表面

The results showed that loading Ag^＋, Ni^2＋, Cu^2＋ or Zn^2＋ ion on the activated carbon obviously improved its adsorption of benzothiophene, while loading Fe^3＋ or Co^3＋ ion on the activated carbon caused a decrease in its adsorption of benzothiophene in comparison with the original unloaded activated carbon, which was due to the variation of the nature of soft and hard acid on the surface of the activated carbon.

采用密度泛函数理论法计算结果表明，苯并噻吩的电负性χ为2.638，属软碱类物质；由于Ag^＋为软酸，活性炭负载Ag^＋离子，增加了其局部表面的软酸，从而增强了对苯并噻吩硫化物的吸附；由于Ni^2＋、Cu^2＋和Zn^2＋离子属交界酸，负载Ni^2＋、Cu^2＋、Zn^2＋离子增加了活性炭表面的交界酸，也在一定程度上提高了其表面对苯并噻吩硫化物的吸附；当活性炭表面负载了硬酸性Fe^3＋或Co^3＋离子，其局部表面硬酸增大从而降低了其对苯并噻吩的吸附。

The precision lapping technology to machine the copper substrate using semi-fixed abrasive plate was studied. The surface roughness and material removal rate as the evaluation of indicators, the influences of the different lapping parameters on the surface roughness and material removal rate were discussed and analyzed. Experimental results indicated that the copper substrate could be efficiently machined by semi-fixed abrasive plate of 800(superscript #) SiC abrasive, and the initial roughness Ra of a machined surface could be improved from 0.553μm to 0.28μm in 10min, produced an ideal rarely scratch surface. Then processed copper polished by diamonded grinding paste, it could be satisfied for the Ni-Pd-P alloy thin film growth.

主要研究半固着磨具精密研磨非晶态Ni-Pd-P合金薄膜铜片衬底，以铜片衬底的表面粗糙度和材料去除率为评价指标，探讨了研磨过程中不同的工艺参数对铜片表面粗糙度和材料去除率的影响结果表明：用800 SiC半固着磨具对铜片衬底进行研磨加工，10min后铜片表面粗糙度Ra可由0553μm减小到0.28μm，同时表面无深划痕：加工后的铜片再经金刚石研磨膏抛光可快速获得满足Ni-Pd-P合金薄膜生长用的铜片衬底表面。

The method connects the exponentially attenuating dividable auto-correlation function which is often used in the study of the lubricating behaviors of rough surfaces, to the theoretical model for studying the contact behaviors of rough surfaces and it will be a foundation for studying the lubrication and failure problems of sliding frictional pairs with anisotropic surfaces.

第三章对Onions-Archard的理论接触模型进行扩展，给出了计算各向异性粗糙表面接触性能的简便方法，并将粗糙表面润滑效应研究中常用的表征粗糙表面的指数衰减可分自相关函数和粗糙表面接触性能研究的理论模型联系了起来，为研究混合润滑工况下各向异性粗糙表面摩擦副的润滑和失效问题提供了基础。

The heat transfer experiments were conducted on dropwise condensation of steam on the surfaces with gradient surface energy.

对空气中水滴在水平梯度表面能材料表面上的运动现象和表面倾角为0°、30°、60°和90°情况下，梯度表面能材料表面上的水蒸气滴状凝结换热进行了可视化实验，研究了凝结液滴的长大、聚并、运动和脱落现象。

The batch seeded isothermal desupersaturation experiments of SPM in aqueous solution were carried out and the overall crystal growth kinetics parameters were determined by the nonlinear optimization techniques. Assuming that the volume diffusion rate at growth is equal to the mass transfer rate at dissolution under the same conditions, the two-step crystal growth rate parameters can be determined. At the fow supersaturation, the surface integration rate is proportional to relative surface supersaturation.

