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表面活性剂

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In this paper, through a series of experiments, two series of quaternary-ammounium Gemini surfactants were synthesized, namely the pair alkylene double quaternary ammonium salt surfactant m-s-m·2Br and the pair the alkylene double quaternary ammonium salt surfactant -s-·2Br. We has carried on the attribute with the infrared spectrum to its structure, and to affected the factor which the synthesis pair the alkylene double quaternary ammonium salt surfactant responded to carry on the discussion. We has discovered the synthesis pair the ethylene double quaternary ammonium salt surfactant m-2-m·2Br optimum condition: The bromo alkane and a tetramethyl ethylene diamine mole of ratio is 3.0: 1.0, makes the solvent by the ethyl alcohol, 80℃ under responds for 48 hours in the backflow temperature; Synthesis pair alkylene double quaternary ammonium salt surfactant 12-S-12 ·2Br optimum condition: 12 tertiary amine and 1, 3- propylene dibromide (1, 4- two bromines butane) a mole of ratio is 2.2: 1.0, makes the solvent by the ethyl alcohol, responds for 48 hours in the constant temperature 80 ℃ under backflow.

本文通过一系列的实验,合成了两个系列的Gemini型表面活性剂,即双烷撑双季铵盐表面活性剂m-s-m·2Br和双烷撑双季铵盐表面活性剂-s-·2Br,用红外光谱对其结构进行了表征,并且对影响合成双烷撑双季铵盐表面活性剂反应的因素进行了讨论,找出了合成双乙撑双季铵盐表面活性剂m-2-m·2Br的最佳条件:溴代烷与四甲基乙二胺的摩尔比为3.0:1.0,以乙醇作溶剂,在回流温度80℃下反应48小时;合成双烷撑双季铵盐表面活性剂12-s-12·2Br的最佳条件:十二叔胺与1,3-二溴丙烷(1,4-二溴丁烷)摩尔比为2.2:1.0,以乙醇作溶剂,在恒温80℃下回流反应48小时。

We also get the proportion of the four surfactants(30:2:1:8).Studing the factors of temperature and metal cation,we found that the floatability resisting to the low temperature and metal cation are improved with the addition.

高岭石浮选体系中,表面活性剂的组合-添加顺序同样能影响表面活性剂的作用效果,表面活性剂后加能提高高岭石的回收率,表面活性剂先添加和预先混合再加能降低其回收率。

In this paper, the surface tension in four types of surfactant solutions, such as SAS, 1631, CAB-35 and JFCS in different concentrations were tested by using automatic surface tensiometer and the critical micelle concentration of each surfactant solution was determined which could be used as the mixing concentration of four types of surfactant solutions and the experiments of effective simulation of dust-settling by spraying them in fully mechanized caving face were carried out.

应用全自动表面张力仪对SAS、1631、CAB-35和JFCS 4种表面活性剂溶液不同浓度下的表面张力进行了测试,确定其临界胶束浓度,并以此浓度作为4种表面活性剂溶液的配比浓度;对4种表面活性剂溶液进行了综放工作面喷雾降尘有效性模拟实验,实验结果表明,所选取用4种表面活性剂溶液降尘效率均比清水有较大提高,对呼尘的降尘效率皆在90%以上;表面张力较小是选定综放工作表面活性剂溶液的重要标准,但非唯一标准。

At present, a kind of novel surfactant oligomeric surfactant which have high surface activity have become one of focus on surfactant research. A typical example of them is dimeric or Gemini surfactant.

当前,一类新型的表面活性剂—低聚表面活性剂成为研究的热点,其中典型的例子是二聚表面活性剂,也称为双子表面活性剂

Its solution behaviors are similar to and even better than those of corresponding polyelectrolytes singly modified with the same hydrophobe to the added surfactant.

