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The function mechanism among the minerals and floatation drugs had been studied with the way of IR and academic calculation, which pointed out that absorption of G-4 on the surface of phosphorite belonged to physical and chemical types, but the chemical one was in the highest flight. Absorption of amine collector named GE-609 on the surface of quartz belonged to electrostatic and physical type. Distilled water could hardly wash the GE-609 down from the surface of quartz. Leading component of S-721 was the concentrated compound of naphthol sulfonic acid and formaldehyde. The compound had a stronger affinity to the Mg~(2+) on surface of dolomite than the Ca2+ on surface of phosphorite, which is the essential reason in the separation of phosphorite and dolomite. The leading components of soluble glass in function were HSiO3 hydronium and F^SiC^ colloid granule.

通过红外光谱测定以及理论计算的方法研究了选矿药剂与矿物间的作用机理,研究表明:脂肪酸捕收剂G-4对胶磷矿的捕收作用是以化学吸附为主、化学吸附与物理吸附共同作用的结果;胺类阳离子捕收剂GE-609在石英表面的吸附属于静电物理吸附,但很难用水洗的方法使GE-609从石英表面脱附;S-721主要成分为萘酚磺酸与甲醛的缩合物,萘酚磺酸与甲醛的缩合物对白云石表面Mg~(2+)的吸附明显强于对胶磷矿表面Ca~(2+)的吸附,这是胶磷矿与白云石分离的根本原因;水玻璃溶液中对石英起抑制作用的主要组分是HSiO_3~-和H_2SiO_3胶粒,水玻璃除对石英起抑制作用外,对矿浆还具有一定的分散作用。

Calcium carbonate and soluble glass and so on were confected as alkaline antifouling agent. The Infrared Spectrometry results showed that 2275-2250 cm~(-1) diagnostic absorb wave crest in part A and 3390-3200 cm~(-1) in part B and 1730 cm~(-1) in coating film strongly proved polymers reacted just as the reacting mechanism, that means polysiloxane which offer low-surface-energy property linked Polyurethane system by —OH groups reacting with —NCO groups. Relative molar mass of part A and part B was determined by Gel Permeation Chromatography and the results were appropriate. Surface-energy was determined and results were between 33.6-47.17 mN/m and it increased when alkaline antifouling agent was put into the coating. Alkaline antifouling agent was releasing steadily when the coating film was dipped in seawater. As time gone, the pH value of seawater was increasing. Solubility parameter and results showed that there was no corrasive phenomenon between the polyethylene strand and the coating.

红外光谱分析结果表明,出现在A组分中的2275~2250cm~(-1)处的异氰酸酯特征吸收峰、B组分中的3390~3200cm~(-1)处硅羟基的特征吸收峰及出现在固化后涂膜中的1730cm~(-1)处氨基甲酸酯基团的特征吸收峰证明了涂料成膜物质交联固化符合本文的设计要求,即赋予涂膜低表面能特性的有机硅组分通过—OH基团与—NCO基团的反应已经链接到聚氨酯体系中;凝胶渗透色谱结果表明,成膜物质的A、B组分均为低分子量,符合预聚物的要求;涂膜表面能的测算结果表明,涂膜的表面能在33.6~47.17mN/m之间;加入碱式防污剂后涂膜的表面能略有升高;碱式防污剂的释放平稳,随着涂膜在海水中浸泡时间的增长,pH值有增加的趋势;用溶解度参数原则来评价涂料与网绳的涂装,结果表明,本试验研制的防污涂料对聚乙烯网绳无溶蚀作用。

Biosurfactant is a high surface-active agent synthesized by microorganism. Compared with chemical surfactant, it has a low toxicity to ecological system and can be easily decomposed.

生物表面活性剂是由微生物产生的具有高表面活性的生物分子,相对于化学合成的表面活性剂,生物表面活性剂对生态系统的毒性较低,且可生物降解。

In chapter three, various theories and experience on the dispersion of nano-powders proposed by former researchers were generalized and reviewed. Technical standards and experimental process for determining technological parameters were suggested for the dispersion of nano-scaled metal oxides in aqueous medium according to their surface wettability, surface charge, the dependence of surface charge on pH and the compatibility of surfactants with pH and pH adjusting agents. Based on these suggested standards and experimental method, highly stable and dispersive aqueous suspensoid of nm-ZnO, nm-TiO〓, nm-Co〓O〓 and nm-MnO powders were prepared successfully and surface modification on these nano-powders was also achieved.

本文第三章通过大量的文献调研,归纳总结了前人在纳米粒子分散技术方面的理论和经验,并在此基础上根据纳米氧化物粉体的表面润湿性、表面电性及其与分散介质pH值的关系、表面活性剂及其与pH调节剂的配伍关系设计了纳米氧化物水分散体系的工艺规范以及确定工艺参数的通用实验步骤,成功地制备了纳米氧化锌、纳米二氧化钛、纳米氧化钴和纳米氧化锰的高稳定分散悬浮液并实现了干粉体的表面改性,为纳米材料在氧化锌压敏电阻中的应用创造了第二个前提条件。

In this paper we performed calculation on electrical structure of SnO2(110) surface of (1×1) and (2×1) symmetry with first principle DFT theory. We emphasized on the effect of O vacancies on surface electronic structure and future adsorption.

