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The authors analysed naked and transformed groups of fibrous brucite, wollastonite, chrysotile asbestos, sepiolite, palygorskite, clinoptilolite, crocidolite and diatomaceous earth mineral dust s by IR under acid and alkali etching and strong mechanical and polarized molecular interaction.

本文通过酸碱蚀、强机械力和极性分子等表面作用,利用红外吸收光谱手段分析7种重要矿物粉尘的表面基团裸露、转化过程,总结了矿物粉尘表面存在的基团类型及其表面活性位的分布及在不同环境条件下的转化,对讨论粉尘生物活性及矿物表面/细胞物理化学作用过程有重要意义。

The discrete random height variable of worn surface is described with continuous random variables by a mathematical method.

建立了磨损表面轮廓数值化基准、用连续随机变量来描述磨损表面轮廓线高度离散随机变量,对磨损表面高度分布作了数理统计分析,研究了载荷、滑动速度及镀层种类对磨损表面几何特性的影响,将数理统计分析结果与镀层的耐磨性作了比较分析,较为完整、深入地描述了磨损表面的几何特性。

The results show that the microstructure of ventra1 scale for python was composed of micro-convex and plank structure that was periodically arranged, it was mensurable and could be described by 9 characteristic parameters. Its surface was different in their forward and backward lean angle. The frictional coefficient of the ventra1 scale had closely relationship with moving direction, it decreased with the increasing load. The value of the frictional coefficient was about 0.07. The frictional coefficient while python moved backward and laterally were equal, and that was 33% more than that moved ahead. The frictional force of the ventra1 scale surface was caused by mechanical tooth function of micro-convex, acting intermolecular force and material's elastic hysteresis. The difference of forward and behind bevel for micro-convex was the anisotropy reason of frictional force.

结果表明:腹鳞表面的微观结构由指状微突体和板结构部分周期排列而成,其结构可用9个特征参数定量描述;腹鳞表面摩擦力由分子作用力、表面微突体的犁沟力、楔形作用力以及材料弹性滞后共同引起;腹鳞表面的摩擦系数在0.07左右并与运动方向有关,摩擦系数随载荷增加而减小;后向运动及左、右侧向运动时摩擦系数基本相等,比前向运动时高33%左右;腹鳞表面微突体不同方向上倾斜角度的差异是引起摩擦各向异性的主要原因。

Being different from conventional multimolecular micelle systems, the unimolecular micelle system of P(AMC14AB) not only shows critical micellar concentration (CMC=0),(i.e.once added to pure water, the surface tension decreases immediately in spite how small the density is), but also the surface tension stays almost the same with the concentration increasing.

P(AMC14AB)在溶液表面也发生表面吸附,使水的表面张力下降,即P(AMC14AB)也具有表面活性;随着浓度增大,表面吸附量增大,水的表面张力持续下降;当表面吸附达饱和时,表面张力~浓度曲线上出现突变点,该点定义为饱和的表面吸附浓度,而不应该再称为临界胶束浓度。

After this research work, we know that: HMCM-22 is a better catalyst of selecting naphthalene alkylation; Surface modification of zeolite Y is effective, but the effect of zeolite 3 is not evident and surface modification doesn"t suits mordenite; Surface modification doesn"t affect the frameworks and inner environments of zeolites, but only reduces diameter of orifice and overlays surface acidities; t-butanol is not suitable for alkylating agent of the reaction using modified zeolites as catalyst; Solvents with smaller molecular size are advantageous for naphthalene alkylation reaction using modified zeolites as catalyst, such as cyclohexane is better than decalin.

通过本论文的研究,我们知道:HMCM-22是萘择形烷基化反应较好的沸石之一;Y沸石的外表面改性效果较好,β沸石则效果不明显,而丝光沸石则不适于外表面改性;外表面改性不改变沸石的骨架结构和孔道内部环境,仅减小孔口直径和覆盖外表面酸性位;叔丁醇不适于作外表面改性沸石催化的反应的烷基化试剂,其反应活性很低,且选择性无明显提升;分子较小的溶剂更适于外表面改性沸石催化的反应,环己烷就明显好于十氢萘。

By thermodynamically and dynamically calculating and analysing ,a new growth mechanism of spherical graphite has been proposed ,that is,the spherical graphite does not grow inwardly,but grow outwardly and when spherical graphite grow outwardly carbon atoms come into and fill-up the entocoele of spherical graphite by the diffusing way.

