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A novel carbonyl transposition led by anilines'nucleophilic addition to methyl 2-keto α-D-glucopyranoside was discovered. And the mechanism of the reaction concerned to an enol rearrangment was provided through tracing the change of 〓H-NMR and 〓C-NMR of a hemiacetal intermediate which was obtained in the reaction of o-phenylene diamine with 2-keto glycoside. Both the intermediate and the converting product were identified by 〓H-NMR,〓C-NMR,〓H-〓H COSY and HMQC.

一、发现了2-位氧化α-甲基D-葡萄糖苷的芳胺亲核加成引起羰基转位的新方法,利用核磁共振氢谱及碳谱对邻苯二胺与2-位氧化α-甲基D-葡萄糖苷加成生成的稳定中间体半缩酮化合物在氘代丙酮中的变化进行跟踪,结合对转化产物的氢氢相关谱和HMQC结构确证,提出了该反应中2-位羰基通过烯醇化互变而转至3-位的机理并得到了验证。

METHODS:After the treatment of TRAIL or LPS at different doses,we tested the nuclear translocation of NF-κB by cell immunohistochemical staining and electrophoretic mobility shift assay,and evaluated the level of IκB by RT-PCR under pyrrolidine dithiocarbamatetreatment.

当不同浓度的TRAIL和LPS作用于细胞后,我们通过细胞免疫组化染色和凝胶电泳迁移试验来检测NF-κB核转位的情况。并通过RT-PCR的方法粗略评定二硫代氨基甲酸吡咯烷对抑制蛋白IκB的影响。

Within the first 1 to 2 weeks of age, transposition of the great arteries is surgically repaired.

在生后第1至2周,要进行大动脉转位的外科矫治,这种手术称为"转换术",概略的说明了手术的做法。

The obvious indication of TGA is a newborn who becomes cyanotic in the transitional first day of life when the maternal source of oxygen is removed.

大动脉转位的明显的迹象是新生儿在其娩出后第一天里当来自胎盘的母体的氧断开后就出现紫绀。

Objective\ To study the anatomy of reversed femoral osteoperiosteal flap.

目的探讨股骨内侧髁骨瓣逆行转位的解剖学基础。

Objective To investigate the effect of ligustrazine on the intracellular translocation of Smad protein in HSC-T6 cell line.

目的 探讨川芎嗪对HSC-T6细胞Smad蛋白细胞内转位的影响。

These papers provide the details of the mechanisms of GTP-dependent elongation and translocation that will be discussed in class.

这些文献提供了课堂上将会讨论的GTP 依赖型延长与转位的详细机转。

The mechanical contraction of circle muscularis strips, the contractile response of dispersed smooth muscle cells, the change of 〓 stimulated by sennoside with different concentration and that stimulated by Ach after incubated with sennoside were evaluated. The translocation of RhoA by sennoside were measured by laser confocal scanting microscopy too.

检测不同浓度的番泻甙对小肠环行肌条和游离环行平滑肌细胞的收缩作用及对〓的影响,然后测定番泻甙对Ach刺激的小肠环行肌条、游离环行平滑肌细胞收缩反应和细胞内〓变化的影响作用,并通过免疫荧光实验检测番泻甙对RhoA的活化和空间转位的影响。

Many researches have proven that extraneous KGF-2 can be translocated into nucleus, but the mechanism and function of this process are still unclear.

此外,KGF-2具有核转位现象,但目前对其核转位的机制和功能还不清楚,也未见研究和报道。

In order to solve the problem, in this dissertation, a new IA technology based on wavelet-filtering and two-position alignment is proposed. The useful signals of sensors are gained by wavelet filtering; the error angles, constant drifts of FOGs and biases of accelerometers are computed through signals at two positions.

对此,本文提出了一种基于小波滤波方法和二位置对准方法相结合的初始对准技术,采用小波滤波方法提取传感器的有用信号,利用两次转位的信号解算初始对准的误差角、陀螺的常值漂移和加速度计的零偏。

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We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。