通过测量螺旋霉素均相成核动力学，获得了表面能的值，估算出表面熵因子的值在1.41～1.56之间，从而可以推断出螺旋霉素晶体生长的表面反应速率同表面相对过饱和度成线性关系，这种生长机理同第四章得到的结果是相吻合的；利用估算的表面熵因子的值，把螺旋霉素晶体看作为简单的立方科瑟尔晶体，根据能量最低原理，对螺旋霉素的晶体生长进行了模拟。

Abstract］ Objective To Treating the nano-SiO2 particle by silicon coupling reagent, functionalize the SiO2 by making double bond on its surface. Polymerizing on the surface of nano-SiO2 surface by the method called emulsion polymerization, the nano-SiO2 is covered by polymer to get the PMMA-KH-570-nano-SiO2 complex material. Test the surface structure of the surface of nano-SiO2 by FTIR, and test sort of its mechanical performances.Comparing the treated nano-SiO2 which is directly dispended in the PMMA emulsion with the SiO2 without any treatment, we are trying to find an effective method which can not only increase the dispersion of SiO2, but also improve the mechanical performance of the artificial teeth.

目的 通过硅烷偶联剂KH-570处理SiO2纳米粒子，向其表面引入双键使其功能化，采用乳液聚合的方法在SiO2纳米粒子表面进行接枝聚合，实现高分子对SiO2纳米粒子的表面包覆处理，制得PMMA－KH-570－SiO2纳米复合材料，采用FTIR对SiO2纳米粒子表面结构进行了表征研究，并且测定了它的多种机械性能，与表面处理过的SiO2纳米粒子直接分散至PMMA乳液中制得的复合材料、未添加任何增强物质的空白组进行比较，探索一种能够提高SiO2在基体中的分散性，为义齿复合材料的研究和开发提供理论依据和参考。

Through designing of composition and structure of the bioactive graded coating,innerstress and its distribution in the coating were analyzed and calculated, the resultsshowed that when composition distribution coefficient n was 1.5, a reasonable stressdistribution could be got, that was at the beginning of deposition the suspension containingrichly BG granules was used so that a rich BG granules layer, a good transitional layerbetween BG layer at the bottom and the coating could be obtained at the titanium alloy side,the bottom of the coating; the stress value near the interface and surface and its character,pressure stress or tensile stress, were decided by the character of its composition itself.Changing composition distribution coefficient n could only change the variation tendency ofstress in the coating, but did not change the stress distribution rule in the coating. Thethinner the coating is, the sharper stress variation in the coating is, which does not mean thatthicker coating is better because the thicker the coating is, the little the permitteddeformation of coating is, so the coating thickness should be thinner, for example, about50μm for bending applications, but for applications only bearing pure shear stress, such asroot of tooth implant, the coating can be thicker little, for instance, about 80～100μm. The study on electrification characteristic and electrophoresis deposition of HAand BG granules in aqueous and non-aqueous solution system found that EPD almost didn'toccur in aqueous solution system. However, because HA granules take position charges inabsolute alcohol, a homogeneous EPD be carried out on the cathode titanium alloy slice, but taking negative charge in absolute alcohol the BG granules not be deposited on the cathode. A guided HA crystallizing, 100～300nm, on surface of the BG granules be realized by metathetical reaction, which cover BG granules with HA microcrystals and make the covered BG granules taking position charges in absolute alcohol, sequentially realize the EPCD of the BG and HA granules on the cathode, so it is feasible to make a titanium alloy/BG/HA bioactive graded coating by making use of EPCD technology. The corrosion experiment of rich boron bioglass coating and plasma spray coating showed that split phase, rich boron and rich silicon phase, occurred during its preparation. In basic medium the corrosion behavior of 〓 BG coating showed uniformity corrosion, the corrosion mostly occurred at rich boron phase area, therefore batch formula design of BGshould avoid the occurring of split phase. The corrosion appearance of plasma spray coatingappeared a non-uniform corrosion, mostly occurred at the edge of the laminated HA moltendrops, and emerged an accelerated corrosion tendency, which will easyly lead to corrosioncrackles extending to the interface and the happening of osmotic interfacial corrosion, thatmay be one of the major reasons leading to the coating cracking-off in the later period. Thetesting results of thermal expansion coefficient of 〓 and 〓BG showed the thermalexpansion coefficient of 〓 BG matched with that of titanium alloy better, and 〓 BG couldsinter with titanium alloy into densification enamel layer at low temperature (720℃).

