衍生物

In this paper, a series of 4,5-dithiacrown ether annulated 1,3-dithiole-2-thiones 8a~8d were prepared via condensing 4,5-bis-1,3-dithiole-2-thione (7) with 1,ω-dimercapto polyglycol derivatives in high dilution. The obvious template effect was found during the synthesis of 8c-8d.

在高度稀释条件下，经4，5-二溴甲基-1，3-二硫杂环戊烯-2-硫酮(7)和多缩乙二醇的1，ω-二巰基衍生物的缩合反应，方便地合成了4，5-位带二硫杂冠醚残基的2-硫代-1，3-二硫杂环戊烯的衍生物8a~8d，中间体硫杂冠醚8c~8d的合成中有明显的&模板效应&。

Four anthryl lower aliphatic amine derivatives were synthesized, and DNA binding properties of these compounds were investigated by fluorescence and absorption spectra.

蒽的低级脂肪胺衍生物水溶性很好，不宜固定于PVC膜中，但它们可与核酸分子相互作用，其荧光光谱和吸收光谱发生明显变化。对于不同脂肪胺的衍生物，其作用结果不同。

Effects of different additives such as sulfurized olefin,mixtures of amine phosphates,ester thiophosphates,N-containing agents and ashless rust-resistant agents on the emulsion stability ,EP/AW properties and rust-resistance of industrial gear oil were studied.

研究了硫化烯烃、磷酸酯胺盐、硫磷酸酯极压抗磨剂，含氮杂环衍生物多功能添加剂和防锈剂等，对工业齿轮油抗乳化性能、极压抗磨性能、防锈性能的影响；以及硫化烯烃、磷酸酯盐极压抗磨剂与含氮杂环衍生物多功能添加剂之间的协和效应。

In the same time, a number of barbituric acid derivatives have been designed. The relations of structure-properties was studied by connecting anthraquinone, benzene and furan.

并以1H-NMR，FTIR，UV-vis，Mass进行了表征，确定了其结构，另外设计了几种巴比妥酸衍生物分子，通过在巴比妥酸衍生物中引入萘、苯以及芳香杂环等不同的共轭桥，研究了结构性能关系。

Compared with 3, 6-carbazo derivatives, the OPA wavelengths of 2, 7-carbazole derivatives are bathochromic shift and the oscillator strength increased; the TPA wavelengths are red-shifted and the TPA cross-section increased.

与3， 6-咔唑衍生物相比，2， 7-咔唑衍生物的单光子吸收波长红移，振子强度增大；双光子吸收波长红移，双光子吸收截面增加。

Four novel benzothiazole-phosphites were prepared from benzothiazole derivatives. Their structures were confirmed by IR, NMR and elemental analysis.

为了寻找具有更高杀菌活性的化合物，将苯并噻唑衍生物与亚磷酸反应，得到了4个苯并噻唑衍生物的亚磷酸盐，其结构均经IR、NMR及元素分析确证。

The studies are significant to propose the synthetic methodology of benzothiazole derivatives,broaden the application of the metal complexes of benzothiazoles.It is practical value of the research in preparation of phenylacetic acid from metal-catalyized carbonylation.The thesis consists of four chapters.

本论文研究了苯并噻唑衍生物及其钴、铑金属配合物的合成，并研究了两类金属配合物的羰基化催化性能，提供了合成苯并噻唑衍生物的可行路线，拓宽了苯并噻唑金属配合物的应用范围，催化羰基化合成苯乙酸的研究具有重要的实用价值。

Due to a variety of biological activity, benzotriazole derivatives receive wider and wider spread attention about their synthesis as well as the activity research.

苯并三氮唑类衍生物由于具有多种生物活性，关于它们的合成以及活性研究受到越来越广泛的关注，因此，苯并三氮唑及其衍生物的研究与开发具有重要的意义。

Based on studies of RCM reaction of 50 and CM reaction ofacrylonitrile with 1-octene or 1-decene catalyzed by pyridine derivative-coordinatedruthenium benzylidene complexes, it can be concluded that ruthenium benzylidene complexwith the more labile dissociating ligand exhibits the higher initial activity and better catalyticperformance.

吡啶衍生物配位的钌卡宾配合物催化含氰基烯烃50闭环交互置换反应和丙烯腈与1-辛烯、1-癸烯交叉交互置换反应表明，催化剂中吡啶衍生物配体越易解离，其初活性越高，催化活性越好。

Similarly, IVB〓 reacted with carboxylic acids in DCC/DMAP/DCM system to produce ten new 5-IVB〓 esters in 66-82% yield. AVB〓 or IVB〓 also reacted with carbamino chloride or phosphoryl chloride in IM/DMAP system to produce eight corresponding carbamates or phosphorylates in good yields.

阿维菌素B〓与氨基甲酰氯反应，合成了2个5-AVB〓氨基甲酸酯衍生物：阿维菌素B〓与膦酰氯反应，合成2个5-AVB〓膦酸酯衍生物；并改进了阿维菌素与酰氯的反应条件，缩短了反应时间，提高了产率和反应的选择性。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。