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路易斯碱

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Another is the Lewis definition (also 1923): An acid is a chemical that can accept an electron pair from a base, which they share to form a covalent bond.

另一种理论是路易斯理论(也是在1923年发表):酸就是能由碱接受一个电子对形成一个共价键的化学物质。

The results showed that MgO has a certain strength of Lewis base, and the adsorption of BATE on MgO is monomolecular chemical adsorption.

结果表明MgO有一定的路易斯碱强度,与硼酸三甲酯之间的吸附是单分子层化学吸附。

We screened a set of Lewis base organocatalysts derived from chiral pipecolinic acid and tert-butanesulfinamide for the reduction of-N-Cbz-1- phenylpropenamine, including newly designed ones and some of those previously developed in our lab. However, only moderate stereoselectivities, albeit high yields were obtained.

在本课题组前期研究的基础上,我们筛选并设计了一系列以手性哌啶酸和叔丁基亚磺酰胺为母体的有机小分子路易斯碱催化剂,它们能催化三氯氢硅对-N-苄氧羰基-1-苯基丙烯胺的不对称还原,获得很高的收率和中等的对映选择性,并且具有很好的底物普适性。

Starting from chiral proline, pipecolinic acid, piperazine-2-carboxylic acid and 1,2-diphenyl amino alcohol, a series of structurally simple and easily prepared amides were developed as highly effective Lewis basic organocatalysts for the asymmetric reduction of imines with trichlorosilane as the reducing agent, which promoted the reduction of N-aryl imines with high yields and excellent enantioselectivities with an unprecedented substrate spectrum.

本文分别由手性脯氨酸、哌啶酸、哌嗪酸以及氨基醇出发,设计和合成了一系列结构新颖、合成简便、性能优良的酰胺类有机小分子路易斯碱催化剂,以廉价的三氯氢硅为氢源,用这些催化剂催化亚胺不对称还原,得到了非常优良的收率、对映选择性和前所未有的底物普适性。

According to molecular orbital theory, the main bonding orbitals of 3d transitionmetal monoxides MO are 9σ, 1δand 4πmolecular orbitals.

过渡金属氧化物与稀有气体原子间除了静电相互作用以外,通常还包含路易斯酸碱相互作用,即稀有气体原子作为路易斯碱可以提供电子给金属氧化物中基于金属中心的空的或部分占据的分子轨道。

Recent progress in the applications of non-enzymatic system about Lewis acid and base tokinetic resolution reactions of racemes is reviewed.

本文讨论了路易斯酸及路易斯碱催化体系在外消旋体动力学拆分反应中应用的最新进展。

Symmetric Lewis base has the following problem in the application that the relatively high content of regulator will reduce the rate of polymerization and impact further polymerization as well as the coupling process after the polymerization.

对称型路易斯碱在应用中存在问题:较高调节剂含量将会降低聚合速率、影响进一步聚合以及聚合以后的偶联过程。

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

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