将Ti6Al4V合金在1000℃下进行真空热处理会降低其力学性能，且合金内的V元素会向表面富集，因此，钛合金真空热处理和表面涂层的烧结温度不能过高，即应低于其相转变点；通过对生物活性梯度涂层的组成和结构的设计，分析和计算了梯度涂层内的应力大小和分布，结果表明：对于本研究，当成分分布系数n=1.5时，可以获得较合理的涂层力学性能，即在沉积开始时，采用富含BG颗粒的悬浮液，以便在钛合金侧获得同底层BG有良好过渡的富BG涂层；梯度涂层界面和表面的应力大小、性质由材料组成本身的性质决定，改变成分分布系数，只能改变涂层内应力变化的趋势；涂层的厚薄不影响涂层内的应力分布规律，但涂层越薄，涂层内的应力变化越快，但这并不意味着涂层越厚越好，因为涂层越厚，涂层允许的变形越小，对于应用于弯曲受力部位的涂层而言，涂层应薄一点为好(50μm)；而对于仅纯受剪切应力的部位，如牙根种植体，涂层可适当加厚(80～100μm)；通过对HA和BG颗粒在水溶液体系和非水溶液体系中的带电特性和电泳沉积的研究发现，它们在水溶液体系中很难发生电沉积；在无水乙醇溶液中，HA颗粒带正电，可在阴极钛合金片上发生均匀的电泳沉积，而BG颗粒则带负电荷；利用复分解反应法，可以制得100～300nm的HA，通过诱导HA在BG颗粒表面结晶，可对BG颗粒进行表面包覆，获得了被HA包覆的BG颗粒，改变了BG颗粒表面的带电特性，使BG和HA颗粒在无水乙醇中均带上正电荷，从而实现了HA和BG颗粒在阴极上的共沉积。

According to the causes,the surface defects can be divided into blister containing non-metallic inclusion,blister without non-metallic inclusion and "raindrop","gills","mountained".

根据产生原因可分为含有非金属夹杂的气囊表面缺陷；不含有非金属夹杂的气囊表面缺陷；由气泡产生的&雨点&状表面缺陷；&鱼鳞&状表面缺陷；&山水画&状表面缺陷。

The results show that the maximum growth quantity of Nocardia can be achieved after culturing 120 h and obvious selective adsorption of Nocardia on the surface of pyrite and sphalerite can be detected. The maximum adsorption rate on the surface of pyrite is 96.99%, whereas it is less than 20% in the case of sphalerite. Adsorption equilibrium can be attained within 20 min on the surfaces of the two minerals. pH value is the key factor influencing upon selective adsorption, and the difference of adsorption quantity on the surfaces of two minerals is apparent when pH is between 4 and 10. Slurry concentration over 6 g/L is favorable to selective adsorption. Nocardia cell concentration, stirring speed and temperature have no obviously effect on selective adsorption.

结果表明：培养120 h后诺卡氏菌达到最大生长量；诺卡氏菌在黄铁矿和闪锌矿表面发生明显的选择性吸附，在黄铁矿表面的最大吸附率可达到96.99％，而在闪锌矿表面的吸附率大都在20％以下；诺卡氏菌在两种矿物表面于20 min内即可达到吸附平衡； pH值是影响诺卡氏菌在两种矿物表面发生选择性吸附的关键因素， pH在4～10之间时，选择性吸附现象明显；矿浆浓度超过6 g/L时有利于发生选择性吸附；细胞悬浊液浓度、搅拌速度和温度对吸附效果影响不大，均可产生选择性吸附。

Investigated the organic surface modification of anatase titanium dioxide pigment and its adsorption mode. It was founded that the surface hydroxyl groups are the active centers for olefinic acid. The adsorption of modifier fit Langmuir single molecule layer adsorption mode.

研究了锐钛型钛白的有机表面改性及表面吸附模型，认为表面羟基是有机烯酸表面改性的活性中心，改性剂在钛白表面的吸附符合Langmuir单分子层吸附模型。

I can not make it blossom and suits me

我不能让树为我开花

When temperatures are above approximately 80 °C discolouration of the raceways or rolling elements is a frequent feature.

当温度高于 80 °C 左右时，滚道或滚动元件褪色是很常见的特征。