质元素

Dinosaur fossils are buried in argillaceous rocks of the Middle Jurassic Shaximiao Formation.

笔者对该恐龙化石埋藏地沙溪庙组泥质岩的常量元素、微量元素和稀土元素特征进行了研究，并根据泥质岩的地球化学特征讨论了物源区性质、构造背景以及物源区的风化特征。

The presence of REE tetrad effects in apatites and whole rocks of S-type granites has been reported by Sha and Chappell (1999) and Zhao et al.(1999), respectively. The REE tetrad effect in minerals, such as apatite, spessartite, beryl, alkali feldspar and spodumene, from all zones of Altay No. 3 pegmatite has been found remarkable, and the fractionations among isovalent incompatible elements in these minerals are also significant. This paper puts forward that the REE tetrad effect is one of the basic features of peraluminous melts and the origin of REE tetrad effect might be probably related to some processes prior to the formation of pegmatite magma. The immiscibile liquid separation between silicate melt and hydrosaline melt may be responsible for it.

由于阿尔泰3号伟晶岩脉各带磷灰石以及与其共生的石榴石、绿柱石、碱性长石、锂辉石矿物均存在明显的稀土"四重效应"以及相同电价、相似离子半径的不相容元素间存在显著的分异，并结合最近赵振华等(1999)和Sha and Chappell(1999)报道S型花岗岩全岩和单矿物(磷灰石、独居石、长石、黄玉等)均存在稀土"四重效应"这一现象，本文研究提出，稀土"四重效应"是富挥发分过铝质岩浆体系的一个基本特征，其机制既不可能由含稀土的副矿物早期结晶引起残余熔体相中REE含量变化的结果，也不能定性地归因于流体相与熔体相相互作用过程中稀土元素在流体/熔体之间分异的结果，而很可能与伟晶岩岩浆形成之前某些过程密切相关，S型花岗岩岩浆在液相线以上存在硅酸盐熔体与高盐熔体的不混溶液相分离有可能是过铝质岩浆体系产生稀土"四重效应"的主要原因。

Geochemical characteristics of 36 Tertiary mudstone samples from Kuqa depression show that the content of CaO is very high, which can somewhat dilute other major elements, trace elements and rare elements. Some reliable indicators for provenance analysis show the source rock nature of noncarbonate sediments. The REE distribution pattern is similar to that of the upper continental crust, characterized by enrichment of LREE and negative Eu anomalies. Some trace element ratios show that the source rocks are mainly felsic.

对库车坳陷第三系36件泥岩样品的地球化学特征分析表明，主量元素中CaO的含量很高，对其他主量元素以及微量和稀土元素有稀释作用，一些可靠的物源分析指标主要指示了非碳酸盐沉积物的源区性质；REE分布模式与上地壳相似，轻稀土元素富集，Eu负异常，微量元素比值显示源岩以长英质岩石为主。

Rhyolitic volcanic rocks are generally characterized by rich alkali, silicon, aluminum,and poor calcium, magnesium. They have relatively high Rb,Th and rather low Ba,Sr,Ti,P,and exhibit obviouslv negative europium anomaly (δEu=0.16~0.44).The εNd values of the rhyolitic volcanic rocks range from -5.93 to -2022.Basalts and rhyolites in different cycles show clear geochemical variance.

流纹质岩石总体具富碱、富硅、富铝，贫钙、贫镁特征，其Rb、Th等元素的含量较高，而Ba、Sr、Ti、P等元素含量则明显偏低，并具显著的铕负异常（εEu=0.16'0.44），岩石的εNd值变化于-5.93~~-2.22.I、II旋回玄武岩和流纹岩在地球化学特征上均具明显变异。

From the fields of regional crust-mantle structure, metallogentic settings, history of tectonic-magmatic activity, distribution of high antimony anomaly, characteristics of deposit, origin of ore-forming materials (including Sb, C, Si, S, solution and associated elements), black dikes, the relation of deposit and mantle metasomatism fluid is expounded by means of geology and geophysics. Xikuangshan antimony deposit is proved to be a typical vein deposit formed by mantle metasomatism fluid. On the basis of this knowledge, the prospecting criteria of blind orebody of the deposit are given as follows: extensive structuer which indicating the activities of mantle metasomatism fluid, change of host rocks (especially exsisting shale barrier bed), silication and carbonization alteration.

