表面涂层

The hydroxyl groups were introduced to the surface of silicone rubber by O_2 cold plasma treatment,coatings made from chitosan were chemically bonded to silicone rubber via silane-glutaraldehyde molecules and proved by the results of surface composites analysis with X-ray photoelectron spectroscopy and attenuated total reflection fourier transform infrared spectroscopy.

用氧低温等离子体处理硅橡胶，在其表面引入羟基，然后利用硅烷偶联剂的硅烷反应，通过中间物戊二醛在硅橡胶表面制备了几丁聚糖涂层。X射线光电子能谱和衰减全反射傅立叶变换红外光谱测试证实在硅橡胶表面成功制备了几丁聚糖涂层，表面接触角测试表明几丁聚糖涂层明显提高了硅橡胶的亲水性

A Si-HA coating was prepared on titanium by a biomimetic method. The surface of the Si-HA coating was porous, and there was coralloid gibbosity on the surface. Si concentration was descent in Si-HA coating from outside to inside. When the Si content increased, the coating became denser and thinner.

钛表面仿生制备的Si-HA涂层表面多孔，有珊瑚状凸起，涂层中的硅由内向外呈梯度分布；随着涂层平均含硅量增加，表面逐渐致密，涂层厚度减小。

However, in the temperature range of 1150-1300℃, the surface morphology of SiC coatings changes to rounded hillocks and the as-deposited coatings are very rough.

沉积温度和SiC涂层表面形貌的关系如下： 950℃时，沉积的SiC颗粒非常细小，为独立的球形堆积； 1000～1100℃时， CVD SiC涂层表面光滑、致密； 1150～1300℃沉积的SiC涂层呈现出球状或瘤状结构且表面粗糙。

It was also found that the protecting effect of erodents on the coating surface does exist. The protecting effect will be more evident if using erosion efficiency of unit mass erodent of sand in the slurry to describe the erosivity of erodent. Besides a model is proposed to explain the protection process. The wear mechanism of the coating is the co-operation of ploughing, cracking and ablation.

对涂层的SEM分析可知，除冲蚀粒子在涂层表面的犁沟作用，冲蚀磨损的结果造成涂层的表面生成了系列针孔，其中的一部分为溶剂挥发所至，另外还存在由增强颗粒的剥落和裂纹的扩展造成的涂层剥落产生的孔洞，这将可能为水的吸收和扩散造成有利条件，使复合涂层亚表层产生内应力。

Results show that the alumina formed on the corroded NiCoCrAlY coating is roughness, cracked and incontinuous and many pits was formed on the surface of the coating after the salt-spray test.

试验结果表明：经过盐雾腐蚀的涂层表面的均匀性和完整性均被破坏，涂层表面产生了大量的腐蚀坑；高温循环氧化以后，表面形成的Al2 O3 氧化膜变得粗糙、破碎且不连续，而且氧化膜容易剥落，降低了涂层的高温抗氧化能力，缩短了涂层的使用寿命

There was an obvious phenomenon of mechanical occlusion on the cold spray coating interface, and the rolled coating had the phenomenon of metallurgical bonding; The structure of cold-sprayed coating is dense. The poriness of the cold-sprayed coating gradually reduce as the coating's thickness increase.

结果 涂层界面形貌的不同反映出两种涂层的结合机理不尽相同，冷喷涂层界面出现明显的机械咬合现象，而轧制涂层以冶金结合为主；冷喷涂层组织致密，孔隙率随着喷涂厚度的增加逐渐降低；冷喷涂层的表面粗糙度高于轧制覆铜板，有必要对其进行一道轧制处理，改善涂层表面平整度。

A Dense scale on the2O3(Cr/Y=4/1) coated specimen;2O3(Al/Y=3.6/1) coated specimen; Oxide nodules formed at the corner on the specimen coated with2O3(Cr/Y=2/1) deposited for 15 s; Locally spalled scale on the same specimen as in; The trace of cracks in the deposited oxide film on the scale formed on the specimen coated with2O3 (Cr/Y=2/1) deposited for 60 s; Showing the similar trace on the same specimen as in b

