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衍射光谱

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Three novel rigid compounds 3, 6-bis[2-(4-pyridylethenyl]-9-ethylcarbazole (L~1), 3,6-bis[2-(2-pyridyl)ethenyl]-9-ethylcarbazole (L~2), 3,6-bis[2-(4-pyridyl)ethenyl]-9 -ethylpyridylcarbazole (L~3) were successfully synthesized by Heck reaction, which were fully characterized by elemental analyses, NMR, MS, IR spectra and single X-ray diffraction analysis.

利用Heck偶联反应,成功地合成了三种新型刚性的吡啶基咔唑类化合物:3,6-二[2-(4-吡啶基)乙烯基]-9-乙基咔唑(L~1),3,6-二[2-(2-吡啶基)乙烯基]-9-乙基咔唑(L~2)和3,6-二[2-(4-吡啶基)吡啶基]-9-乙基吡啶基咔唑(L~3),通过元素分析、核磁共振谱、质谱、红外光谱和单晶X-射线衍射等分析手段确证了它们的结构。

A novel supramolecular complex, [Cu2]CH3OHH2O (fum=fumarate dianion, dpphen=4, 7-diphenyl-1, 10-phenanthroline), has been prepared from the reaction of bidentate ligand, fumarate with CuCl2, and were characterized by element analysis, IR, thermal analysis and X-ray diffraction technique.

利用螯合配体4,7-二苯基-1,10-邻菲罗啉与反丁烯二酸钠及铜盐反应合成了一种新型超分子配合物[Cu2]CH3OHH2O(fum=反丁烯二酸根,dpphen=4,7-二苯基-1,10-邻菲罗啉)。通过元素分析、红外光谱、热分析和X射线单晶衍射等技术对其进行了表征。

The structure was characterized by elemental analysis and IR spectroscopy as well as thermal gravimetric analysis.

对该配位聚合物进行元素分析、红外光谱表征、热重分析和X-射线单晶衍射测定。

The charge transfer salts with second order nonlinear optical properties have been synthesized based on hexamethylenamine and the heteropoly acids,H 3PMo 12 O 40 ·nH 2O,H 4SiMo 12 O 40 ·nH 2O and H 4GeMo 12 O 40 ·nH 2O and characterized by elemental analysis,IR spectra and UV spectra.

本文研究了一系列不同富硫有机配体的配合物以及富硫有机分子修饰的硫化物;合成了两个系列的7个富硫配合物和2个电荷转移盐,运用元素分析、红外、紫外-可见光谱对配合物进行了表征,并且通过单晶四圆X-衍射测定了C_5H_6S_5CuI(1)、(C_5H_6S_5)2PdI_2(6)、C_(10H_(10)S_8[(C_4H_4S_4)AuCl_2](8)、C_(10H_(10)S_8Hg_2Cl_6(9)四个化合物的晶体结构。

The fresh and discharged catalysts from the isoamylene unit are characterized by XRD,TG-DTA,FT-IR and the pore structure analysis.

利用X射线衍射、热重分析、红外光谱和孔结构分析对新鲜的和从装置卸出的催化剂进行表征,并对催化剂活性下降的机理进行了讨论。

The fresh and discharged catalysts from the isoamylene unit are characterized by XRD, TG-DTA, FT-IR, and the pore structure analysis. The active decline mechanism of the catalyst is discussed.

利用X射线衍射、热重分析、红外光谱和孔结构分析对新鲜的和从装置卸出的催化剂进行表征,并对催化剂活性下降的机理进行了讨论。

The granular morphology and size, molecular weight distribution, crystal structure, thermodynamic properties, structural character, digestibility and glycaemic-index of starch from Kabuli and Desi chickpeas cultivars were investigated using scanning electron microscope, high performance liquid chromotagraphy, X-ray diffraction, differential scanning calorimetry,infrared spectrum and other modern analytical methods.

采用扫描电镜、高效液相色谱、X射线衍射、差示扫描量热仪、红外光谱等现代分析手段探讨了Kabuli与Desi品种鹰嘴豆淀粉的颗粒形貌与大小、分子量分布、结晶结构、热焓性质、结构特征、消化性能及血糖生成指数。

The granular morphology and size, molecular weight distribution, crystal structure, thermodynamic properties, structural character, digestibility and glycaemicindex of starch from Kabuli and Desi chickpeas cultivars were investigated using scanning electron microscope, high performance liquid chromotagraphy, Xray diffraction, differential scanning calorimetry, infrared spectrum and other modern analytical methods.

采用扫描电镜、高效液相色谱、X射线衍射、差示扫描量热仪、红外光谱等现代分析手段探讨了Kabuli与Desi品种鹰嘴豆淀粉的颗粒形貌与大小、分子量分布、结晶结构、热焓性质、结构特征、消化性能及血糖生成指数。

Cyclohexanone glycol ketal was synthesis from cyclohexanone and ethylene glycol in the presence of a late-model catalyst, which was prepared with fly ash as raw material. The catalysts were characterized by means of XRD, TG and FTIR.

以粉煤灰为原料制备了一种新型的固体酸催化剂,用X射线衍射、热分析和红外光谱等手段表征了催化剂的物化性能。

The total of 36 compounds were characterized by X-ray single crystal diffraction, EA, TG, IR, luminescence, adsorption, XPS, powder XRD, M〓ssbauer spectra, EPR, magnetical measurements.

本论文利用水热法,成功设计和合成出三个系列Ln-M(M=Mn〓,Fe〓,Ag〓)共23个未见文献报道的稀土—过渡混合金属配位聚合物,同时也得到了结构新颖的仅含稀土或两种不同过渡金属的从一维到三维的聚合物13个,并对它们进行了结构、元素分析、热重分析、红外光谱、荧光、吸附、磁性、光电子能谱、粉末衍射和M〓ssbauer谱等表征。

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