质元素

Water-rock interaction demonstrates that, a gold-boring formation , i. e., a set of light metamorphic clastic gritstone, sandy slate, and tuffaceous slate in Wuqiang Runnel Formation, Ban Stream Group, act as the source of gold deposits in South-West Hunan. The gold is originally derived from volcanic eruption materials in Wuling-Xuefeng period; for the typical single gold deposit such as Mobin, which is short of sulphide, chlorine is very important in the metallogenic process; sulphur and chlorine perform as the major negative ions to form complex ions with Au throughout the gold activation and migration movement. The complex ion of chlorine and gold may keep stable in a wide range of temperature; the physical-chemical conditions in typical geothermal fluid system are of deciding significance for gold activation, migration and precipitation.

特定体系的水岩实验证实了漠滨及整个湘西南金矿的成矿元素Au和伴生元素主要源于赋矿围岩-板溪群五强溪组的一套浅变质碎屑砂岩、砂质板岩和凝灰质板岩；首次突破传统认识，证明氯在中低温热液体系中能与Au形成稳定络合物的形式进行运移，因此氯在本区Au成矿过程中起着相当重要的作用；成矿热液流体中Au主要以金硫、金氯络合物形式在溶液中迁移，阴离子∑S、Cl〓对金的活化、迁移及沉淀起主导作用，Au的伴生元素As、Sb在热液体系中与Au形成金锑、金砷络合物有利于金的进一步活化、迁移及沉淀；中低温热液流体成矿过程中，体系的物理化学参数对Au的活化、迁移及沉淀富集起决定性作用。

The characters of geochemistry are rich alkali. And at the same time the content of calcium is high. They are rich in alkali, high in Potassium, enriched in LILE, LREE and Pb, depleted in HFSE and have a small Sr, Nd, Pb isotope range. Their source is probably a kind of even metasomatic mantle. This is consistent with the fact that there is kimberlite containing flogopite in the deep-source enclosure of Cenozoic super-K alkali lava in the southern part of this rock zone.

组成这些钾质碱性岩带的岩石：在岩相上，包括深成相、浅成相和喷溢相等不同岩相；在岩性上，从超基性、基性、中性到酸性岩石；造岩矿物，从超基性到酸性岩石中均有透辉石，在基性、超基性岩中有霞石；在岩石化学成分上，所有岩石均表现出富碱高钾富钙，微量元素富集Rb、Sr、Ba等大离子亲石元素和Th、U等放射性元素，贫Nb、Ta、Zr、Hf等高场强元素；稀土元素富集轻稀土，铕负异常不明显；Sr、Nd、Pb同位素组成，显示了物质来源于富集地幔源区。

The PGE distributive patterns are the PtPd type, the Pt/Pd ratios of 0.32-0.68 are between the values of enriched sulfide tholeiite (0.38) and primitive upper mantle (1.36), and the similarity of partition patterns of chondritenormalized REE, MORB-normalized trace element and primitive mantle normalized PGE for the rocks of the three phase zones, indicate the Baimazhai intrusive body I formed by the evolution, liquation, intrusion and diagenesismetallogenesis of basaltic magma.

铂族元素配分模式为Pt-Pd型，w/w比值为0.32~0.68，介于富硫化物拉斑玄武岩(0.38)和原始上地幔(1.36)之间，以及稀土元素配分模式、微量元素蛛网图和铂族元素配分模式中不同岩石配分曲线的相似性揭示3个相带不同岩石之间的高度一致性，展示基性-超基性岩形成于玄武质岩浆演化、熔离及岩浆一次性侵入、分异成岩成矿的特征。

The structure measurement indicates that only a small amount of Bi3+ ions can not enter the A-site of La2/3Ca1/3MnO3 lattice. Because of the low melting behavior of bismuth oxide, the superfluous Bi will segregate as insulating bismuth oxides and bismuthate. Because of the segregation of Bi, the surface of the main phase has different ferromagnetic property from that of the core, namely the magnetic inhomogeneity of the samples is enhanced, which results in the broader ferromagnetism-paramagnetism transition and magnetoresistance plateaus in samples with the high Bi content.