沉积复合OTFC试样的氧化层形貌有如下特征：(1)氧化层绝大部分致密、完整、与基体附着良好，晶粒细小（图7a，7b）；(2)在短时间(15s)沉积2O3 OTFC试样的局部表面出现了不均匀氧化（图7c，7d），但只是在沉积Cr/Y=4/1膜试样的局部表面产生了类似无涂层Fe25Cr上剥落的厚膜（图7d）；(3)沉积2O3(Cr/Y=2/1) 60s（图7e）与15s（图7c）的结果不同，前者整个试样表面氧化产物颗粒细小，无粗大氧化物颗粒形成；(4)沉积2O3(Cr/Y=2/1) 60s和2O3(Al/Y=3.6/1)薄膜的试样由于氧化增重非常少，氧化层很薄，刻印着涂层中局部出现的裂纹（图7e，7f），这种印迹的保留可能反映着传质机制的改变，即新氧化物由在外表面形成转变为在外表面以下形成。

The results show that in the applied load range of 10250 N, the mass loss rate of coated AZ91D alloy can be identified to three stages, which are related with whether the coating is worn out. Abrasion is the main mechanism for the coated alloy. The friction coefficient of the coated alloy during sliding wear appears oscillation before it reaches a constant value, which is close to the μ value of the matrix alloy. The mass loss rate of coated alloy increases slightly with increasing applied load when the applied load is more than 150 N because of high plastic deformation accommodation on the matrix alloy surface.

结果表明：根据载荷大小，涂层处理后AZ91D镁合金的磨损行为明显分为3个阶段，这些阶段同陶瓷层是否磨穿密切相关；微弧氧化涂层AZ91D镁合金的磨损机理主要是磨粒磨损；受表面状况的影响，陶瓷涂层的摩擦因数在 0.20~0.45 间波动；在较高载荷下，涂层被磨穿后，涂层的摩擦因数趋于基体合金的摩擦因数，涂层合金的表面变形能力提高，该阶段质量磨损速率随载荷增加，趋势变得缓慢。

In this thesis, the research about surface modification of titanium alloy was carried on starting with improving stability of calcium phosphate biomedical coating by force of chemical treatment, Physical Vapor Deposition of titanium metal at high temperature and Electrophoresis Codeposition and sintering technology of the coating. By way of the studying of graded design of microstructure and composition of coating and EPCD and sintering technology, a systemic technology by which a calcium phosphate graded ceramic coating was prepared and sintered rapidly on the surface of a complex shaped product was obtainedand a high function titanium alloy/bioglass/hydroxyapatitegraded coating wasdeveloped.

本文从改善钛合金表面钙磷生物涂层的稳定性入手，采用化学处理、高温真空镀钛和电泳共沉积--烧结等技术对钛合金的表面进行了改性的研究，通过对涂层的结构和组成的梯度设计和EPCD--烧结技术的研究，获得了较系统的能在复杂形状的制品表面涂覆钙磷梯度涂层及其低温快速烧结技术，并研制出了高性能的钛合金／生物玻璃／羟基磷灰石梯度涂层。

The polyurea coating was tested with Taber tribomachine and the highp ressure water jet erosion tester for studying the wear behavior of polyure coating under conditions of dry friction and highspeed water jet contained sand. The morphology of the coating was observed with SEM and Chromatic confocal 3D Profiler. The surface component of test samp les was measured by FT2IR Spectrometer and Electron Energy Disperse Spectroscopy. The p roperties of polyurea coating under two testing conditionswas analyzed.

为研究聚脲涂层在干摩擦条件下和高速含砂水流冲蚀条件下的性能变化情况，用 Taber 磨损试验机和高速含沙水射冲蚀磨损试验机测试了聚脲涂层的磨损性能，用扫描电子显微镜和白光共焦三维轮廓仪观测涂层的磨损表面形貌，用表面红外光谱和电子显微镜能谱元素分析了涂层表面试验前后的组分变化，分析了涂层在2种摩擦条件下的磨损情况。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。