本文应用第一性原理密度泛函理论研究了具有(1×1)和(2×1)对称性的SnO2(110)氧化表面和还原表面的几何结构和电子结构,重点分析了表面氧空穴对表面电子结构的影响以及对气体分子吸附的影响。

However the addition order of tartrate and phosphate on activity of enzyme adsorbed by goethite produced the greatest impact.

胶体表面类型(硅氧烷表面或羟基化表面)及阴离子配体对胶体表面负电荷的贡献量在酶的吸附及活性保持中的重要性;B阴离子配体后加入时酶的吸附量一般比配体先加入时的高;C)配体加入顺序对二氧化锰的影响最显著,对砖红壤和高岭石的居中;对针铁矿的次之;对黄棕壤的最小。D)乙酸或草酸加入顺序对高岭石上固定化酶比活性的影响最大,而酒石酸或磷酸则对针铁矿影响最大。

The dispersion behavior of ultrafine talc in aqueous system was investigated by the sedimentation test. The dispersion effects of cationic surfactant and some anionic surfactants with different hydrophilic ionogens were studied. By testing the changes of Zeta potential and the dispersion rate of the system with the addition of surfactant, the dispersion mechanism of dispersants was discussed.

采用沉降法考察了阳离子表面活性剂和几种亲水基不同的阴离子表面活性剂在水介质中对微细滑石颗粒的分散效果;通过测试加入表面活性剂前后颗粒表面Zeta电位、体系分散率变化,探讨了分散剂的作用机理。

Heating billet temperature cannot be detected in the hearth. Only by detecting temperatures of the stove side or hearth with estimation from mere experience could lead to great error on the measurement of billet temperature and affect the quality of post-processing accordingly; Overheating also exists in the heating process, and the quality of product is sway by overheating oxidation. Though infrared thermoscope is used to detect the temperature of billet when it is taken out of the stove, precision is still affected because of the oxide layer on the surface.

燃气与空气的配气量比例,一般通过人工调节,未实现按加热条件自动动态调节;无法在炉膛内检测被加热钢材的温度,只能通过检测炉壁或炉膛温度,再凭经验估计钢材温度,结果是钢板温度误差大,影响后续加工质量;钢材加热存在表面过烧现象,有时表面烧损、氧化严重,影响产品质量;尽管钢材出炉时,可用红外线测温仪来进行钢材表面温度检测,但因钢材表面存在氧化层,也影响钢材温度检测精度。

A heavy duty tire comprises a tread portion, a pair of sidewall portions, a pair of bead portions each with a bead core therein, the bead core with an aspect ratio (HC 1 /WC) of from 0.43 to 0.58, and a carcass comprising a carcass ply of cords extending between the bead portions and turned up around a bead core in each bead portion from the inside to outside of the tire so as to form a pair of turnup portions and a main portion therebetween, the turnup portion comprising a turnup main-part extending along an axially inner surface, a radially inner surface and an axially outer surface of the bead core smoothly, and a turnup sub-part extending from the turnup main-part toward the main portion near the radially outer surface of the bead core.

本发明公开一种重载轮胎,包括:胎圈部分;一对胎侧部分;一对胎圈部分,每个胎圈部分中具有一胎圈芯,所述胎圈芯的高宽比(HC1/WC)在0.43到0.58范围内;以及胎体,其包括胎体帘布层,该胎体帘布层的帘线在胎圈部分之间延伸并且绕每个胎圈部分中的胎圈芯从轮胎内侧卷绕到轮胎外侧,而形成一对卷起部分以及位于该对卷起部分之间的主体部分,卷起部分包括沿胎圈芯的轴向内表面、径向内表面以及轴向外表面平滑延伸的卷起主部以及邻近胎圈芯的径向外表面而从卷起主部朝主体部分延伸的卷起子部。

The oxidation kinetics of depleted uranium was studied in pure oxygen pressure of 5 kPa at below 100°C by using spectroscopic ellipsometry. The relationship of the thickness of uranium oxide with time is measured. The results indicate that below 100°C in the initial period, the relationship between oxidation layer thickness and time is parabolic. The oxidation mechanism of depleted uranium is discussed and the active energy of depleted uranium at given experimental conditions is 87.165kJ/mol from calculation.

采用椭偏技术研究了45~95℃和5kPa纯氧气氛中金属铀的氧化,通过不同温度下金属铀表面氧化层厚度随时间的变化规律,得到贫铀在初始氧化阶段的表面氧化层厚度与时间的关系均呈现抛物线规律;绘制出了在不同温度下金属铀表面的氧化动力学曲线,由此得到在低于100℃,5kPa的纯氧气氛下贫铀表面形成氧化物的反应活化能为87.165kJ/mol。

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