衍生物

In order to get more active compounds,two related active drugs by combination theory with raw material cinnamic acid.

目的：利用拼合原理，以桂皮酸为原料，与相关活性的药物成酯得到衍生物，以期得到活性更高的药物。

The reaction between 3, 4 cinnamic acid and 〓 has also been investigated as an evidence for the electron transfer mechanism.

以〓为过氧自由基模型，研究了羟基肉桂酸衍生物对该自由基的清除作用，发现这类化合物，特别是芥子酸，能够通过电子转移反应有效地还原过氧自由基。3，4-亚甲二氧基肉桂酸与〓的反应的动力学研究为电子转移机制提供了证据。

The interaction between the polycation and polyanion was studied by spectrophotometry and conductometric titration.

目前研究得较多的体系是聚苯乙烯衍生物，如Ioplex 1 0 1即由聚苯乙烯磺酸钠和聚氯化乙烯基苄基三甲基铵反应而得[2 ，3] 。。。。。

The factors affect on the degree of substitution of product, yield and apparent viscosity, such as the mol rates of EPTAC with -NH2, reaction temperature, reaction time and the content of water in system have been discussed in detail. FTIR spectrometer and UV spectrometer are used to characterize the structure of the derivative and it is proved that substitution reaction mainly occurs on the -N element .The particle size and morphology of chitosan and quantemary ammonium salt of chitosan are analysised by comparing photos of their scanning electron microscope. The degree of substitution of HACC is determined by acid -base conductometric titration. An error in current formula of DS has pointed out and a correct formula has presented.On the base of experience of above experiment, the reaction conditions of HACC were systematically investigated through orthogonal design, and then the best conditions are found. Water-solubility and dependence of pH are studied.

壳聚糖和环氧丙基三甲基氯化铵在异相条件下发生反应，通过单因素实验，制备了一系列不同性能的壳聚糖季铵盐，本文首次详细讨论了反应条件(反应摩尔比、反应时间、反应温度、水含量)对产率及产物性能的影响；用红外光谱和核磁共振对结构进行表征分析时，发现季铵盐阳离子基以N位上取代为主；通过电镜图片对壳聚糖和季铵盐衍生物外观形貌进行对比，采用酸碱电导滴定法测定产物的取代度，并对常用取代度公式做了修正。

The structure and stability of all possible isomers of C50X(X=SiH2, PH, S) were investigated by ab initio HF/3-21G calculations. The calculation results indicate that the preferred position for cycloaddition of SiH2, PH, and S on C50 is consistent, i.e. on the C3-C4 and C4-C4 sites of C50, and the resultant most stable cycloaddition isomers are [5,6]-closed and [5,5]-closed structures. The main driving force governing the stability of the C50X(X=SiH2, PH, S) isomers is the strain, or the conjugative effect, or the combination of strain and conjugative effect, depending on the addition positions and the types of the attacked C-C bonds.

用从头算HF/3-21G方法研究了C50的环加成衍生物C50X(X=SiH2， PH， S)所有可能的异构体的结构与稳定性，计算结果表明，SiH2基团、PH基团与S原子在C50上环加成的优先加成位置相同，都为C3-C4类键和C4-C4类键，并且相应形成[5，6]-闭环和[5，5]-闭环结构的最稳定异构体；决定C50X(X=SiH2，PH，S)各异构体稳定性的主要因素，因加成位置以及发生加成反应的C-C键的单双键类型的不同，可能是张力、共轭效应或者二者的共同作用。

Crystal by DTT into the protoxin with an end amino group; activation and derivation of abamectin to form abamectin-COONa with a carboxylic group; final bioconjugation by using amino-carboxylic conjugator EDC to achieve the substance combination of two biotoxins.

晶体进行酶解改造，形成带末端氨基的原毒素；将阿维菌素的羟基进行激活、衍生化，形成带羧基的阿维菌素衍生物（Abamectin-COONa）；再利用氨基-羧基偶联剂进行两种生物毒素的生物耦合。

The characteristics defined this way are functionally equivalent to the characteristics that are printed on a card; for example, they define the token's copiable values.

鬼怪斥候衍生物」的名称是「鬼怪斥候」，且它的生物副类别为鬼怪和斥候。

In the present study,a novel microgel was designed by the incorporation of temperature sensititive N-isopropylacrylamide and pH sensitive acrylic acid to copolymerize with glucosamine derivative,acrylamido-2-deoxy-glucose. The novel microgel has favorable biocompatibility,tissue-targeting and stimuli-responsibility to pH and temperature.

本文利用具有生物相容性的氨基葡萄糖单糖衍生物、具有温敏性的异丙基丙烯酰胺及具有pH敏感性的丙烯酸共聚得到了全新的微凝胶，新型微凝胶具有良好的生物相容性、组织靶向性和对温度、pH的刺激响应性。

Based on the problem of various types of catalyst and according to the features of carbonylation catalysts reactions, our team has been designed a series of new metal complexes of benimidazoles, which can be used for carbonylation catalyst of industry. Seven new benzimidazole derivatives were prepared by the o-phenylenediamine、oxalic acid、glycolic acid、monomethyl monopotassium malonate、ethyl cyanoacetate、succinic anhydride. The structures of them were confirmed by IR、Elemental analsis. The crystal structures of d and e were determined by X-ray single crystal diffraction of Germanic Bruker Smart APEX II CCD. The catalysis of them was tested by carbonylation reactions.

本文设计以邻苯二胺和草酸、羟基乙酸、丙二酸单甲酯、氰基乙酸乙酯、丁二酸单甲酯为原料采用PPA催化和无机酸催化法，合成了4种苯并咪唑-2-羧酸衍生物并进行了表征；培养了2个化合物d、e的晶体并测定和讨论了晶体结构；制备了3种未见报道的苯并咪唑金属配合物，对配合物在羰基化法制醋酐-醋酸反应的催化作用进行了初步试验。

Photoinduced Electron Transfer [2+2] Cycloaddition Reactions ofBenzannelated Isoquinolin-1-ones with Electron Deficient Alkenes Photoinduced [2+2] cycloaddition reactions of 11H-benzoxazolo[3,2-b]isoquinolin-11-one 8 and 11H-benzothiazolo[3,2-b]isoquinolin-11-one 13 with electron deficient alkenessuch as acrylonitrile, methyl acrylate, dimethyl fumarate and dimethyl maleate afforded a group of polycyclic isoquinoline derivatives bearing cyclobutane moieties ingood to excellent yields and resulted in the Schenck isomerization of the alkenes.

3苯并增环异喹啉-1-酮与缺电子烯烃的光诱导电子转移[2+2]环加成反应 11H-苯并恶唑[3，2-b]异喹啉-11-酮8和11H-苯并噻唑[3，2-b]异喹啉-11-酮13与缺电子烯烃如丙烯腈，丙烯酸甲酯，富马酸二甲酯及马来酸二甲酯的光诱导[2+2]环加成反应以高产率给出一系列含有环丁烷结构单元的多环异喹啉衍生物并导致烯烃的Schenck异构化作用。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。