通过溶液共聚,将碳氢和氟碳这两种疏水单体无规地接枝到聚电解质主链上,得到的这类混合改性的聚电解质无论与碳氢小分子表面活性剂还是与氟碳小分子表面活性剂作用均表现出和同种大分子表面活性剂与小分子表面活性剂作用时相似甚至更好的缔合情形。

The results show that the surfactant species impact apparently on the purity, dispersion degree and particle size of the reducing sample. The non-ion surfactants can improve the dissemination of ultrafine silver particles, but both the dispersive effects of cation and anion surfactants are unapparent.

结果表明:表面活性剂的种类对制备样品的纯度、分散性和颗粒大小有着重要的影响,其中阳离子表面活性剂和阴离子表面活性剂的分散效果不明显,非离子表面活性剂的分散效果最好。

The fluorescent intensity ratio of the first vibronic peak (λ=373 nm) to the third vibronic peak (λ=383 nm) of pyrene solubilized in micelle decreased gradually, which was different from the conventional surfactant, such as SDS. The aberrant property indicated a broad micelle size for the m+nAr-T surfactants. That is, the aggregates of the studied surfactants gradually grew in size with increasing concentration over wide concentration range.

与传统表面活性剂不同,增溶于N-酰基牛磺酸钠胶团中的芘的第一个电子振动峰(λ=372nm)的荧光强度I1和第三个电子振动峰(λ=385nm)的荧光强度I3之比I1/I3值随着表面活性剂浓度的增加而缓慢降低,说明了N-酰基牛磺酸钠表面活性剂在低浓度区形成疏松的聚集体,随着浓度的增大则有更多的表面活性剂分子挤入已形成的聚集体。

Comparison of Insecticidal Activities between Cyfluthrin and Its Preparation of Sample ( beta-cyfluthrin ) by Epimerization for the Army Worm;2. Toxicity and Field Effect of Different Ratios of Rotenone to Beta-cyfluthrin against Uroleucon gobonis;3. The relationship of the content of mixed surfactant , the content of co-surfactant and the maxium addition content of beta-cyfluthrin in the formation of beta-cyfluthrin microemulsion were studied, and a math theory model was established by using multivatiable linear regression analysis.

通过研究高效氟氯氰菊酯微乳剂形成过程中表面活性剂混剂、助表面活性剂与高效氟氯氰菊酯最大加入量的关系,利用多元回归处理方法,建立了表面活性剂混剂、助表面活性剂与高效氟氯氰菊酯最大加入量三者之间的数学模型;通过测定不同温度下高效氟氯氰菊酯的最大加入量,得出高效氟氯氰菊酯最大加入量随温度升高而增大的规律。

For the mieroemulsions, Miglyol 812 was chosen as oil phase, SbPC and HS-15~ as surfactants, PEG400 and ethanol (7:3) as cosurfactant and the double-distilled water as water phase. Pseudo-ternary phase diagrams were constructed to obtain the concentration range of each component for the microemulsion formation. The effects of various ratio of SbPC to HS-15 and different weight ratios of surfactant to cosurfactant on the droplet size were investigated, as well as viscosity and stability of microemulsion. The constitute of stable blank ME with more oil and little surfactant was confirmed.

分别以IPM和Miglyol 812作为油相、豆磷脂与HS-15为表面活性剂、PEG 400和乙醇作为助表面活性剂、重蒸水作为水相,绘制伪三元相图,研究各组分的组成对微乳形成的影响,并考察了不同油相、不同表面活性剂、助表面活性剂的组成变化对制剂粒径、粘度及稳定性的影响,确定了含有较多油相、较少表面活性剂的稳定空白微乳的组成。

Based on these results, it is reasonable to assume that cationic surfactant could form well-stabilized films on the surface of partially hydrated polyacrylamide solution, as a result a kind of surface active complex was formed between cationic surfactant and HPAM.

总之,本论文系统研究了阳离子表面活性剂和不同水解度的聚丙烯酰胺之间的相互作用,发现阳离子表面活性剂能在HPAM水溶液表面成膜,这和表面活性剂的HLB值有关,还与HPAM的水解度以及溶液的pH值有关;两者之间的静电引力是主要驱动力,这一过程又被表面活性剂链之间的疏水相互作用所增强。

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