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Surface activities and colloidal properties of amphoteric surfactants were introduced and relationship of concentration and cluster structure of amphoteric surfactante was given.

介绍了两性表面活性剂的表面活性和胶体性质,给出了浓度与表面活性剂团簇结构之间的关系。

The results showed that the copolymer possesses good thickening property, and the performance of decreasing the interfacial tension between oil and water.

由于高分子表面活性剂具有高分子的增稠性和低分子表面活性剂的表面活性,在三次采油中具有广泛的应用。

The intermediate decyl-glycidol ether of Gemini phosphate surfactant was synthesized with decanol and epichlorohydrin in the presence of phase-transfer catalyst; the intermediate decyl digomeric glycol of Gemini phosphate surfactant was prepared by opening ring reaction of decyl glycide ether and glycol in the presence of potassium as catalyst; and the influence of type and dosage of phase-transfer catalysts was studied.

以正癸醇与环氧氯丙烷为原料在相转移催化剂存在的条件下合成Gemini磷酸酯表面活性剂的中间体I-正癸基缩水甘油醚,讨论催化剂种类及用量对反应的影响;以乙二醇和正癸基缩水甘油醚为原料,金属钾为催化剂合成Gemini磷酸酯表面活性剂的中间体Ⅱ-正癸基低聚二醇,讨论催化剂种类与用量对反应的影响;以P2O5与正癸基低聚二醇为原料合成Gemini磷酸酯表面活性剂,讨论投料比、反应温度和反应时间等因素对反应的影响。

The hydrophobic monomers such as glycidyl octyl dimethylammonium chloride, glycidyl dodecyl dimethylammonium chloride, glycidyl tetradecyl dimethylammonium chloride was applied to the hydrophobic modification of two kinds of sodium cellulose sulfate in isopropyl alcohol under 65℃.The success of synthesis of a kind of novel amphoteric surfactant by FT-IR and NMR. 3. By the measuring surface tension of all kinds of amphoteric polymeric surfactants based on cellulose, the critic micelle concentration was obtained such as 0.4wt%、0.3wt%、0.25wt% and corresponding surface tension was about 30mN/m

通过动态接触角测量仪确定了各种纤维素表面活性剂的表面张力和临界胶束浓度,结果表明该类表面活性剂可与小分子表面活性剂的降低表面张力的能力相媲美,最低可达28.41 mN/m,随着疏水基中碳链的增长,降低表面张力的能力下降,而临界胶束浓度从0.4wt%相应降低0.25wt%;应用环境扫描电镜确定其不同浓度胶束形态,结果表明在较低浓度下形成棒状单分子胶束,随着浓度的升高,单分子胶束逐渐聚集成树枝状胶束,进一步提高浓度,则聚集成网状结构;此外,采用了高级流变仪对其溶液的流变性质进行了研究,结果表明其溶液属于剪切变稀流体,是高分子溶液特有的性质。

The effects of different of categories surfactants, the proportion of surfactant and cosurfactant , the chain lengths of alcohol and alkane, temperatures and pH values on the W/O microemulsion phase areas are systematically studied in the dissertation. SEM and laser scatting techniques are used to verify particles'sizes of W/O microemulsion. Consequently, a system TritonX-100/n-C〓H〓OH (weight ratio 1: 1)/C〓H〓/H〓O is obtained which is a stable system with relatively large W/O microemulsion phase area.

本文系统研究了表面活性剂种类、助表面活性剂的链长、表面活性剂和醇的配比、烷烃的链长以及温度、pH值等对W/O微乳液相区域的影响,并用SEM、激光光散射等对微乳液粒度进行了表征,从而获得一种稳定的、W/O微乳液区域较大的体系:壬基苯酚聚氧乙烯醚(TritonX-100)/正戊醇(质量比1:1)/环己烷/水体系。

It is shown from the study that influence of co-use anionic and nonionic surfactants on the enzyme activity are less than single anionic surfactant Multi-component stabilizers are much better than single-component stabilizers for enzyme activity.

研究结果表明:阴离子表面活性剂与非离子或另一种阴离子表面活性剂复配后,对酶活性的影响明显小于单一阴离子表面活性剂的影响。多组分稳定剂比单组分稳定剂对改善酶的稳定作用好得多。

Alkyl diphenyl ether disulfonate is a serie of anionic surfactants with many functions. It has two hydrophilic head groups and different from conventional surfactants.

烷基二苯醚二磺酸钠是一类在结构和性能上有别于传统表面活性剂的多功能性双亲水基型阴离子表面活性剂,具有卓越的表面化学性能及应用性能。

But, at present, the production of a soil displacement agent from heavy alkylbenzene sulfonate and petroleum sulfonate as oil displacement agent, there were still some problems as the instable quality, produce scale. It is necessary to develop a feasible production process of arylalkyl sulfonate, alkylated diphenyl ether sulfonate and fatty alcohol ether sulfonate as they can be used as oil displacement assistant in some special oil reservoir. In which Because their abundant raw material, big changeability of structure, high electrolyte tolerance, especial strong calcium tolerance, fatty alcohol ether sulfonate has huge industrialized value.

指出重烷基苯磺酸盐和石油磺酸盐作为三次采油的主表面活性剂,目前在工业化生产中仍存在一些问题,产品质量不太稳定,需进一步改进生产工艺技术,提高产品质量,扩大生产规模;芳基烷基磺酸盐和烷基二苯醚磺酸盐可作为助表面活性剂用于特殊的油藏条件,有必要尽快开发可行的工业化生产工艺;脂肪醇醚磺酸盐类表面活性剂的原料来源丰富,分子结构可变性强,耐电解质能力强,尤其是耐钙能力强,应用领域广,极具工业化价值。

Surfactant sorbed on soil increases the adsorption capacity of the soil; however, the microemulsion composed of surfactant and organic materials decreases the adsorption capacity of the soil.

增加离子强度对非离子表面活性剂的吸附无影响,却可略微增加阴离子表面活性剂的吸附。表面活性剂吸附于土壤后对憎水性污染物在土壤/水间的分配行为产生显著作用。

CTAB could form well-stabilized films on the surface of HPAM solution, this process is dependent on the linear density and conformation of the polymer chain; it is reasonable to suppose that a complex, which is surface active, was formed between CTAB and HPAM.

阳离子表面活性剂能在HPAM水溶液的表面成膜,表面活性剂的成膜能力与它本身的HLB有关,还与亚相中HPAM的线性电荷密度以及高分子在溶液中的分子构象有关。

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