通过对石墨球最终表面的形态进行分析,可以获得气泡的表面并不是石墨球的最终表面,石墨球表面主要由于受到石墨球表面各微晶长大速度不均匀性、铁水中的三大起伏、微量元素与碳原子的竟相吸附、由于浓度梯度和温度梯度所引起铁水的对流等各种因素的综合影响结果使其表面成为凹凸起伏的形状

Three part of research works had been carried out in the dissertation. The first part: a kind of multidentate amine modified silica gel was synthesized through the following steps:(1) introduce the amino groups onto the surface of silica-gel by the treatment of surface silanol groups withγ-aminopropyl trimethoxy silane;(2) michael addition of excess trihydroxymethyl propyl triacrylate to amino groups on the silica gel surface;(3) amidation of the unreacted double bonds of TMPTA on the surface of TMPTA modified silica gel with diethylenetriamine;(4) the multidentate amine modified silica gel was finally obtained by the reaction of amino groups on the surface of DETA modified silica gel with double bond of butyl acrylate.

本论文进行了三部分研究工作,第一部分:通过多步反应对硅胶进行改性合成了一种多齿胺改性硅胶配体,合成过程如下:1通过γ-氨丙基三甲氧基硅烷与硅胶表面的硅羟基反应,使硅胶表面带有氨基;2利用硅胶表面氨基与过量的三羟甲基丙烷三丙烯酸酯发生Michael加成反应;3利用二乙烯三胺与TMPTA改性硅胶表面未反应的双键发生反应使硅胶表面氨基化;4最后用丙烯酸正丁酯与DETA改性硅胶表面氨基充分反应成功合多齿胺改性硅胶配体。

The numerical results of stationary and transient Green'sfunction for high-velocity surface-head wave on some selected crystals are comparedThrough the above analyse,it is indicate that the first arrival wave mode is thelongitudinal-wave head-wave,and its propagate velocity is equal to the groupvelocity of the longitudinal bulk wave alone the surface.Furthermore,this modedoes not have the Δv/v effect,i.e.,its velocity is the same no matter the surface isfree or metalized.

通过对表面激发的瞬态和稳态Green理论分析和数值计算,表明在压电晶体表面上实际上看到的最高速的最先到达的波动模式是纵波头波,它具有沿表面纵波的群速度,而且对压电晶体,它不具有Δv/v效应,即在自由表面和金属化表面其传播速度是一样的,而压电晶体表面波及伪表面波均存在Δv/v效应。

The roughness shape of ceramic machining surface is analysed by four kinds of test methods: surface profile, scanning electron microanalyses, bearing ratio curve and profile ratio of peak to valley. Ceramics are machined by"plateau honing"to obtain the plateau property and wearability of machining surface. The machining surfaces own its functional surface.

采用表面微观轮廓、扫描电镜观察、表面支承长度率曲线以及表面轮廓峰谷比等四种研究方法,详尽分析了陶瓷材料加工表面的轮廓形状特征,并采用平顶珩磨加工方法,获得陶瓷加工表面的平顶特性,提高了加工表面耐磨性。

A series of erosion-corrosion test has been done to J55 steel under the influence of current of gas-liquid phase by indoor self-made devices, and the corrosion mechanism of current of gas-liquid phase to oil pipe's inner surface has been got. The results show that oil pipe's inner surface will be corroded fleetly by liquid medium and corrosion products will form on it. But at the same time, the corrosion products or protective layer will be removed from the inner surface of steel pipes under the alternate impact of high speed gas and liquid flow, and on this bare steel surface corrosion film will form again and be removed again. Thus, by these ways the corrosion is exacerbated. Surface erosion-corrosion failure comes into being with the circulation of this process going on.

本文主要在气液两相流作用条件下,通过室内自制装置,对管材钢J55做了系列冲刷-腐蚀试验,结果表明,气液两相流对钢管内表面冲刷-腐蚀的机理是钢管内表面会受到液体介质的快速腐蚀,生成腐蚀产物,同时钢管金属表面不断被具有高流速的气液相交替地冲击,不断地从金属表面脱去保护膜或腐蚀产物,裸露的钢表面又会被介质快速腐蚀形成腐蚀膜后,再被两相流冲掉,如此反复,造成管内金属表面膜的连续破坏,使腐蚀加剧,最终导致钢铁表面的冲刷腐蚀失效。

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