotransformation, Baker's yeast has shown the highest tranformation efficiency among the eight yeast strains.

以香叶醇转化为香茅醇作为模型反应，通过气相色谱法进行定性和定量分析研究了影响该有机相生物转化反应的几个基本因素，考察了两种有机溶剂正己烷和乙酸丁酯对生物相容性的影响，选用甲醇、乙醇、乙二醇、正丁醇和l-己醇分别作为能量物质进行实验，比较其对转化的影响并探讨了Baker's酵母、XST-KO酵母、LP酵母、酒精酵母、假丝酵母、干酵母、安琪酵母和梅山酵母八种不同酵母作为生物催化剂对模型反应的催化能力，结果表明，正己烷作为有机溶剂，其生物相容性明显好于乙酸丁酯，更加有利于该生物转化反应进行；乙二醇作为能量物质，该模型反应转化率最高；而 Baker's酵母作为生物催化剂，对该模型反应的催化能力最强，最适合作为该模型反应的催化剂。

Under this condition, the percent of the BaO in the clinker aggregate is up to 54%, which is above 70% according to the rate of conversion.

在这种条件下，毒重石焙烧后的熟料中BaO的含量可达54%，换算成转化率即为70%以上。

In this paper, three kinds of hydroxyl component are prepared for two-component waterborne polyurethane paint, that is, acrylic dispersion, acrylic emulsion and silicone-modified acrylic emulsion. The influence of the composites of these dispersion and emulsions on polymerization process, viscosity, particle size and coagulum are investigated, infrared spectroscopy , inductance coupling plasma , transmission electron microscopy and thermogravimetric analysis are used to characterized their structure, composite, morphology and thermal stability, respectively.

本论文制备了三种用于水性双组分聚氨酯涂料的含羟基组分，即丙烯酸分散体、丙烯酸乳液和有机硅改性丙烯酸乳液，研究了这些分散体和乳液在制备过程中聚合物的羟值、酸值、玻璃化温度、乳化剂、反应温度等对聚合转化率、凝聚物含量、聚合物粘度和粒径的影响，用红外光谱、热重分析、透射电镜和感应偶合等离子技术表征了其结构、组成、形态和热稳定性。

Transmission Electron Microscope and other properties testing results show that the complex emulsifier system is the crucial influence factor of the polymerization process and the properties of products. It may influence the coagulum content and reaction rate of the polymerization process, the performance, particle diameter,viscosity, electrolyte stability and storage stability of the emulsion products and the contact angle of the film.The initiator mainly influences the coagulum content and reaction rate.The acrylic monomers mainly influence the solid content, Minimum Film Formation Temperature of the emulsion and the Glass Transition Temperature of the film.The organic silicone monomer mainly influences the water absorption of the film.The reaction temperature mainly influences the reaction rate and conversion.The stirring intensity mainly influences the coagulum content of the polymerization process.

透射电镜等性能测试结果显示：复合乳化剂体系是硅丙共聚乳液的聚合过程及产品性能的主要影响因素，它可以对聚合过程的凝胶率、反应速率以及乳液的外观、粒径、粘度、耐电解质稳定性及贮存稳定性，还有乳液涂膜的接触角等造成不同程度的影响；引发剂主要影响反应速率和凝胶率；丙烯酸酯单体主要影响到乳液的固含量、最低成膜温度以及涂膜的玻璃化转变温度，有机硅单体主要影响涂膜的吸水率等；聚合反应温度主要影响乳液的反应速率和转化率等；搅拌强度主要是影响到聚合过程的凝胶率。

Secondly,the Popescu method was adopted to do further screening by virtue of linear correlation coefficient of regression calculation.

首先分析反应发生的过程，对机理函数作初步筛选；然后采用Popescu法通过函数拟合的线性相关度对机理函数作进一步的推断；最后采用单个扫描速率的微分法与等转化率法相结合的方法，以活化能为判据确定最概然机理函数。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

If you have any questions, you can contact me anytime.

如果有任何问题，你可以随时联系我。