结构测试表明Bi并不能进入La2/3Ca1/3MnO3的晶格锰位，由于A位元素的过量和铋氧化物的低熔点特性，烧结过程中Bi元素析出形成了绝缘性的第二相；并且Bi的析出导致样品主相的表面存在与主相体心磁性质不同的铁磁相，即样品的磁不均匀性增强，使得高Bi含量的样品表现出宽的铁磁-顺磁转变和磁电阻平台效应。

These data were used to infer the molecular formula and the elemental compositions of all the fragmental ions through software interpretation and, by further applying fragmentation regularities of mass spectrometry, the majority of ions were fully assigned. A base peak at m/z 402 in the mass spectrum was found as the molecular ion. The fragments were created mainly from the fragmentations of the tetrahydrofuran rings and the hydroxyl group. The most fragment products contain the dimethoxy phenyl group.

利用这些数据通过软件导出了分子式和所有碎片离子的元素组成，由此进一步根据质谱裂解规律对石梓醇分子的电子轰击质谱的主要裂解碎片给出了完全的归属，质谱中发现基峰为分子离子峰(m/z402)，裂解碎片主要来自双骈四氢呋喃环的裂解和羟基引起的裂解，绝大部分裂解产物包含二甲氧基苯基基团。

On the basis of the information obtained through field geological survey and indoor integrated petrological and petrochemical studies, it has been found that there is a clear and sharp pulsatory intrusive contact between various rock units of the rock body and a number of dark dioritic microinclusions are present. The rocks are characterized by a relatively low total REE content, relative enrichment in K, Rb, Ba and Th and relative depletion in Cr, Ti, Nb, Sr and P.

根据野外地质调查资料和室内的岩石学、岩石化学等特征的综合研究成果，发现该岩体各单元之间呈脉动式侵入接触，接触界线清晰，且含有较多暗色闪长质微粒包体；稀土总量较低，K、Rb、Ba、Th元素相对富集，Cr、Ti、Nb、 Sr、Zr、P元素相对亏损。

Sequential leaching experiments indicate fluorine in carbonate rock, phosphorite and Mo-Ni ore layer occurs principally in dissolvable forms: water-soluble, associated with carbonate or phosphorite, so fluorine in which rocks have high chemical mobility at surface conditions. Fluorine in siliceous rock, black shale and carbonaceous slate mainly occurs in undissolvable forms, which are inert at surface conditions.

氟在碳酸盐岩、磷块岩、钼、镍等多元素富集层及部分硅质岩中主要以水溶态、碳酸盐结合态等易溶形式存在，其在自然条件下的化学活动性强；而氟在碳质板岩、黑色页岩及大部分硅质岩中主要存在于难溶矿物中，其化学活动性较弱。

It is also the main factors to control the abundances of noncrystal phase. The typical feature is that the elemental concentrations in this speciation and the percentages of this speciation in samples have significantly variation down the core, especially there is a sharp change at the depth of 80cm.

3铁锰氧化物结合态是除残渣态外的又一元素主要赋存形态，是控制元素在非晶质结合态中赋存的主要因素，同时也是岩芯不同深度沉积物中元素含量和萃取比例变化最大的一个相态。

The content of platinum-group elements in samples of sulfides and gold-bearing breccia from the Taibai gold deposit was determined by the nickel sulfide fire assay and inductively coupled plasma-mass spectrometry.The results show that the PGE content in these samples is higher than that in the Baguamiao gold deposit,Qinling,but lower than that in the primitive mantle.

采用硫镍火法试金结合电感耦合等离子质谱分析了太白金矿硫化物和含金角砾岩中铂族元素的含量，结果显示，与秦岭地区八卦庙相比铂族元素含量较高，而低于原始地幔，其中铂、钯、钌富集，并结合前人研究资料对铂族元素的来源和迁移机制进行探讨。

Two novel well-defined star-graft copolymers with poly as main chain are successfully prepared by combination of anionic and atom transfer radical polymerization. Anionic copolymerized 2,5-epoxypropyl-1-ethoxyethyl ether with EO by initiation of mixture of diphenylmethylpotassium and polyol [1,1,1-trispropane or pentaerythritol] to give the well-defined three-arm star poly and four-arm star poly.

用核磁共振(~1H NMR)、红外光谱、元素分析、气相色谱—质谱、凝胶渗透色谱和基质辅助激光解吸附电离飞行时间质谱(MALDI-TOF-MS)等手段对中间产物及最终产物进行了详细地表征，证明了这种合成聚醚为主链的接枝共聚物的方法是可行的，并且是成功的。2。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。