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4R,5S,6R-5,6-Bis-allyl-6-aldehyde-γ-hexanelactone I-145 was prepared from D-arabinose by six steps. Compound I-145 underwent Mukaiyama-type intramolecular aldolization to produce bicyclooctane I-147 stereospecifically.

我们以D-阿拉伯糖为起始原料,经六步反应,得到(4R,5S,6R)-5, 6-二烯丙氧基-6-醛基-γ-己酸内酯I-145,然后I-145发生分子内的Mukaiyama式aldol缩合反应,完全立体专一性地得到环化中间体I-147。

The pure isomers 3-(1-hydroxyethyl)-8-vinyldeuteroporphyrin Ⅸ and 3-vinyl-8-(1-hydroxyethyl)deuteroporphyrin Ⅸ were obtained from protoporphyrin Ⅸ dimethyl ester.Starting from these two acetylating compounds,eight new porphyrin derivatives were synthesized through an alkyloxy fission reaction.

以原卟啉Ⅸ二甲酯为起始原料,合成并分离得到3-(1-羟乙基)-8-乙烯基次卟啉Ⅸ(Ⅱ1)和3-乙烯基-8-(1-羟乙基)次卟啉Ⅸ(Ⅱ2)二个异构体,两者分别经酰化后与醇进行烷氧裂解反应合成了8个全新的卟啉衍生物。

Jiangsu Anpon Electrical Chemistry Co., Ltd., Huaian 223002, Jiangsu, China Abstract: 2-Amino-4,6-dimethoxy-1,3,5-triazine, an important intermediate for preparing cinosulfuron, was synthesized utilizing 2,4,6-trichloro-1,3,5-triazine as raw material via ammonization, methoxylation. The purity was 96.0% and the average yield was 90.4%.

江苏安邦电化有限公司,江苏淮安 223002 摘要:2-氨基-4,6-二甲氧基-1,3,5-三嗪是合成醚磺隆的重要中间体,以三聚氯氰为起始原料,经氨化、甲氧基化中试反应得到2-氨基-4,6-二甲氧基-1,3,5-三嗪,纯度为96.0%,平均收率90.4%。

Analyses were performed on 428 initially asymptomatic subjects.

对起始无症状的428人进行分析。

The mixed culture system of Staphyloccus auricularis C131,Dabaryomyces hansenii Y163 and Lactobacillus sake L04 was construct for production of Rugao sausage.

以耳式葡萄球菌C131、德巴利汉逊酵母Y163、米酒乳杆菌 L04为受试菌株构建发酵剂混培养技术体系,当L04、C131和Y163的起始菌构成比分别为1:2:1、1:4:1,使用加有0。

Then we took a walk through Warsong Hold, the Horde starting area at Borean Tundra.

再走几步就到了战歌要塞Warsong Hold,这是部落在北风苔原上的起始区域。

The total synthesis of the title compound 10 was accomplished starting from 3,5-dimethoxybenzoic acid (1) and p-hydroxybenzaldehyde (6). In the process, esterification, reduction, bromination and Wittig-Homer reaction were performed.

以3,5-二甲氧基苯甲酸为起始原料,经过甲醇酯化、氢化铝锂还原、四溴化碳溴代和Wittig-Homer反应,高产率的合成了Wittig-Homer试剂(5)。

The target compound 1 was successfully prepared via esterification, reduction, bromization and cyanation processes by using L--malic acid (2), which is an inexpensive and easily available starting material. The overall yield was 56.7%.

以廉价、易得的L--苹果酸为起始原料,经酯化、还原、溴代和氰化四步反应得到目标化合物-4-氰基-3-羟基丁酸乙酯,合成总收率为56.7%。

D-proline was ob tamed from the asymmetric transformafion of L-proline via the formation of-tartaric acid salt by using butanal as catalyst.

以L-脯氨酸为起始原料,S-酒石酸为拆分剂,运用不对称转换的方法合成D-脯氨酸。

Methods:The target compound was synthesized using 4-hydrazino-N-methyl-benzyl-sulphonamide hydrochloride and 4,4-dimethoxy-N,N-dimethyl butylamine as the starting materials,PPA and sodium dihydrogen phosphate instead as catalysts and isopropyl ether and acetone as solvents for recrylstallization,via 4-step reactions:condensation,rearrangement,cyclization and salt formtion.

以4-肼基-N-甲基-苄基磺酰胺盐酸盐与4,4-二甲氧基-N,N-二甲基-丁胺为起始原料,改用多聚磷酸和磷酸二氢钠作为催化剂,后处理采用异丙醚和丙酮作为重结晶溶剂,经缩合、重排、环合、成盐的4步反应合成琥珀酸舒马曲坦。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。