文中对地幔交代流体组成、性质、活动特点及其成岩、成矿作用作了综述与探讨；从锡矿山区域壳幔结构和成矿背景、地质构造-岩浆活动史、高锑地球化学场结构分析、矿床特征、成矿物质(包括Sb、C、Si、S、流体及伴生元素)、与成矿有时空联系的暗色脉岩等方面入手，利用地质、地球物理、地球化学手段多方面论述了矿床与地幔交代流体活动的关系，论证了锡矿山超大型锑矿的地幔交代流体成因，并以此为基础提出盲矿体地质找矿标志：即指示地幔交代流体活动的构造，尤其是具有成矿元素和碱质异常、热液蚀变的断裂构造；有利的岩石物理化学性质；硅化、碳酸盐化围岩蚀变等。

The level of soil fertility was high in GAP base, but nutrients distribution was unbalanceable: nitrogen and phosphorus in soil could basically satisfy the crop growth; but potassium was not enough.

对三七GAP基地的土壤质地、供肥特性和土壤肥力进行了调查和分析，结果表明，三七GAP基地土壤以壤质粘土为主，偏酸性，土壤肥力水平较高，但各养分因子分布不平衡，氮、磷元素基本满足三七生长的需求，而钾元素普遍不足，在栽培管理上，应根据三七的生长特点、不同生长期及具体的种植片区对养分的要求制定施肥方案，并注意多施钾肥。

The Isocon analyses also shows that the altered quartz sandstone of the Salitashi deposit which enriches in Cd, As, Ba, Sb, Ag, Co, Ni and Fe, gained Pb, Zn, Cd, Ag, Co, but lost Mn, Zr, Ba, V and Cr during it alteration, the ore and its dolomitized limestones intensively enrich in Ag, Cd, As, V, Cr, Co, Ni and Cu also.

矿石中强烈富集Ag、Cd、As和过渡族元素V、Cr、Co、Ni、Cu，且Cr、Co、Ni在矿石中的富集程度远远高于矿区碎屑岩，近矿白云质灰岩具有和矿石相近的元素富集特征，该矿床的早期矿化和后期的改造成矿作用都与深部岩浆去气有关。

The interlayer oxidized zone and the concentration of uranium has the typical characters of low temperature geochemical processes. Interlayer oxidized zone can be defined from the bedrock to horizon C under hypergene weathering by such parameters as chemical metamorphosing、index of chemical weathering and index of mineral chemical differentiation.(2)Major elements can be divided into sensitive group、 active、 weak active and inert groups according to chemical metamorphosing parameter and fractional migration potential. For major elements of multivalent in the active group( Fe_2O_3、 FeO) and U, the migration and concentration trend in interlayer oxidized zone is apparent.

层间氧化带形成和铀富集成矿是地下水在低温、常压、开放体系、非平衡状态对围岩长期作用结果，元素含量及其有关地球化学参数在氧化带不同亚带中表现出一定的变化和分布规律，除Fe_2O_3、FeO、Fe_2O_3／FeO外其它元素含量及其参数只在统计学上呈现规律性变化，而不具分带意义，具有典型的低温地球化学作用特点；利用风化作用化学蚀变参数PC值、化学风化指数ICA和矿物化学分异指数ICV将层间氧化带作用界定于表生风化作用的基岩到母质层阶段。

State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, ChinaStrontium and barium in otoliths are mainly from ambient water where fish survives.

鱼耳石中元素锶和钡主要来源于鱼类生存的水体，这两种元素通过腮或肠进入内耳淋巴液，继而以类质同象的方式沉淀在耳石晶格内部空位和晶格间隙中。

Employing high-dilute method and 5-fold excess amine prepared two new "two-armed" acyclic diamine intermediates I_a and I_b, which are also intermediates of synthesizing microcyclic compounds, and eight aromatic Schiff bases, II_, were synthesized from reaction of I_a or I_b condensing with different aromatic aldehydes. Their composition and structure were characterized by Elemental analysis, IR, UV-Vis, LIF,~1HNMR and MS. The hydrogen bond interactions and MS fragmental patterns were also discussed.3. Several novel transition metal complexes using II_a as ligand were synthesized and identified by Elemental analysis, IR, UV-Vis,~1HNMR and molar conductivity.

1，采用高度稀释及胺过量五倍的方法合成了两个具有吡啶双酰胺臂的非环二胺Ⅰ_a和Ⅰ_b，并以它们为中间体进一步合成了八个芳香席夫碱Ⅱ_a-Ⅱ_h，通过元素分析及各种波谱测试鉴定了它们的组成与结构，对化合物的UV-Vis、LIF、IR、~1HNMR及MS进行了较为详细的讨论，还探讨了席夫碱的氢键相互作用及质谱裂解方式； 2，以席夫碱Ⅱ_a为配体合成了几个新型的过渡金属配合物，并通过元素分析、UV-Vis、IR、~1HNMR、摩尔电导及DTA—TG对其进行了表征，讨论了化合物的配位情况及配体在配位中的脱质子行为。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。