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表面活性剂

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Surface activities and colloidal properties of amphoteric surfactants were introduced and relationship of concentration and cluster structure of amphoteric surfactante was given.

介绍了两性表面活性剂的表面活性和胶体性质,给出了浓度与表面活性剂团簇结构之间的关系。

The surface activity dose joins the queen, since jointly there is the water loving base group in the surface activity dose and detest the water base group in molecular structure , the pole is as a result easy to wind notable lessening menstruum surface tension from inside transition to interface in the solution.

液体分子在和空气等接触的表面会形成一层特殊的结构,表现为表面张力或表面能。表面活性剂加入后,由于表面活性剂分子结构中合有亲水基团和憎水基团,因而在溶液中极易从内部跃迁到界面上显著降低溶剂的表面张力。

The longer the alkyl-chains are, the stronger the surface activity of cosurfactant is. It's liable to form mixed film at interface with surfactant. Alcohol with short chain has weak surface activity and"solubilize" in reverse micromulsion to adjust micropolarity of microemulsion, so alcohol not only to act as cosurfactant but also act as"cosolute"in reverse microemulsion.

醇的碳链越长,表面活性越强,越易于进入界面与表面活性剂形成混合膜,短链醇的表面活性弱,主要溶解于反相微乳液中调节反相微乳液的微极性;因而醇在反相微乳液中的作用不仅是助表面活性剂也是助&溶剂&。

But, at present, the production of a soil displacement agent from heavy alkylbenzene sulfonate and petroleum sulfonate as oil displacement agent, there were still some problems as the instable quality, produce scale. It is necessary to develop a feasible production process of arylalkyl sulfonate, alkylated diphenyl ether sulfonate and fatty alcohol ether sulfonate as they can be used as oil displacement assistant in some special oil reservoir. In which Because their abundant raw material, big changeability of structure, high electrolyte tolerance, especial strong calcium tolerance, fatty alcohol ether sulfonate has huge industrialized value.

指出重烷基苯磺酸盐和石油磺酸盐作为三次采油的主表面活性剂,目前在工业化生产中仍存在一些问题,产品质量不太稳定,需进一步改进生产工艺技术,提高产品质量,扩大生产规模;芳基烷基磺酸盐和烷基二苯醚磺酸盐可作为助表面活性剂用于特殊的油藏条件,有必要尽快开发可行的工业化生产工艺;脂肪醇醚磺酸盐类表面活性剂的原料来源丰富,分子结构可变性强,耐电解质能力强,尤其是耐钙能力强,应用领域广,极具工业化价值。

This article introduces the development of antibiotic and disinfectant hand cleaner with skin-cared effect, on the precondition of its disinfectant effect, by treating with contents of trace of copper sulfate, dramatically enhancing the effectiveness of disinfection in cationic surfactants with cetylpyridinium chloride, and avoiding treating with other special sterilizations for disinfection.

在保证杀菌效果的前提下,通过添加微量硫酸铜的办法,对阳离子表面活性剂十六烷基吡啶氯化铵的杀菌能力进行大幅增效,使得消毒杀菌洗手液中不再添加其他专用消毒剂。并通过选择温和表面活性剂复配、限制表面活性剂总量等办法,最大程度地减少消毒杀茵洗手液对皮肤的损害。再辅添芦荟浸膏等护肤成分对皮肤进行修复和保湿。由此研制出具有良好杀菌、护肤和去污效果的护肤型消毒杀菌洗手液

The washing experiment of soil contaminated by petroleum alkane was performed with two kinds of biosurfactants in laboratory. The results showed that biosurfactant would enhance on removal of residual alkane in soil, after washing with 20 pore volume solution the removal rate with BS-UC and MELs were three times and twice as that of water, respectively.

在实验室内对南极假丝酵母产生的两种生物表面活性剂进行了石油烃类污染土壤的冲洗实验,结果表明,经过大约20个孔隙体积的冲洗,BS-UC溶液的除油率为清水的三倍,MEL溶液为清水的两倍,这表明该生物表面活性剂能够加速土壤残油的去除,而来自污染底物的生物表面活性剂更具有优越性。

The mechanisms responsible for synergism between alkyl benzene sulfonate and methyl oleate in surfactant/brine/model oil and surfactant/alkali/model oil systems were studied.

摘要研究了表面活性剂/盐/模拟油体系与表面活性剂/碱/模拟油体系中油酸甲醴与表面活性剂协同效应机理。

As shown in the experimental results: as the conductor of petroleum biological degradation, the quantity of microorganism is the important factor of petroleum degradation efficiency, the huge natural capacity of microorganism in soil is its foundation of bioremediation; petroleum density in certain scope do not affect for the degradation efficiency of petroleum, and in the density of 5%, its initial degradation efficiency is higher, however after training 40 days, this kind of advantage change weak gradually, the reason may be the petroleum of high density probably having certain poison role for microorganism; the best ecological condition of petroleum contaminated soil bioremediation is that nutrition material C: N = 60, electron receives body HiOi joining quantity amount to 12 mg/g, water content is 50%, surface activator is anion surface activator of 12 Wan base benzene sulphur sour sodium; the relation of primary and secondary of factor is water content, surface activator, nutrition material and electron receiver.

试验研究结果表明:作为石油生物降解的执行者,微生物的数量是影响石油降解效率的重要因素,土壤中微生物的巨大的自然容量是其生物修复的基础;石油浓度在一定范围内对石油的降解效率并没有影响,并且在5%浓度时,其起始降解效率较高,但是到了培养40天以后,这种优势渐渐变弱,可能还是高浓度的石油对微生物有一定的毒害作用;石油污染土壤生物修复的最佳生态条件为:营养物质C:N为60,电子受体H_2O_2的累计加入量为12mg/g,含水量为50%,表面活性剂为阴离子表面活性剂十二烷基苯磺酸钠;因素的主次关系为:含水量、表面活性剂、营养物质和电子受体。

Surfactant sorbed on soil increases the adsorption capacity of the soil; however, the microemulsion composed of surfactant and organic materials decreases the adsorption capacity of the soil.

增加离子强度对非离子表面活性剂的吸附无影响,却可略微增加阴离子表面活性剂的吸附。表面活性剂吸附于土壤后对憎水性污染物在土壤/水间的分配行为产生显著作用。

It has promoted the growth of new surfactants by the development of new technologies and changes in consumption concepts.

文章就表面活性剂市场的现状及发展趋势进行了论述,并且介绍了一些国际化工企业或表面活性剂生产商在表面活性剂研发方面的动态及其新产品开发,以及应对 REACH 法规的措施。

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